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Published work

116 published item(s)

preprint2026arXiv

Mantis: Mamba-native Tuning is Efficient for 3D Point Cloud Foundation Models

Pre-trained 3D point cloud foundation models (PFMs) have demonstrated strong transferability across diverse downstream tasks. However, full fine-tuning these models is computationally expensive and storage-intensive. Parameter-efficient fine-tuning (PEFT) offers a promising alternative, but existing PEFT approaches are primarily designed for Transformer-based backbones and rely on token-level prompting or feature transformation. Mamba-based backbones introduce a granularity mismatch between token-level adaptation and state-level sequence dynamics. Consequently, straightforward transfer of existing PEFT approaches to frozen Mamba backbones leads to substantial accuracy degradation and unstable optimization. To address this issue, we propose Mantis, the first Mamba-native PEFT framework for 3D PFMs. Specifically, a State-Aware Adapter (SAA) is introduced to inject lightweight task-conditioned control signals into selective state-space updates, enabling state-level adaptation while keeping the pre-trained backbone frozen. Moreover, different valid point cloud serializations are regularized by Dual-Serialization Consistency Distillation (DSCD), thereby reducing serialization-induced instability. Extensive experiments across multiple benchmarks demonstrate that our Mantis achieves competitive performance with only about 5% trainable parameters. Our code is available at https://github.com/gzhhhhhhh/Mantis.

preprint2024arXiv

Query-Based Knowledge Sharing for Open-Vocabulary Multi-Label Classification

Identifying labels that did not appear during training, known as multi-label zero-shot learning, is a non-trivial task in computer vision. To this end, recent studies have attempted to explore the multi-modal knowledge of vision-language pre-training (VLP) models by knowledge distillation, allowing to recognize unseen labels in an open-vocabulary manner. However, experimental evidence shows that knowledge distillation is suboptimal and provides limited performance gain in unseen label prediction. In this paper, a novel query-based knowledge sharing paradigm is proposed to explore the multi-modal knowledge from the pretrained VLP model for open-vocabulary multi-label classification. Specifically, a set of learnable label-agnostic query tokens is trained to extract critical vision knowledge from the input image, and further shared across all labels, allowing them to select tokens of interest as visual clues for recognition. Besides, we propose an effective prompt pool for robust label embedding, and reformulate the standard ranking learning into a form of classification to allow the magnitude of feature vectors for matching, which both significantly benefit label recognition. Experimental results show that our framework significantly outperforms state-of-the-art methods on zero-shot task by 5.9% and 4.5% in mAP on the NUS-WIDE and Open Images, respectively.

preprint2024arXiv

SyCoCa: Symmetrizing Contrastive Captioners with Attentive Masking for Multimodal Alignment

Multimodal alignment between language and vision is the fundamental topic in current vision-language model research. Contrastive Captioners (CoCa), as a representative method, integrates Contrastive Language-Image Pretraining (CLIP) and Image Caption (IC) into a unified framework, resulting in impressive results. CLIP imposes a bidirectional constraints on global representation of entire images and sentences. Although IC conducts an unidirectional image-to-text generation on local representation, it lacks any constraint on local text-to-image reconstruction, which limits the ability to understand images at a fine-grained level when aligned with texts. To achieve multimodal alignment from both global and local perspectives, this paper proposes Symmetrizing Contrastive Captioners (SyCoCa), which introduces bidirectional interactions on images and texts across the global and local representation levels. Specifically, we expand a Text-Guided Masked Image Modeling (TG-MIM) head based on ITC and IC heads. The improved SyCoCa can further leverage textual cues to reconstruct contextual images and visual cues to predict textual contents. When implementing bidirectional local interactions, the local contents of images tend to be cluttered or unrelated to their textual descriptions. Thus, we employ an attentive masking strategy to select effective image patches for interaction. Extensive experiments on five vision-language tasks, including image-text retrieval, image-captioning, visual question answering, and zero-shot/finetuned image classification, validate the effectiveness of our proposed method.

preprint2022arXiv

"Adversarial Examples" for Proof-of-Learning

In S&P '21, Jia et al. proposed a new concept/mechanism named proof-of-learning (PoL), which allows a prover to demonstrate ownership of a machine learning model by proving integrity of the training procedure. It guarantees that an adversary cannot construct a valid proof with less cost (in both computation and storage) than that made by the prover in generating the proof. A PoL proof includes a set of intermediate models recorded during training, together with the corresponding data points used to obtain each recorded model. Jia et al. claimed that an adversary merely knowing the final model and training dataset cannot efficiently find a set of intermediate models with correct data points. In this paper, however, we show that PoL is vulnerable to ``adversarial examples''! Specifically, in a similar way as optimizing an adversarial example, we could make an arbitrarily-chosen data point ``generate'' a given model, hence efficiently generating intermediate models with correct data points. We demonstrate, both theoretically and empirically, that we are able to generate a valid proof with significantly less cost than generating a proof by the prover.

preprint2022arXiv

Auditing Privacy Defenses in Federated Learning via Generative Gradient Leakage

Federated Learning (FL) framework brings privacy benefits to distributed learning systems by allowing multiple clients to participate in a learning task under the coordination of a central server without exchanging their private data. However, recent studies have revealed that private information can still be leaked through shared gradient information. To further protect user's privacy, several defense mechanisms have been proposed to prevent privacy leakage via gradient information degradation methods, such as using additive noise or gradient compression before sharing it with the server. In this work, we validate that the private training data can still be leaked under certain defense settings with a new type of leakage, i.e., Generative Gradient Leakage (GGL). Unlike existing methods that only rely on gradient information to reconstruct data, our method leverages the latent space of generative adversarial networks (GAN) learned from public image datasets as a prior to compensate for the informational loss during gradient degradation. To address the nonlinearity caused by the gradient operator and the GAN model, we explore various gradient-free optimization methods (e.g., evolution strategies and Bayesian optimization) and empirically show their superiority in reconstructing high-quality images from gradients compared to gradient-based optimizers. We hope the proposed method can serve as a tool for empirically measuring the amount of privacy leakage to facilitate the design of more robust defense mechanisms.

preprint2022arXiv

Conditional Bilingual Mutual Information Based Adaptive Training for Neural Machine Translation

Token-level adaptive training approaches can alleviate the token imbalance problem and thus improve neural machine translation, through re-weighting the losses of different target tokens based on specific statistical metrics (e.g., token frequency or mutual information). Given that standard translation models make predictions on the condition of previous target contexts, we argue that the above statistical metrics ignore target context information and may assign inappropriate weights to target tokens. While one possible solution is to directly take target contexts into these statistical metrics, the target-context-aware statistical computing is extremely expensive, and the corresponding storage overhead is unrealistic. To solve the above issues, we propose a target-context-aware metric, named conditional bilingual mutual information (CBMI), which makes it feasible to supplement target context information for statistical metrics. Particularly, our CBMI can be formalized as the log quotient of the translation model probability and language model probability by decomposing the conditional joint distribution. Thus CBMI can be efficiently calculated during model training without any pre-specific statistical calculations and large storage overhead. Furthermore, we propose an effective adaptive training approach based on both the token- and sentence-level CBMI. Experimental results on WMT14 English-German and WMT19 Chinese-English tasks show our approach can significantly outperform the Transformer baseline and other related methods.

preprint2022arXiv

Demonstration of Parametric Instability suppression through optical feedback

We demonstrate the suppression of parametric instability using through optical actuation in an electro-optical feedback loop, stabilising the high order optical mode content in an 80 metre long Fabry-Perot cavity. The loop suppression of the high order mode is achieved by injecting a high order mode with the same frequency and opposite phase. Frequency matching is achieved by measuring the beat note signal between the fundamental and high order mode in transmission of the cavity and applying that signal to an electro-optical modulator to create the required frequency sideband. Spatial mode matching of the sideband to the high order mode is accomplished through the inherent mode overlap between the input injected beam and the high order mode of the cavity. The paper presents the theoretical analysis and experimental demonstration of parametric instability suppression, for an instability which would normally ring up with a parametric gain of approximately 2.5.

preprint2022arXiv

DProQ: A Gated-Graph Transformer for Protein Complex Structure Assessment

Proteins interact to form complexes to carry out essential biological functions. Computational methods have been developed to predict the structures of protein complexes. However, an important challenge in protein complex structure prediction is to estimate the quality of predicted protein complex structures without any knowledge of the corresponding native structures. Such estimations can then be used to select high-quality predicted complex structures to facilitate biomedical research such as protein function analysis and drug discovery. We challenge this significant task with DProQ, which introduces a gated neighborhood-modulating Graph Transformer (GGT) designed to predict the quality of 3D protein complex structures. Notably, we incorporate node and edge gates within a novel Graph Transformer framework to control information flow during graph message passing. We train and evaluate DProQ on four newly-developed datasets that we make publicly available in this work. Our rigorous experiments demonstrate that DProQ achieves state-of-the-art performance in ranking protein complex structures.

preprint2022arXiv

EGR: Equivariant Graph Refinement and Assessment of 3D Protein Complex Structures

Protein complexes are macromolecules essential to the functioning and well-being of all living organisms. As the structure of a protein complex, in particular its region of interaction between multiple protein subunits (i.e., chains), has a notable influence on the biological function of the complex, computational methods that can quickly and effectively be used to refine and assess the quality of a protein complex's 3D structure can directly be used within a drug discovery pipeline to accelerate the development of new therapeutics and improve the efficacy of future vaccines. In this work, we introduce the Equivariant Graph Refiner (EGR), a novel E(3)-equivariant graph neural network (GNN) for multi-task structure refinement and assessment of protein complexes. Our experiments on new, diverse protein complex datasets, all of which we make publicly available in this work, demonstrate the state-of-the-art effectiveness of EGR for atomistic refinement and assessment of protein complexes and outline directions for future work in the field. In doing so, we establish a baseline for future studies in macromolecular refinement and structure analysis.

preprint2022arXiv

Exceptional complete intersection maps of local rings

This work concerns surjective maps $φ\colon R\to S$ of commutative noetherian local rings with kernel generated by a regular sequence that is part of a minimal generating set for the maximal ideal of $R$. The main result provides criteria for detecting such exceptional complete intersection maps in terms of the lattices of thick subcategories of the derived category of complexes of finite length homology. A key input is a characterization of such maps in terms of the truncated Atiyah class of $φ$.

preprint2022arXiv

Label Relation Graphs Enhanced Hierarchical Residual Network for Hierarchical Multi-Granularity Classification

Hierarchical multi-granularity classification (HMC) assigns hierarchical multi-granularity labels to each object and focuses on encoding the label hierarchy, e.g., ["Albatross", "Laysan Albatross"] from coarse-to-fine levels. However, the definition of what is fine-grained is subjective, and the image quality may affect the identification. Thus, samples could be observed at any level of the hierarchy, e.g., ["Albatross"] or ["Albatross", "Laysan Albatross"], and examples discerned at coarse categories are often neglected in the conventional setting of HMC. In this paper, we study the HMC problem in which objects are labeled at any level of the hierarchy. The essential designs of the proposed method are derived from two motivations: (1) learning with objects labeled at various levels should transfer hierarchical knowledge between levels; (2) lower-level classes should inherit attributes related to upper-level superclasses. The proposed combinatorial loss maximizes the marginal probability of the observed ground truth label by aggregating information from related labels defined in the tree hierarchy. If the observed label is at the leaf level, the combinatorial loss further imposes the multi-class cross-entropy loss to increase the weight of fine-grained classification loss. Considering the hierarchical feature interaction, we propose a hierarchical residual network (HRN), in which granularity-specific features from parent levels acting as residual connections are added to features of children levels. Experiments on three commonly used datasets demonstrate the effectiveness of our approach compared to the state-of-the-art HMC approaches and fine-grained visual classification (FGVC) methods exploiting the label hierarchy.

preprint2022arXiv

Monolithically integrated active passive waveguide array fabricated on thin film lithium niobate using a single continuous photolithography process

We demonstrate a robust low-loss optical interface by tiling passive (i.e., without doping of active ions) thin film lithium niobate (TFLN) and active (i.e., doped with rare earth ions) TFLN substrates for monolithic integration of passive/active lithium niobate photonics. The tiled substrates composed of both active and passive areas allow to pattern the mask of the integrated active passive photonic device at once using a single continuous photolithography process. The interface loss of tiled substrate is measured as low as 0.26 dB. Thanks to the stability provided by this approach, a four-channel waveguide amplifier is realized in a straightforward manner, which shows a net gain of ~5 dB at 1550-nm wavelength and that of ~8 dB at 1530-nm wavelength for each channel. The robust low-loss optical interface for passive/active photonic integration will facilitate large-scale high performance photonic devices which require on-chip light sources and amplifiers.

preprint2022arXiv

Monolithically integrated waveguide-coupled single-frequency microlaser on erbium-doped thin film lithium niobate

We overcome the difficulty in realizing a monolithic waveguide-coupled microring laser integrated on erbium-doped thin film lithium niobate (Er: TFLN) using photolithography assisted chemo-mechanical etching (PLACE) technique. We demonstrate an integrated single-frequency microring laser operating around 1531 nm wavelength. The PLACE technique, enabling integrated Er: TFLN photonics with low propagation loss, can thus be used to realize low cost mass production of monolithic on-chip microlasers with applications ranging from optical communication and photonic integrated circuit (PIC) to precision metrology and large-scale sensing.

preprint2022arXiv

Multi-Forgery Detection Challenge 2022: Push the Frontier of Unconstrained and Diverse Forgery Detection

In this paper, we present the Multi-Forgery Detection Challenge held concurrently with the IEEE Computer Society Workshop on Biometrics at CVPR 2022. Our Multi-Forgery Detection Challenge aims to detect automatic image manipulations including but not limited to image editing, image synthesis, image generation, image photoshop, etc. Our challenge has attracted 674 teams from all over the world, with about 2000 valid result submission counts. We invited the Top 10 teams to present their solutions to the challenge, from which three teams are awarded prizes in the grand finale. In this paper, we present the solutions from the Top 3 teams, in order to boost the research work in the field of image forgery detection.

preprint2022arXiv

Multi-parametric Analysis for Mixed Integer Linear Programming: An Application to Transmission Planning and Congestion Control

Enhancing existing transmission lines is a useful tool to combat transmission congestion and guarantee transmission security with increasing demand and boosting the renewable energy source. This study concerns the selection of lines whose capacity should be expanded and by how much from the perspective of independent system operator (ISO) to minimize the system cost with the consideration of transmission line constraints and electricity generation and demand balance conditions, and incorporating ramp-up and startup ramp rates, shutdown ramp rates, ramp-down rate limits and minimum up and minimum down times. For that purpose, we develop the ISO unit commitment and economic dispatch model and show it as a right-hand side uncertainty multiple parametric analysis for the mixed integer linear programming (MILP) problem. We first relax the binary variable to continuous variables and employ the Lagrange method and Karush-Kuhn-Tucker conditions to obtain optimal solutions (optimal decision variables and objective function) and critical regions associated with active and inactive constraints. Further, we extend the traditional branch and bound method for the large-scale MILP problem by determining the upper bound of the problem at each node, then comparing the difference between the upper and lower bounds and reaching the approximate optimal solution within the decision makers' tolerated error range. In additional, the objective function's first derivative on the parameters of each line is used to inform the selection of lines to ease congestion and maximize social welfare. Finally, the amount of capacity upgrade will be chosen by balancing the cost-reduction rate of the objective function on parameters and the cost of the line upgrade. Our findings are supported by numerical simulation and provide transmission line planners with decision-making guidance.

preprint2022arXiv

Negative Zero-Point-Energy Parameter in the Meyer-Miller Mapping Model for Nonadiabatic Dynamics

The celebrated Meyer-Miller mapping model has been a useful approach for generating practical trajectory-based nonadiabatic dynamics methods. It is generally assumed that the zero-point-energy (ZPE) parameter is positive. The constraint implied in the conventional Meyer-Miller mapping Hamiltonian for an F-electronic-state system actually requires that parameter γis larger than -1/F for the ZPE parameter for each electronic degree of freedom. Both negative and positive values are possible for such a parameter. We first establish a rigorous formulation to construct exact mapping models in the Cartesian phase space when the constraint is applied. When nuclear dynamics is approximated by the linearized semiclassical initial value representation, a negative ZPE parameter could lead to reasonably good performance in describing dynamic behaviors in typical spin-boson models for condensed-phase two-state systems, even at challenging zero temperature.

preprint2022arXiv

New Phase Space Formulations and Quantum Dynamics Approaches

We report recent progress on the phase space formulation of quantum mechanics with coordinate-momentum variables, focusing more on new theory of (weighted) constraint coordinate-momentum phase space for discrete-variable quantum systems. This leads to a general coordinate-momentum phase space formulation of composite quantum systems, where conventional representations on infinite phase space are employed for continuous variables. It is convenient to utilize (weighted) constraint coordinate-momentum phase space for representing the quantum state and describing nonclassical features. Various numerical tests demonstrate that new trajectory-based quantum dynamics approaches derived from the (weighted) constraint phase space representation are useful and practical for describing dynamical processes of composite quantum systems in gas phase as well as in condensed phase.

preprint2022arXiv

On the Cayley-persistence algebra

In this paper, we introduce a persistent (co)homology theory for Cayley digraph grading. We give the algebraic structures of Cayley-persistence object. Specifically, we consider the module structure of persistent (co)homology and show the decomposition of a finitely generated Cayley-persistence module. Moreover, we introduce the persistence-cup product on the Cayley-persistence module and study the twisted structure with respect to the persistence-cup product. As an application on manifolds, we show that the persistent (co)homology is closely related to the persistent map of fundamental classes.

preprint2022arXiv

On-chip integrated Yb3+-doped waveguide amplifiers on thin film lithium niobate

We report the fabrication and optical characterization of Yb3+-doped waveguide amplifiers (YDWA) on the thin film lithium niobate fabricated by photolithography assisted chemo-mechanical etching. The fabricated Yb3+-doped lithium niobate waveguides demonstrates low propagation loss of 0.13 dB/cm at 1030 nm and 0.1 dB/cm at 1060 nm. The internal net gain of 5 dB at 1030 nm and 8 dB at 1060 nm are measured on a 4.0 cm long waveguide pumped by 976nm laser diodes, indicating the gain per unit length of 1.25 dB/cm at 1030 nm and 2 dB/cm at 1060 nm, respectively. The integrated Yb3+-doped lithium niobate waveguide amplifiers will benefit the development of a powerful gain platform and are expected to contribute to the high-density integration of thin film lithium niobate based photonic chip.

preprint2022arXiv

Radiation hardness study on a CMOS pixel sensor for charged particle tracking

A CMOS pixel sensor, named Supix-1, is developed for a pixelated silicon tracker for the Circular Electron-Positron Collider (CEPC) project. The sensor, consisted of nine sectors varying in pixel sizes, diode sizes and geometries, is fabricated with a 180 nm CMOS Image Sensor (CIS) process to study the particle detection performance of enlarged pixels. In this work, the radiation-induced effects on the charge collection of the sensor under the fluence of 1 $\times$ 10^13 1 MeV neq/cm^2 are studied by the measurements with the radioactive source of Fe-55 and the Technology Computer Aided Design (TCAD) simulations, since the radiation hardness of 6.8 $\times$ 10^12 1 MeV neq/cm^2 per year for Non-Ionizing Energy Loss (NIEL) effects is required. In measurements, the sensor gain has been calibrated using the k-$α$ peak of Fe-55 before and after irradiation. The pixel-wise equivalent noise charge (ENC), charge collection efficiency (CCE) and signal-to-noise ratio (SNR) were evaluated. The radiation-induced effects on cluster properties are studied through a self-developed reconstruction algorithm. In TCAD simulations, charge collections in 5 $\times$ 5 pixel matrixes for two typical impinging cases of incident particles were simulated with and without irradiation. Both measurements and simulations indicate that enlarged pixels with area of 21 $μ$m $\times$ 84 $μ$m, though suffering greater loss on sensor performance than small pixels do, still have satisfactory noise and charge collection performance after irradiation for particle tracking in the upcoming collider detectors.

preprint2022arXiv

RIBAC: Towards Robust and Imperceptible Backdoor Attack against Compact DNN

Recently backdoor attack has become an emerging threat to the security of deep neural network (DNN) models. To date, most of the existing studies focus on backdoor attack against the uncompressed model; while the vulnerability of compressed DNNs, which are widely used in the practical applications, is little exploited yet. In this paper, we propose to study and develop Robust and Imperceptible Backdoor Attack against Compact DNN models (RIBAC). By performing systematic analysis and exploration on the important design knobs, we propose a framework that can learn the proper trigger patterns, model parameters and pruning masks in an efficient way. Thereby achieving high trigger stealthiness, high attack success rate and high model efficiency simultaneously. Extensive evaluations across different datasets, including the test against the state-of-the-art defense mechanisms, demonstrate the high robustness, stealthiness and model efficiency of RIBAC. Code is available at https://github.com/huyvnphan/ECCV2022-RIBAC

preprint2022arXiv

Spatiotemporal 2-D Channel Coding for Very Low Latency Reliable MIMO Transmission

To fully support vertical industries, 5G and its corresponding channel coding are expected to meet requirements of different applications. However, for applications of 5G and beyond 5G (B5G) such as URLLC, the transmission latency is required to be much shorter than that in eMBB. Therefore, the resulting channel code length reduces drastically. In this case, the traditional 1-D channel coding suffers a lot from the performance degradation and fails to deliver strong reliability with very low latency. To remove this bottleneck, new channel coding scheme beyond the existing 1-D one is in urgent need. By making full use of the spacial freedom of massive MIMO systems, this paper devotes itself in proposing a spatiotemporal 2-D channel coding for very low latency reliable transmission. For a very short time-domain code length $N^{\text{time}}=16$, $64 \times 128$ MIMO system employing the proposed spatiotemporal 2-D coding scheme successfully shows more than $3$\,dB performance gain at $\text{FER}=10^{-3}$, compared to the 1-D time-domain channel coding. It is noted that the proposed coding scheme is suitable for different channel codes and enjoys high flexibility to adapt to difference scenarios. By appropriately selecting the code rate, code length, and the number of codewords in the time and space domains, the proposed coding scheme can achieve a good trade-off between the transmission latency and reliability.

preprint2022arXiv

Unified Formulation of Phase Space Mapping Approaches for Nonadiabatic Quantum Dynamics

Nonadiabatic dynamical processes are one of the most important quantum mechanical phenomena in chemical, materials, biological, and environmental molecular systems, where the coupling between different electronic states is either inherent in the molecular structure or induced by the (intense) external field. The curse of dimensionality indicates the intractable exponential scaling of calculation effort with system size and restricts the implementation of numerically exact approaches for realistic large systems. The phase space formulation of quantum mechanics offers an important theoretical framework for constructing practical approximate trajectory-based methods for quantum dynamics. This Account reviews our recent progress in phase space mapping theory: a unified framework for constructing the mapping Hamiltonian on phase space for coupled F-state systems where the renowned Meyer-Miller Hamiltonian model is a special case, a general phase space formulation of quantum mechanics for nonadiabatic systems where the electronic degrees of freedom are mapped onto constraint space and the nuclear degrees of freedom are mapped onto infinite space, and an isomorphism between the mapping phase space approach for nonadiabatic systems and that for nonequilibrium electron transport processes.

preprint2022arXiv

VPNets: Volume-preserving neural networks for learning source-free dynamics

We propose volume-preserving networks (VPNets) for learning unknown source-free dynamical systems using trajectory data. We propose three modules and combine them to obtain two network architectures, coined R-VPNet and LA-VPNet. The distinct feature of the proposed models is that they are intrinsic volume-preserving. In addition, the corresponding approximation theorems are proved, which theoretically guarantee the expressivity of the proposed VPNets to learn source-free dynamics. The effectiveness, generalization ability and structure-preserving property of the VP-Nets are demonstrated by numerical experiments.

preprint2022arXiv

Watermark Vaccine: Adversarial Attacks to Prevent Watermark Removal

As a common security tool, visible watermarking has been widely applied to protect copyrights of digital images. However, recent works have shown that visible watermarks can be removed by DNNs without damaging their host images. Such watermark-removal techniques pose a great threat to the ownership of images. Inspired by the vulnerability of DNNs on adversarial perturbations, we propose a novel defence mechanism by adversarial machine learning for good. From the perspective of the adversary, blind watermark-removal networks can be posed as our target models; then we actually optimize an imperceptible adversarial perturbation on the host images to proactively attack against watermark-removal networks, dubbed Watermark Vaccine. Specifically, two types of vaccines are proposed. Disrupting Watermark Vaccine (DWV) induces to ruin the host image along with watermark after passing through watermark-removal networks. In contrast, Inerasable Watermark Vaccine (IWV) works in another fashion of trying to keep the watermark not removed and still noticeable. Extensive experiments demonstrate the effectiveness of our DWV/IWV in preventing watermark removal, especially on various watermark removal networks.

preprint2021arXiv

CelebA-Spoof Challenge 2020 on Face Anti-Spoofing: Methods and Results

As facial interaction systems are prevalently deployed, security and reliability of these systems become a critical issue, with substantial research efforts devoted. Among them, face anti-spoofing emerges as an important area, whose objective is to identify whether a presented face is live or spoof. Recently, a large-scale face anti-spoofing dataset, CelebA-Spoof which comprised of 625,537 pictures of 10,177 subjects has been released. It is the largest face anti-spoofing dataset in terms of the numbers of the data and the subjects. This paper reports methods and results in the CelebA-Spoof Challenge 2020 on Face AntiSpoofing which employs the CelebA-Spoof dataset. The model evaluation is conducted online on the hidden test set. A total of 134 participants registered for the competition, and 19 teams made valid submissions. We will analyze the top ranked solutions and present some discussion on future work directions.

preprint2021arXiv

Enabling Fast and Universal Audio Adversarial Attack Using Generative Model

Recently, the vulnerability of DNN-based audio systems to adversarial attacks has obtained the increasing attention. However, the existing audio adversarial attacks allow the adversary to possess the entire user's audio input as well as granting sufficient time budget to generate the adversarial perturbations. These idealized assumptions, however, makes the existing audio adversarial attacks mostly impossible to be launched in a timely fashion in practice (e.g., playing unnoticeable adversarial perturbations along with user's streaming input). To overcome these limitations, in this paper we propose fast audio adversarial perturbation generator (FAPG), which uses generative model to generate adversarial perturbations for the audio input in a single forward pass, thereby drastically improving the perturbation generation speed. Built on the top of FAPG, we further propose universal audio adversarial perturbation generator (UAPG), a scheme crafting universal adversarial perturbation that can be imposed on arbitrary benign audio input to cause misclassification. Extensive experiments show that our proposed FAPG can achieve up to 167X speedup over the state-of-the-art audio adversarial attack methods. Also our proposed UAPG can generate universal adversarial perturbation that achieves much better attack performance than the state-of-the-art solutions.

preprint2021arXiv

Proposal for measuring Newtonian constant of gravitation at an exceptional point in an optomechanical system

We develop a quantum mechanical method of measuring the Newtonian constant of gravitation, G. In this method, an optomechanical system consisting of two cavities and two membrane resonators is used. The added source mass would induce the shifts of the eigenfrequencies of the supermodes. Via detecting the shifts, we can perform our measurement of G. Furthermore, our system can features exceptional point (EP) which are branch point singularities of the spectrum and eigenfunctions. In the paper, we demonstrate that operating the system at EP can enhance our measurement of G. In addition, we derive the relationship between EP enlarged eigenfrequency shift and the Newtonian constant. This work provides a way to engineer EP-assisted optomechanical devices for applications in the field of precision measurement of G

preprint2020arXiv

Adversarial Training Based Multi-Source Unsupervised Domain Adaptation for Sentiment Analysis

Multi-source unsupervised domain adaptation (MS-UDA) for sentiment analysis (SA) aims to leverage useful information in multiple source domains to help do SA in an unlabeled target domain that has no supervised information. Existing algorithms of MS-UDA either only exploit the shared features, i.e., the domain-invariant information, or based on some weak assumption in NLP, e.g., smoothness assumption. To avoid these problems, we propose two transfer learning frameworks based on the multi-source domain adaptation methodology for SA by combining the source hypotheses to derive a good target hypothesis. The key feature of the first framework is a novel Weighting Scheme based Unsupervised Domain Adaptation framework (WS-UDA), which combine the source classifiers to acquire pseudo labels for target instances directly. While the second framework is a Two-Stage Training based Unsupervised Domain Adaptation framework (2ST-UDA), which further exploits these pseudo labels to train a target private extractor. Importantly, the weights assigned to each source classifier are based on the relations between target instances and source domains, which measured by a discriminator through the adversarial training. Furthermore, through the same discriminator, we also fulfill the separation of shared features and private features. Experimental results on two SA datasets demonstrate the promising performance of our frameworks, which outperforms unsupervised state-of-the-art competitors.

preprint2020arXiv

Comprehensive Control of Metamagnetic Transition of Antiferromagnetic Mott Insulator Sr2IrO4 by in-situ Anisotropic Strain

Metamagnetism in antiferromagnets exhibits distinct critical behaviors and dynamics when invoking spin reversal and rotation. Here we show a 0.05% anisotropic strain suffices to in-situ modulate the metamagnetic critical field of the Mott insulator Sr2IrO4 by over 50%, enabling electrical switching of the transition. Resonant x-ray scattering and model simulation reveal that the transition is completely tuned from the spin-flop to spin-flip type as the strain introduces C4-symmetry-breaking magnetic anisotropy. Simultaneous transport study indicates the metamagnetic responses are reflected in the large elasto- and magnetoconductance, highlighting the active charge degree of freedom in the spin-orbit-coupled Mott state and its potential for spin-electronics.

preprint2020arXiv

Evolution of clustering structure through the momentum distributions in $^{8-10}$Be isotopes

We investigate the evolution of clustering structure through the momentum distributions in the $^{8-10}$Be isotopes. The nucleon dynamics within the inter-cluster antisymmetrization are discussed via the momentum distribution of a Brink type $α$-$α$ wave function. For the state with a small $α$-$α$ distance, we observe a significant depression with a dip structure at zero-momentum and an enhanced tail at relatively higher momentum region. In addition, we find the "cluster structure" in the intrinsic frame of momentum space, which is complementary to its significant $α$-cluster dissolution in the coordinate space because of the strong antisymmetrization. For the physical $^{8-10}$Be isotopes, the Tohsaki-Horiuchi-Schuck-R{ö}pke (THSR) wave functions are adopted. The evolution from the dilute clustering state to the compact one is demonstrated by a successive depression at the zero-momentum of nucleon distribution for the two $α$-clusters within $^{8-10}$Be isotopes. For the compact $^{10}$Be nucleus, the momentum distribution of all nucleons shows significant depression at zero-momentum with a dip structure, which is found to be contributed by both the inter-cluster antisymmetrization and the $p$-orbit occupation of the valence neutrons. This study proposes a new window for the investigations of the $α$-clustering effects via the low-momentum components of nuclei, which is expected to be extended to the heavier nuclear clustering states.

preprint2020arXiv

Gate-tunable van der Waals heterostructure for reconfigurable neural network vision sensor

Early processing of visual information takes place in the human retina. Mimicking neurobiological structures and functionalities of the retina provide a promising pathway to achieving vision sensor with highly efficient image processing. Here, we demonstrate a prototype vision sensor that operates via the gate-tunable positive and negative photoresponses of the van der Waals (vdW) vertical heterostructures. The sensor emulates not only the neurobiological functionalities of bipolar cells and photoreceptors but also the unique synaptic connectivity between bipolar cells and photoreceptors. By tuning gate voltage for each pixel, we achieve reconfigurable vision sensor for simultaneously image sensing and processing. Furthermore, our prototype vision sensor itself can be trained to classify the input images, via updating the gate voltages applied individually to each pixel in the sensor. Our work indicates that vdW vertical heterostructures offer a promising platform for the development of neural network vision sensor.

preprint2020arXiv

Gravitational waves detection with exceptional points in micro cavities

Here we propose a new gravitational waves(GWs) detector in broad frequency band, which is operated at exceptional points(EPs) in micro cavities. The detected signal is an eigenfrequency split of the mechanical modes caused by the spatial strain. Due to the complex square root topology near the EP, the splitting is greatly enhanced for sufficiently small perturbations. Compared to current strategies, it can be achieved at the room temperature and has advantages in micro device scale, wide frequency band and higher sensitivity.

preprint2020arXiv

LogiQA: A Challenge Dataset for Machine Reading Comprehension with Logical Reasoning

Machine reading is a fundamental task for testing the capability of natural language understanding, which is closely related to human cognition in many aspects. With the rising of deep learning techniques, algorithmic models rival human performances on simple QA, and thus increasingly challenging machine reading datasets have been proposed. Though various challenges such as evidence integration and commonsense knowledge have been integrated, one of the fundamental capabilities in human reading, namely logical reasoning, is not fully investigated. We build a comprehensive dataset, named LogiQA, which is sourced from expert-written questions for testing human Logical reasoning. It consists of 8,678 QA instances, covering multiple types of deductive reasoning. Results show that state-of-the-art neural models perform by far worse than human ceiling. Our dataset can also serve as a benchmark for reinvestigating logical AI under the deep learning NLP setting. The dataset is freely available at https://github.com/lgw863/LogiQA-dataset

preprint2020arXiv

Real-time, Universal, and Robust Adversarial Attacks Against Speaker Recognition Systems

As the popularity of voice user interface (VUI) exploded in recent years, speaker recognition system has emerged as an important medium of identifying a speaker in many security-required applications and services. In this paper, we propose the first real-time, universal, and robust adversarial attack against the state-of-the-art deep neural network (DNN) based speaker recognition system. Through adding an audio-agnostic universal perturbation on arbitrary enrolled speaker's voice input, the DNN-based speaker recognition system would identify the speaker as any target (i.e., adversary-desired) speaker label. In addition, we improve the robustness of our attack by modeling the sound distortions caused by the physical over-the-air propagation through estimating room impulse response (RIR). Experiment using a public dataset of 109 English speakers demonstrates the effectiveness and robustness of our proposed attack with a high attack success rate of over 90%. The attack launching time also achieves a 100X speedup over contemporary non-universal attacks.

preprint2020arXiv

Review and Examination of Input Feature Preparation Methods and Machine Learning Models for Turbulence Modeling

Model extrapolation to unseen flow is one of the biggest challenges facing data-driven turbulence modeling, especially for models with high dimensional inputs that involve many flow features. In this study we review previous efforts on data-driven Reynolds-Averaged Naiver Stokes (RANS) turbulence modeling and model extrapolation, with main focus on the popular methods being used in the field of transfer learning. Several potential metrics to measure the dissimilarity between training flows and testing flows are examined. Different Machine Learning (ML) models are compared to understand how the capacity or complexity of the model affects its behavior in the face of dataset shift. Data preprocessing schemes which are robust to covariate shift, like normalization, transformation, and importance re-weighted likelihood, are studied to understand whether it is possible to find projections of the data that attenuate the differences in the training and test distributions while preserving predictability. Three metrics are proposed to assess the dissimilarity between training/testing dataset. To attenuate the dissimilarity, a distribution matching framework is used to align the statistics of the distributions. These modifications also allow the regression tasks to have better accuracy in forecasting under-represented extreme values of the target variable. These findings are useful for future ML based turbulence models to evaluate their model predictability and provide guidance to systematically generate diversified high-fidelity simulation database.

preprint2020arXiv

Strain-modulated Slater-Mott crossover of pseudospin-half square-lattice in (SrIrO3)1/ (SrTiO3)1 superlattices

We report on the epitaxial strain-driven electronic and antiferromagnetic modulations of a pseudospin-half square lattice realized in superlattices of (SrIrO3)1/(SrTiO3)1. With increasing compressive strain, we find the low-temperature insulating behavior to be strongly suppressed with a corresponding systematic reduction of both the Neel temperature and the staggered moment. However, despite such a suppression, the system remains weakly insulating above the Neel transition. The emergence of metallicity is observed under large compressive strain but only at temperatures far above the Néel transition. These behaviors are characteristics of the Slater-Mott crossover regime, providing a unique experimental model system of the spin-half Hubbard Hamiltonian with a tunable intermediate coupling strength.

preprint2019arXiv

Drastic suppression of superconducting $T_{c}$ by anisotropic strain near a nematic quantum critical point

High temperature superconductivity emerges in the vicinity of competing strongly correlated phases. In the iron-based superconductor $Ba(Fe_{1-x}Co_{x})_{2}As_{2}$, the superconducting state shares the composition-temperature phase diagram with an electronic nematic phase and an antiferromagnetic phase that break the crystalline rotational symmetry. Symmetry considerations suggest that anisotropic strain can enhance these competing phases and thus suppress the superconductivity. Here we study the effect of anisotropic strain on the superconducting transition in single crystals of $Ba(Fe_{1-x}Co_{x})_{2}As_{2}$ through electrical transport, magnetic susceptibility, and x-ray diffraction measurements. We find that in the underdoped and near-optimally doped regions of the phase diagram, the superconducting critical temperature is rapidly suppressed by both compressive and tensile stress, and in the underdoped case this suppression is enough to induce a strain-tuned superconductor to metal quantum phase transition.

preprint2019arXiv

Epitaxial growth and antiferromagnetism of Sn-substituted perovskite iridate SrIr$_{0.8}$Sn$_{0.2}$O$_3$

5d iridates have shown vast emergent phenomena due to a strong interplay among its lattice, charge and spin degrees of freedom, because of which the potential in spintronic application of the thin-film form is highly leveraged. Here we have epitaxially stabilized perovskite SrIr$_{0.8}$Sn$_{0.2}$O$_3$ on [001] SrTiO$_3$ substrates through pulsed laser deposition and systematically characterized the structural, electronic and magnetic properties. Physical properties measurements unravel an insulating ground state with a weak ferromagnetism in the compressively strained epitaxial film. The octahedral rotation pattern is identified by synchrotron x-ray diffraction, resolving a mix of $a^+b^-c^-$ and $a^-b^+c^-$ domains. X-ray magnetic resonant scattering directly demonstrates a G-type antiferromagnetic structure of the magnetic order and the spin canting nature of the weak ferromagnetism.

preprint2017arXiv

Universal Scaling in Intrinsic Resistivity of Two-Dimensional Metal Borophene

Two-dimensional boron sheets (borophenes) have been successfully synthesized in experiments and are expected to exhibit intriguing transport properties such as the emergence of superconductivity and Dirac Fermions. However, quantitative understanding of intrinsic electrical transport of borophene has not been achieved. Here, we report a comprehensive first-principles study on electron-phonon driven intrinsic electrical resistivity (\r{ho}) of emerging borophene structures. We find that the resistivity is highly dependent on the atomic structures and electron density of borophene. Low-temperature resistivity of borophene \r{ho} exhibits a universal scaling behavior, which increases rapidly with temperature T (\r{ho}~T^4), while \r{ho} increases linearly for a large temperature window T > 100 K. It is observed that this universal behavior of intrinsic resistivity is well described by Bloch-Grünesisen model. Different from graphene and conventional three-dimensional metals, the intrinsic resistivity of borophenes can be easily tuned by adjusting carrier densities while the Bloch-Grünesisen temperature is nearly fixed at ~100 K. Our work suggests monolayer boron can serve as an intriguing platform for realizing high-tunable two-dimensional electronic devices.

preprint2016arXiv

Atomic-scale control of magnetic anisotropy via novel spin-orbit coupling effect in La2/3Sr1/3MnO3/SrIrO3 superlattices

Magnetic anisotropy (MA) is one of the most important material properties for modern spintronic devices. Conventional manipulation of the intrinsic MA, i.e. magnetocrystalline anisotropy (MCA), typically depends upon crystal symmetry. Extrinsic control over the MA is usually achieved by introducing shape anisotropy or exchange bias from another magnetically ordered material. Here we demonstrate a pathway to manipulate MA of 3d transition metal oxides (TMOs) by digitally inserting non-magnetic 5d TMOs with pronounced spin-orbit coupling (SOC). High quality superlattices comprised of ferromagnetic La2/3Sr1/3MnO3 (LSMO) and paramagnetic SrIrO3 (SIO) are synthesized with the precise control of thickness at atomic scale. Magnetic easy axis reorientation is observed by controlling the dimensionality of SIO, mediated through the emergence of a novel spin-orbit state within the nominally paramagnetic SIO.

preprint2016arXiv

Context-aware System Service Call-oriented Symbolic Execution of Android Framework with Application to Exploit Generation

Android Framework is a layer of software that exists in every Android system managing resources of all Android apps. A vulnerability in Android Framework can lead to severe hacks, such as destroying user data and leaking private information. With tens of millions of Android devices unpatched due to Android fragmentation, vulnerabilities in Android Framework certainly attract attackers to exploit them. So far, enormous manual effort is needed to craft such exploits. To our knowledge, no research has been done on automatic generation of exploits that take advantage of Android Framework vulnerabilities. We make a first step towards this goal by applying symbolic execution of Android Framework to finding bugs and generating exploits. Several challenges have been raised by the task. (1) The information of an app flows to Android Framework in multiple intricate steps, making it difficult to identify symbolic inputs. (2) Android Framework has a complex initialization phase, which exacerbates the state space explosion problem. (3) A straightforward design that builds the symbolic executor as a layer inside the Android system will not work well: not only does the implementation have to ensure the compatibility with the Android system, but it needs to be maintained whenever Android gets updated. We present novel ideas and techniques to resolve the challenges, and have built the first system for symbolic execution of Android Framework. It fundamentally changes the state of the art in exploit generation on the Android system, and has been applied to constructing new techniques for finding vulnerabilities.

preprint2016arXiv

Emerging magnetism and anomalous Hall effect in iridate-manganite heterostructures

Strong Coulomb repulsion and spin-orbit coupling are known to give rise to exotic physical phenomena in transition metal oxides. Initial attempts to investigate systems where both of these fundamental interactions are comparably strong, such as 3d and 5d complex oxide superlattices, have revealed properties that only slightly differ from the bulk ones of the constituent materials. Here, we observe that the interfacial coupling between the 3d antiferromagnetic insulator SrMnO3 and the 5d paramagnetic metal SrIrO3 is enormously strong, yielding an anomalous Hall response as the result of charge transfer driven interfacial ferromagnetism. These findings show that low dimensional spin-orbit entangled 3d-5d interfaces provide an avenue to uncover technologically relevant physical phenomena unattainable in bulk materials.

preprint2016arXiv

Explicit high-order non-canonical symplectic particle-in-cell algorithms for Vlasov-Maxwell systems

Explicit high-order non-canonical symplectic particle-in-cell algorithms for classical particle-field systems governed by the Vlasov-Maxwell equations are developed. The algorithm conserves a discrete non-canonical symplectic structure derived from the Lagrangian of the particle-field system, which is naturally discrete in particles. The electromagnetic field is spatially-discretized using the method of discrete exterior calculus with high-order interpolating differential forms for a cubic grid. The resulting time-domain Lagrangian assumes a non-canonical symplectic structure. It is also gauge invariant and conserves charge. The system is then solved using a splitting method discovered by He et al., which produces five exactly-soluable sub-systems, and high-order structure- preserving algorithms follow by combinations. The explicit, high-order, and conservative nature of the algorithms is especially suitable for long-term simulations of particle-field systems with extremely large number of degrees of freedom on massively parallel supercomputers. The algorithms have been tested and verified by the two physics problems, i.e., the nonlinear Landau damping and the electron Bernstein wave.

preprint2016arXiv

Explicit high-order noncanonical symplectic algorithms for ideal two-fluid systems

An explicit high-order noncanonical symplectic algorithm for ideal two-fluid systems is developed. The fluid is discretized as particles in the Lagrangian description, while the electromagnetic fields and internal energy are treated as discrete differential form fields on a fixed mesh. With the assistance of Whitney interpolating forms, this scheme preserves the gauge symmetry of the electromagnetic field, and the pressure field is naturally derived from the discrete internal energy. The whole system is solved using the Hamiltonian splitting method discovered by He et al., which was been successfully adopted in constructing symplectic particle-in-cell schemes. Because of its structure preserving and explicit nature, this algorithm is especially suitable for large-scale simulations for physics problems that are multi-scale and require long-term fidelity and accuracy. The algorithm is verified via two tests: studies of the dispersion relation of waves in a two-fluid plasma system and the oscillating two-stream instability.

preprint2016arXiv

Explicit symplectic algorithms based on generating functions for charged particle dynamics

Dynamics of a charged particle in the canonical coordinates is a Hamiltonian system, and the well-known symplectic algorithm has been regarded as the de facto method for numerical integration of Hamiltonian systems due to its long-term accuracy and fidelity. For long-term simulations with high efficiency, explicit symplectic algorithms are desirable. However, it is widely accepted that explicit symplectic algorithms are only available for sum-separable Hamiltonians, and that this restriction severely limits the application of explicit symplectic algorithms to charged particle dynamics. To overcome this difficulty, we combine the familiar sum-split method and a generating function method to construct second and third order explicit symplectic algorithms for dynamics of charged particle. The generating function method is designed to generate explicit symplectic algorithms for product-separable Hamiltonian with form of $H(\mathbf{p},\mathbf{q})=\mathbf{p}_{i}f(\mathbf{q})$ or $H(\mathbf{p},\mathbf{q})=\mathbf{q}_{i}f(\mathbf{p})$. Applied to the simulations of charged particle dynamics, the explicit symplectic algorithms based on generating functions demonstrate superiorities in conservation and efficiency.

preprint2016arXiv

First-principles study of pyroelectricity in GaN and ZnO

First-principles calculations are made for the primary pyroelectric coefficients of wurtzite GaN and ZnO. The pyroelectricity is attributed to the quasiharmonic thermal shifts of internal strains (internal displacements of cations and anions carrying their Born effective charges). The primary (zero-external-strain) pyroelectricity dominates at low temperatures, while the secondary pyroelectricity (the correction from external thermal strains) becomes comparable with the primary pyroelectricity at high temperatures. Contributions from the acoustic and the optical phonon modes to the primary pyroelectric coefficient are only moderately well described by the corresponding Debye function and Einstein function respectively.

preprint2016arXiv

Hamiltonian particle-in-cell methods for Vlasov-Maxwell equations

In this paper, we develop Hamiltonian particle-in-cell methods for Vlasov-Maxwell equations by applying conforming finite element methods in space and splitting methods in time. For the spatial discretisation, the criteria for choosing finite element spaces are presented such that the semi-discrete system possesses a discrete non-canonical Poisson structure. We apply a Hamiltonian splitting method to the semi-discrete system in time, then the resulting algorithm is Poisson preserving and explicit. The conservative properties of the algorithm guarantee the efficient and accurate numerical simulation of the Vlasov-Maxwell equations over long-time.

preprint2016arXiv

High order volume-preserving algorithms for relativistic charged particles in general electromagnetic fields

We construct high order symmetric volume-preserving methods for the relativistic dynamics of a charged particle by the splitting technique with processing. Via expanding the phase space to include time $t$, we give a more general construction of volume-preserving methods that can be applied to systems with time-dependent electromagnetic fields. The newly derived methods provide numerical solutions with good accuracy and conservative properties over long time of simulation. Furthermore, because of the use of processing technique the high order methods are explicit, and cost less than the methods derived from standard compositions, thus are more efficient. The results are verified by the numerical experiments. Linear stability analysis of the methods show that the high order processed method allows larger time step size during integration.

preprint2016arXiv

Largest Particle Simulations Downgrade the Runaway Electron Risk for ITER

Fusion energy will be the ultimate clean energy source for mankind. One of the most visible concerns of the future fusion device is the threat of deleterious runaway electrons (REs) produced during unexpected disruptions of the fusion plasma. Both efficient long-term algorithms and super-large scale computing power are necessary to reveal the complex dynamics of REs in a realistic fusion reactor. In the present study, we deploy the world's fastest supercomputer, Sunway TaihuLight, and the newly developed relativistic volume-preserving algorithm to carry out long-term particle simulations of 10^7 sampled REs in 6D phase space, which involves simulation scale of 10^18 particle-steps, the largest ever achieved in fusion research. Our simulations show that in a realistic fusion reactor, the concern of REs is not as serious as previously thought. Specifically, REs are confined much better than previously predicted and the maximum average energy is in the range of 150MeV, less than half of previous estimate.

preprint2016arXiv

Multi-scale Full-orbit Analysis on Phase-space Behavior of Runaway Electrons in Tokamak Fields with Synchrotron Radiation

In this paper, the secular full-orbit simulations of runaway electrons with synchrotron radiation in tokamak fields are carried out using a relativistic volume-preserving algorithm. Detailed phase-space behaviors of runaway electrons are investigated in different dynamical timescales spanning 11 orders. When looking into the small timescale, i.e., the characteristic timescale imposed by Lorentz force, the severely deformed helical trajectory of energetic runaway electron is witnessed. A qualitative analysis of the neoclassical scattering, a kind of collisionless pitch-angle scattering phenomena, is provided when considering the coupling between the rotation of momentum vector and the background magnetic field. In large timescale up to one second, it is found that the initial condition of runaway electrons in phase space globally influences the pitch-angle scattering, the momentum evolution, and the loss-gain ratio of runaway energy evidently. However, the initial value has little impact on the synchrotron energy limit. It is also discovered that the parameters of tokamak device, such as the toroidal magnetic field, the loop voltage, the safety factor profile, and the major radius, can modify the synchrotron energy limit as well as the strength of neoclassical scattering. The maximum runaway energy is also proved to be lower than the synchrotron limit when the magnetic field ripple is considered.

preprint2016arXiv

On the structure of the two-stream instability -- complex G-Hamiltonian structure and Krein collisions between positive- and negative-action modes

The two-stream instability is probably the most important elementary example of collective instabilities in plasma physics and beam-plasma systems. For a warm plasma with two charged particle species based on a 1D warm-fluid model, the instability diagram of the two-stream instability exhibits an interesting band structure that has not been explained. We show that the band structure for this instability is the consequence of the Hamiltonian nature of the warm two-fluid system. Interestingly, the Hamiltonian nature manifests as a complex G-Hamiltonian structure in wave-number space, which directly determines the instability diagram. Specifically, it is shown that the boundaries between the stable and unstable regions are locations for Krein collisions between eigenmodes with different Krein signatures. In terms of physics, this rigorously implies that the system is destabilized when a positive-action mode resonates with a negative-action mode, and that this is the only mechanism by which the system can be destabilized. It is anticipated that this physical mechanism of destabilization is valid for other collective instabilities in conservative systems in plasma physics, accelerator physics, and fluid dynamics systems, which admit infinite-dimensional Hamiltonian structures.

preprint2016arXiv

Prototype Active Silicon Sensor in 150 nm HR-CMOS Technology for ATLAS Inner Detector Upgrade

The LHC Phase-II upgrade will lead to a significant increase in luminosity, which in turn will bring new challenges for the operation of inner tracking detectors. A possible solution is to use active silicon sensors, taking advantage of commercial CMOS technologies. Currently ATLAS R&D programme is qualifying a few commercial technologies in terms of suitability for this task. In this paper a prototype designed in one of them (LFoundry 150 nm process) will be discussed. The chip architecture will be described, including different pixel types incorporated into the design, followed by simulation and measurement results.

preprint2016arXiv

Strain-induced nonsymmorphic symmetry breaking and removal of Dirac semimetallic nodal line in an orthoperovskite iridate

By using a combination of heteroepitaxial growth, structure refinement based on synchrotron x-ray diffraction and first-principles calculations, we show that the symmetry-protected Dirac line nodes in the topological semimetallic perovskite SrIrO3 can be lifted simply by applying epitaxial constraints. In particular, the Dirac gap opens without breaking the Pbnm mirror symmetry. In virtue of a symmetry-breaking analysis, we demonstrate that the original symmetry protection is related to the n-glide operation, which can be selectively broken by different heteroepitaxial structures. This symmetry protection renders the nodal line a nonsymmorphic Dirac semimetallic state. The results highlight the vital role of crystal symmetry in spin-orbit-coupled correlated oxides and provide a foundation for experimental realization of topological insulators in iridate-based heterostructures.

preprint2016arXiv

Superconductor to Mott insulator transition in YBa$_2$Cu$_3$O$_7$/LaCaMnO$_3$ heterostructures

The superconductor-to-insulator transition (SIT) induced by means such as external magnetic fields, disorder or spatial confinement is a vivid illustration of a quantum phase transition dramatically affecting the superconducting order parameter. In pursuit of a new realization of the SIT by interfacial charge transfer, we developed extremely thin superlattices composed of high $T_c$ superconductor YBa$_2$Cu$_3$O$_7$ (YBCO) and colossal magnetoresistance ferromagnet La$_{0.67}$Ca$_{0.33}$MnO$_3$ (LCMO). By using linearly polarized resonant X-ray absorption spectroscopy and magnetic circular dichroism, combined with hard X-ray photoelectron spectroscopy, we derived a complete picture of the interfacial carrier doping in cuprate and manganite atomic layers, leading to the transition from superconducting to an unusual Mott insulating state emerging with the increase of LCMO layer thickness. In addition, contrary to the common perception that only transition metal ions may response to the charge transfer process, we found that charge is also actively compensated by rare-earth and alkaline-earth metal ions of the interface. Such deterministic control of $T_c$ by pure electronic doping without any hindering effects of chemical substitution is another promising route to disentangle the role of disorder on the pseudo-gap and charge density wave phases of underdoped cuprates.

preprint2016arXiv

Theoretical study on nuclear structure by the multiple Coulomb scattering and magnetic scattering of relativistic electrons

Electron scattering is an effective method to study the nuclear structure. For the odd-$A$ nuclei with proton holes in the outmost orbits, we investigate the contributions of proton holes to the nuclear quadrupole moments $Q$ and magnetic moments $μ$ by the multiple Coulomb scattering and magnetic scattering. The deformed nuclear charge densities are constructed by the relativistic mean-field (RMF) models. Comparing the theoretical Coulomb and magnetic form factors with the experimental data, the nuclear quadrupole moments $Q$ and nuclear magnetic moments $μ$ are investigated. From the electron scattering, the wave functions of the proton holes of odd-$A$ nuclei can be tested, which can also reflect the validity of the nuclear structure model.

preprint2016arXiv

Towards Fairness of Cryptocurrency Payments

Motivated by the great success and adoption of Bitcoin, a number of cryptocurrencies such as Litecoin, Dogecoin, and Ethereum are becoming increasingly popular. Although existing blockchain-based cryptocurrency schemes can ensure reasonable security for transactions, they do not consider any notion of fairness. Fair exchange allows two players to exchange digital "items", such as digital signatures, over insecure networks fairly, so that either each player gets the other's item, or neither player does. Given that blockchain participants typically do not trust each other, enabling fairness in existing cryptocurrencies is an essential but insufficiently explored problem. In this paper, we explore the solution space for enabling the fair exchange of a cryptocurrency payment for a receipt. We identify the timeliness of an exchange as an important property especially when one of the parties involved in the exchange is resource-constrained. We introduce the notion of strong timeliness for a fair exchange protocol and propose two fair payment-for-receipt protocol instantiations that leverage functionality of the blockchain to achieve strong timeliness. We implement both and compare their security and efficiency.

preprint2016arXiv

Ultrafast energy and momentum resolved dynamics of magnetic correlations in photo-doped Mott insulator Sr$_2$IrO$_4$

Measuring how the magnetic correlations throughout the Brillouin zone evolve in a Mott insulator as charges are introduced dramatically improved our understanding of the pseudogap, non-Fermi liquids and high $T_C$ superconductivity. Recently, photoexcitation has been used to induce similarly exotic states transiently. However, understanding how these states emerge has been limited because of a lack of available probes of magnetic correlations in the time domain, which hinders further investigation of how light can be used to control the properties of solids. Here we implement magnetic resonant inelastic X-ray scattering at a free electron laser, and directly determine the magnetization dynamics after photo-doping the Mott insulator Sr$_2$IrO$_4$. We find that the non-equilibrium state 2~ps after the excitation has strongly suppressed long-range magnetic order, but hosts photo-carriers that induce strong, non-thermal magnetic correlations. The magnetism recovers its two-dimensional (2D) in-plane Néel correlations on a timescale of a few ps, while the three-dimensional (3D) long-range magnetic order restores over a far longer, fluence-dependent timescale of a few hundred ps. The dramatic difference in these two timescales, implies that characterizing the dimensionality of magnetic correlations will be vital in our efforts to understand ultrafast magnetic dynamics.

preprint2015arXiv

180 degree Ferroelectric Stripe Nanodomains in BiFeO3 Thin Films

There is growing evidence that domain walls in ferroics can possess emergent properties that are absent in bulk materials. For example, 180 domain walls in the ferroelectric-antiferromagnetic BiFeO3 are particularly interesting because they have been predicted to possess a range of intriguing behaviors; including electronic conduction and enhanced magnetization. To date, however, ordered arrays of such domain structures have not been reported. Here, we report the observation of 180 stripe nanodomains in (110)-oriented BiFeO3 thin films grown on orthorhombic GdScO3 (010)O substrates, and their impact on exchange coupling to metallic ferromagnets. Nanoscale ferroelectric 180 stripe domains with {112 } domain walls were observed in films < 32 nm thick to compensate for large depolarization fields. With increasing film thickness, we observe a domain structure crossover from the depolarization field-driven 180 stripe nanodomains to 71 domains determined by the elastic energy. Interestingly, these 180 domain walls (which are typically cylindrical or meandering in nature due to a lack of strong anisotropy associated with the energy of such walls) are found to be highly-ordered. Additional studies of Co0.9Fe0.1/BiFeO3 heterostructures reveal exchange bias and exchange enhancement in heterostructures based-on BiFeO3 with 180 domain walls and an absence of exchange bias in heterostructures based-on BiFeO3 with 71 domain walls; suggesting that the 180 domain walls could be the possible source for pinned uncompensated spins that give rise to exchange bias. This is further confirmed by X-ray circular magnetic dichroism studies, which demonstrate that films with predominantly 180 domain walls have larger magnetization than those with primarily 71 domain walls. Our results could be useful to extract the structure of domain walls and to explore domain wall functionalities in BiFeO3.

preprint2015arXiv

Application of bond valence method in the non-isovalent semiconductor alloy (GaN)$_{1-x}$(ZnO)$_x$

This paper studies the bond valence method (BVM) and its application in the non-isovalent semiconductor alloy (GaN)$_{\rm{1-x}}$(ZnO)$_{\rm{x}}$. Particular attention is paid to the role of short-range order (SRO). A physical interpretation based on atomic orbital interaction is proposed and examined by density-functional theory (DFT) calculations. Combining BVM with Monte-Carlo simulations and a DFT-based cluster expansion model, bond-length distributions and bond-angle variations are predicted. The correlation between bond valence and bond stiffness is also revealed. Finally the concept of bond valence is extended into the modelling of an atomistic potential.

preprint2015arXiv

Canonical symplectic particle-in-cell method for long-term large-scale simulations of the Vlasov-Maxwell system

Particle-in-Cell (PIC) simulation is the most important numerical tool in plasma physics. However, its long-term accuracy has not been established. To overcome this difficulty, we developed a canonical symplectic PIC method for the Vlasov-Maxwell system by discretizing its canonical Poisson bracket. A fast local algorithm to solve the symplectic implicit time advance is discovered without root searching or global matrix inversion, enabling applications of the proposed method to very large-scale plasma simulations with many, e.g., $10^{9}$, degrees of freedom. The long-term accuracy and fidelity of the algorithm enables us to numerically confirm Mouhot and Villani's theory and conjecture on nonlinear Landau damping over several orders of magnitude using the PIC method, and to calculate the nonlinear evolution of the reflectivity during the mode conversion process from extraordinary waves to Bernstein waves.

preprint2015arXiv

Comment on "Hamiltonian splitting for the Vlasov-Maxwell equations"

The paper [1] by Crouseilles, Einkemmer, and Faou used an incorrect Poisson bracket for the Vlasov-Maxwell equations. If the correct Poisson bracket is used, the solution of one of the subsystems cannot be computed exactly in general. As a result, one cannot construct a symplectic scheme for the Vlasov-Maxwell equations using the splitting Hamiltonian method proposed in Ref [1].

preprint2015arXiv

Explicit non-canonical symplectic algorithms for charged particle dynamics

We study the non-canonical symplectic structure, or K-symplectic structure inherited by the charged particle dynamics. Based on the splitting technique, we construct non-canonical symplectic methods which is explicit and stable for the long-term simulation. The key point of splitting is to decompose the Hamiltonian as four parts, so that the resulting four subsystems have the same structure and can be solved exactly. This guarantees the K-symplectic preservation of the numerical methods constructed by composing the exact solutions of the subsystems. The error convergency of numerical solutions is analyzed by means of the Darboux transformation. The numerical experiment display the long-term stability and efficiency for these methods.

preprint2015arXiv

Giant reversible nanoscale piezoresistance at room temperature in Sr2IrO4 thin films

Layered iridates have been the subject of intense scrutiny on account of their unusually strong spin-orbit coupling, which opens up a narrow gap in a material that would otherwise be a metal. This insulating state is very sensitive to external perturbations. Here, we show that vertical compression at the nanoscale, delivered using the tip of a standard scanning probe microscope, is capable of inducing a five orders of magnitude change in the room temperature resistivity of Sr2IrO4. The extreme sensitivity of the electronic structure to anisotropic deformations opens up a new angle of interest on this material, and the giant and fully reversible perpendicular piezoresistance makes iridates a promising material for room temperature piezotronic devices.

preprint2015arXiv

Hamiltonian integration methods for Vlasov-Maxwell equations

Hamiltonian integration methods for the Vlasov-Maxwell equations are developed by a Hamiltonian splitting technique. The Hamiltonian functional is split into five parts, i.e., the electrical energy, the magnetic energy, and the kinetic energy in three Cartesian components. Each of the subsystems is a Hamiltonian system with respect to the Morrison-Marsden-Weinstein Poisson bracket and can be solved exactly. Compositions of the exact solutions yield Poisson structure preserving, or Hamiltonian, integration methods for the Vlasov-Maxwell equations, which have superior long-term fidelity and accuracy.

preprint2015arXiv

Integrating Heterogeneous Information via Flexible Regularization Framework for Recommendation

Recently, there is a surge of social recommendation, which leverages social relations among users to improve recommendation performance. However, in many applications, social relations are absent or very sparse. Meanwhile, the attribute information of users or items may be rich. It is a big challenge to exploit these attribute information for the improvement of recommendation performance. In this paper, we organize objects and relations in recommendation system as a heterogeneous information network, and introduce meta path based similarity measure to evaluate the similarity of users or items. Furthermore, a matrix factorization based dual regularization framework SimMF is proposed to flexibly integrate different types of information through adopting the similarity of users and items as regularization on latent factors of users and items. Extensive experiments not only validate the effectiveness of SimMF but also reveal some interesting findings. We find that attribute information of users and items can significantly improve recommendation accuracy, and their contribution seems more important than that of social relations. The experiments also reveal that different regularization models have obviously different impact on users and items.

preprint2015arXiv

Local existence of solution to free boundary value problem for compressible Navier-Stokes equations

This paper is concerned with the free boundary value problem for multi-dimensional Navier-Stokes equations with density-dependent viscosity where the flow density vanishes continuously across the free boundary. A local (in time) existence of weak solution is established, in particular, the density is positive and the solution is regular away from the free boundary.

preprint2015arXiv

Neoclassical Pitch-Angle Scattering of Runaway Electrons

It is discovered that the tokamak field geometry generates a pitch-angle scattering effect for runaway electrons. This neoclassical pitch-angle scattering is much stronger than the collisional scattering and invalidates the gyro-center model for runaway electrons. As a result, the energy limit of runaway electrons is found to be larger than the prediction of the gyro-center model and to depend heavily on the background magnetic field.

preprint2015arXiv

Novel electronic behavior driving NdNiO3 metal-insulator transition

We present evidence that the metal-insulator transition (MIT) in a tensile strained NdNiO3 (NNO) film is facilitated by a redistribution of electronic density and neither requires Ni charge disproportionation nor symmetry change [1, 2]. Given epitaxial tensile strain in thin NNO films induces preferential occupancy of the $e_g$ $d_{x^2-y^2}$ orbital ($s_{3z^2-r^2}$) we propose the larger transfer integral of this orbital state with the O 2p mediates a redistribution of electronic density from the Ni atom. A decrease in Ni $d_{x^2-y^2}$ orbital occupation is directly observed by resonant inelastic x-ray scattering below the MIT temperature. Furthermore, an increase in Nd charge occupancy is measured by x-ray absorption at the Nd L3 edge. Both spin-orbit coupling and crystal field effects combine to break the degeneracy of the Nd 5d states shifting the energy of the Nd $e_g$ $d_{x^2-y^2}$ orbital towards the Fermi level allowing the A site to become an active acceptor during the MI transition. This work identifies the relocation of electrons from the Ni 3d to the Nd 5d orbitals across the MIT. We propose the insulating gap opens between the Ni 3d and O 2p resulting from Ni 3d electron localization mediated by charge loss. The transition seems neither purely Mott-Hubbard nor simple charge transfer.

preprint2015arXiv

Response to Comment (arXiv:1506.02787v1) on Selective Interface Control of Order Parameters in Complex Oxides

In response to Lu et al, (arXiv:1506.02787v1), here we present a detailed writeup concerning the questions raised in their comment on our eprint (arXiv:1505.07451). The key question raised by Lu et al was if the bulk-like charge ordered state becomes indetectable with resonant scattering due to ultrathin film thickness. In this reply, we first detail the relation of our work to past work on the same compound by Staub et al to demonstrate that the presented data are indeed sufficient to support our claims of no charge order on ultra thin films of NdNiO3 (NNO) on NdGaO3 (NGO). Further, we demonstrate that if a well defined charge ordered phase exists in ultra thin films, it is indeed resolvable such as that in EuNiO3 (ENO).

preprint2015arXiv

Room-temperature antiferromagnetic memory resistor

The bistability of ordered spin states in ferromagnets (FMs) provides the magnetic memory functionality. Traditionally, the macroscopic moment of ordered spins in FMs is utilized to write information on magnetic media by a weak external magnetic field, and the FM stray field is used for reading. However, the latest generation of magnetic random access memories demonstrates a new efficient approach in which magnetic fields are replaced by electrical means for reading and writing. This concept may eventually leave the sensitivity of FMs to magnetic fields as a mere weakness for retention and the FM stray fields as a mere obstacle for high-density memory integration. In this paper we report a room-temperature bistable antiferromagnetic (AFM) memory which produces negligible stray fields and is inert in strong magnetic fields. We use a resistor made of an FeRh AFM whose transition to a FM order 100 degrees above room-temperature, allows us to magnetically set different collective directions of Fe moments. Upon cooling to room-temperature, the AFM order sets in with the direction the AFM moments pre-determined by the field and moment direction in the high temperature FM state. For electrical reading, we use an antiferromagnetic analogue of the anisotropic magnetoresistance (AMR). We report microscopic theory modeling which confirms that this archetypical spintronic effect discovered more than 150 years ago in FMs, can be equally present in AFMs. Our work demonstrates the feasibility to realize room-temperature spintronic memories with AFMs which greatly expands the magnetic materials base for these devices and offers properties which are unparalleled in FMs.

preprint2015arXiv

Selective Interface Control of Order Parameters in Complex Oxides

In complex materials observed electronic phases and transitions between them often involves coupling between many degrees of freedom whose entanglement convolutes understanding of the instigating mechanism. Metal-insulator transitions are one such problem where coupling to the structural, orbital, charge, and magnetic order parameters frequently obscures the underlying physics. Here, we demonstrate a way to unravel this conundrum by heterostructuring a prototypical multi-ordered complex oxide NdNiO3 in ultra thin geometry, which preserves the metal-to-insulator transition and bulk-like magnetic order parameter, but entirely suppresses the symmetry lowering and charge order parameter. These findings illustrate the utility of heterointerfaces as a powerful method for removing competing order parameters to gain greater insight into the nature of the transition, here revealing that the magnetic order generates the transition independently, leading to a purely electronic Mott metal-insulator transition.

preprint2015arXiv

Special Quasi-ordered Structures: role of short-range order in the semiconductor alloy (GaN)$_{1-x}$(ZnO)$_x$

This paper studies short-range order (SRO) in the semiconductor alloy (GaN)$_{1-x}$(ZnO)$_x$. Monte Carlo simulations performed on a density functional theory (DFT)-based cluster expansion model show that the heterovalent alloys exhibit strong SRO because of the energetic preference for the valence-matched nearest-neighbor Ga-N and Zn-O pairs. To represent the SRO-related structural correlations, we introduce the concept of Special Quasi-ordered Structure (SQoS). Subsequent DFT calculations reveal dramatic influence of SRO on the atomic, electronic and vibrational properties of the (GaN)$_{1-x}$(ZnO)$_x$ alloy. Due to the enhanced statistical presence of the energetically unfavored Zn-N bonds with the strong Zn3$d$-N2$p$ repulsion, the disordered alloys exhibit much larger lattice bowing and band-gap reduction than those of the short-range ordered alloys. Inclusion of lattice vibrations stabilizes the disordered alloy.

preprint2015arXiv

Temperature and composition dependence of the band gaps of Ga$_{1-x}$In$_x$N alloy: a first-principles study based on the virtual crystal approximation

We report on the structural, electronic and vibrational properties of the Ga$_{1-x}$In$_x$N alloy using virtual crystal approximation (VCA) from first-principles. A band gap bowing parameter of 3.85 eV is obtained with the TB09 functional. Phonon density of states shifts to lower frequency as the In content is increased. However, VCA ignores disorder effect and is therefore unable to describe the broadening of the phonon spectra upon alloying. The role of electron-phonon interaction in the temperature dependence of the band gap is also studied for GaN, InN and their alloy Ga$_{1-x}$In$_x$N. The calculated zero-point motion renormalization and the fitted Varshni parameter over the entire composition range are discussed.

preprint2015arXiv

The Eleventh and Twelfth Data Releases of the Sloan Digital Sky Survey: Final Data from SDSS-III

The third generation of the Sloan Digital Sky Survey (SDSS-III) took data from 2008 to 2014 using the original SDSS wide-field imager, the original and an upgraded multi-object fiber-fed optical spectrograph, a new near-infrared high-resolution spectrograph, and a novel optical interferometer. All the data from SDSS-III are now made public. In particular, this paper describes Data Release 11 (DR11) including all data acquired through 2013 July, and Data Release 12 (DR12) adding data acquired through 2014 July (including all data included in previous data releases), marking the end of SDSS-III observing. Relative to our previous public release (DR10), DR12 adds one million new spectra of galaxies and quasars from the Baryon Oscillation Spectroscopic Survey (BOSS) over an additional 3000 sq. deg of sky, more than triples the number of H-band spectra of stars as part of the Apache Point Observatory (APO) Galactic Evolution Experiment (APOGEE), and includes repeated accurate radial velocity measurements of 5500 stars from the Multi-Object APO Radial Velocity Exoplanet Large-area Survey (MARVELS). The APOGEE outputs now include measured abundances of 15 different elements for each star. In total, SDSS-III added 2350 sq. deg of ugriz imaging; 155,520 spectra of 138,099 stars as part of the Sloan Exploration of Galactic Understanding and Evolution 2 (SEGUE-2) survey; 2,497,484 BOSS spectra of 1,372,737 galaxies, 294,512 quasars, and 247,216 stars over 9376 sq. deg; 618,080 APOGEE spectra of 156,593 stars; and 197,040 MARVELS spectra of 5,513 stars. Since its first light in 1998, SDSS has imaged over 1/3 of the Celestial sphere in five bands and obtained over five million astronomical spectra.

preprint2015arXiv

Variational Symplectic Particle-in-cell Simulation of Nonlinear Mode Conversion from Extraordinary waves to Bernstein Waves

In this paper, the nonlinear mode conversion of extraordinary waves in nonuniform magnetized plasmas is studied using the variational symplectic particle-in-cell simulation. The accuracy of the nonlinear simulation is guaranteed by the long-term accuracy and conservativeness of the symplectic algorithm. The spectra of the electromagnetic wave, the evolution of the wave reflectivity, the energy deposition profile, and the parameter-dependent properties of radio-frequency waves during the nonlinear mode conversion are investigated. It is illustrated that nonlinear effects significantly modify the physics of the radio-frequency injection in magnetized plasmas. The evolutions of the radio-frequency wave reflectivity and the energy deposition are observed, as well as the self-interaction of the Bernstein waves and mode excitations. Even for waves with small magnitude, nonlinear effects can also become important after continuous wave injections, which are common in the realistic radio-frequency wave heating and current drive experiments.

preprint2015arXiv

What is the fate of runaway positrons in tokamaks?

Massive runaway positrons are generated by runaway electrons in tokamaks. The fate of these positrons encodes valuable information about the runaway dynamics. The phase space dynamics of a runaway position is investigated using a Lagrangian that incorporates the tokamak geometry, loop voltage, radiation and collisional effects. It is found numerically that runaway positrons will drift out of the plasma to annihilate on the first wall, with an in-plasma annihilation possibility less than 0.1\%. The dynamics of runaway positrons provides signatures that can be observed as diagnostic tools.

preprint2014arXiv

Electronic and magnetic properties of (1 1 1)-oriented CoCr2O4 epitaxial thin film

We report on the fabrication of high quality (1 1 1)-oriented ferrimagnetic normal spinel CoCr2O4 epitaxial thin films on single crystal Al2O3 substrates. The structural, electronic and magnetic properties were characterized by in-situ reflection high energy electron diffraction, atomic force microscopy, X-ray diffraction, X-ray photoemission spectroscopy, SQUID magnetometry and element resolved resonant X-ray magnetic scattering. The comprehensive characterization reveals that no disorder in the cation distribution or multivalency issue is present in the samples. As a result, Kagome and triangular layers are naturally formed via this specific growth approach. These findings offer a pathway to fabricate two dimensional Kagome heterostructures with novel quantum many-body phenomena by means of geometrical design.

preprint2014arXiv

Molecular-Scale Hydrophilicity Induced by Solute: Molecular-thick Charged Pancakes of Aqueous Salt Solution on Hydrophobic Carbon-based Surfaces

We directly observed molecular-thick aqueous salt-solution pancakes on a hydrophobic graphite surface under ambient conditions employing atomic force microscopy. This observation indicates the unexpected molecular-scale hydrophilicity of the salt solution on graphite surfaces, which is different from the macroscopic wetting property of a droplet standing on the graphite surface. Interestingly, the pancakes spontaneously displayed strong positively charged behavior. Theoretical studies showed that the formation of such positively charged pancakes is attributed to cation-π interactions between Na+ ions in the aqueous solution and aromatic rings on the graphite surface, promoting the adsorption of water molecules together with cations onto the graphite surface; i.e., Na+ ions as a medium adsorbed to the graphite surface through cation-π interactions on one side while at the same time bonding to water molecules through hydration interaction on the other side at a molecular scale. These findings suggest that actual interactions regarding carbon-based graphitic surfaces including those of graphene, carbon nanotubes, and biochar may be significantly different from existing theory and they provide new insight into the control of surface wettability, interactions and related physical, chemical and biological processes.

preprint2013arXiv

Anisotropic magnetoresistance in antiferromagnetic semiconductor Sr2IrO4 epitaxial heterostructure

Lord Kelvin with his discovery of the anisotropic magnetoresistance (AMR) phenomenon in Ni and Fe was 70 years ahead of the formulation of relativistic quantum mechanics the effect stems from, and almost one and a half century ahead of spintronics whose first commercial applications relied on the AMR. Despite the long history and importance in magnetic sensing and memory technologies, the microscopic understanding of the AMR has struggled to go far beyond the basic notion of a relativistic magnetotransport phenomenon arising from combined effects on diffusing carriers of spin-orbit coupling and broken symmetry of a metallic ferromagnet. Our work demonstrates that even this seemingly generic notion of the AMR phenomenon needs revisiting as we observe the ohmic AMR effect in a nano-scale film of an antiferromagnetic (AFM) semiconductor Sr2IrO4 (SIO). Our work opens the recently proposed path for integrating semiconducting and spintronic technologies in AFMs. SIO is a particularly favorable material for exploring this path since its semiconducting nature is entangled with the AFM order and strong spin-orbit coupling. For the observation of the low-field Ohmic AMR in SIO we prepared an epitaxial heterostructure comprising a nano-scale SIO film on top of an epilayer of a FM metal La2/3Sr1/3MnO3 (LSMO). This allows the magnetic field control of the orientation of AFM spins in SIO via the exchange spring effect at the FM-AFM interface.

preprint2013arXiv

Enhanced Spin and Electronic Reconstructions at the Cuprate-Manganite Interface

We report on a resonant soft X-ray spectroscopy study of the electronic and magnetic structure of the cuprate-manganite interface. Polarized X-ray spectroscopy measurements taken at the Cu L edge reveal up to a five-fold increase in the dichroic signal as compared to past experimental and theoretical values. Furthermore an increase in the degree of interlayer charge transfer up to 0.25e (where e is charge of an electron) per copper ion is observed leading to a profound reconstruction in the orbital scheme for these interfacial copper ions. It is inferred that these enhancement are related to an increase in TMI observed for manganite layers grown with rapidly modulated flux.

preprint2013arXiv

Epitaxy-distorted spin-orbit Mott insulator in Sr2IrO4 thin films

High quality epitaxial thin films of Jeff=1/2 Mott insulator Sr2IrO4 with increasing in-plane tensile strain have been grown on top of SrTiO3(001) substrates. Increasing the in-plane tensile strain up to ~0.3% was observed to drop the c/a tetragonality by 1.2 %. X-ray absorption spectroscopy detected a strong reduction of the linear dichroism upon increasing in-plane tensile strain towards a reduced anisotropy in the local electronic structure. While the most relaxed thin film shows a consistent dependence with previously reported single crystal bulk measurements, electrical transport reveals a charge gap reduction from 200 meV down to 50 meV for the thinnest and most epitaxy-distorted film. We argue that the reduced tetragonality plays a major role in the change of the electronic structure, which is reflected in the change of the transport properties. Our work opens the possibility for exploiting epitaxial strain as a tool for both structural and functional manipulation of spin-orbit Mott systems.

preprint2013arXiv

Heterointerface engineered electronic and magnetic phases of NdNiO3 thin films

Mott physics is characterized by an interaction-driven metal-to-insulator transition in a partially filled band. In the resulting insulating state, antiferromagnetic orders of the local moments typically develop, but in rare situations no long-range magnetic order appears, even at zero temperature, rendering the system a quantum spin liquid. A fundamental and technologically critical question is whether one can tune the underlying energetic landscape to control both metal-to-insulator and Néel transitions, and even stabilize latent metastable phases, ideally on a platform suitable for applications. Here we demonstrate how to achieve this in ultrathin films of NdNiO3 with various degrees of lattice mismatch, and report on the quantum critical behaviours not reported in the bulk by transport measurements and resonant X-ray spectroscopy/scattering. In particular, on the decay of the antiferromagnetic Mott insulating state into a non-Fermi liquid, we find evidence of a quantum metal-to-insulator transition that spans a non-magnetic insulating phase.

preprint2013arXiv

Interfacial Coupling in Multiferroic-Ferromagnet Heterostructures

We report local probe investigations of the magnetic interaction between BiFeO3 films and a ferromagnetic Co0.9Fe0.1 layer. Within the constraints of intralayer exchange coupling in the Co0.9Fe0.1, the multiferroic imprint in the ferromagnet results in a collinear arrangement of the local magnetization and the in-plane BiFeO3 ferroelectric polarization. The magnetic anisotropy is uniaxial, and an in-plane effective coupling field of order 10 mT is derived. Measurements as a function of multiferroic layer thickness show that the influence of the multiferroic layer on the magnetic layer becomes negligible for 3 nm thick BiFeO3 films. We ascribe this breakdown in the exchange coupling to a weakening of the antiferromagnetic order in the ultrathin BiFeO3 film based on our X-ray linear dichroism measurements. These observations are consistent with an interfacial exchange coupling between the CoFe moments and a canted antiferromagnetic moment in the BiFeO3.

preprint2013arXiv

Mechanism of preferential adsorption of SO$_2$ into two microporous paddle wheel frameworks M(bdc)(ted)0.5

The selective adsorption of a corrosive gas, SO$_2$, into two microporous pillared paddle-wheel frameworks M(bdc)(ted)0.5 [M = Ni, Zn; bdc = 1,4-benzenedicarboxylate; ted = triethylenediamine] is studied by volumetric adsorption measurements and a combination of in-situ infrared spectroscopy and ab initio density functional theory (DFT) calculations. The uptake of SO$_2$ in M(bdc)(ted)0.5 at room temperature is quite significant, 9.97 mol/kg at 1.13 bar. The major adsorbed SO$_2$ molecules contributing to the isotherm measurements are characterized by stretching bands at 1326 and 1144 cm$^{-1}$. Theoretical calculations including van der Waals interactions (based on vdW-DF) suggest that two adsorption configurations are possible for these SO$_2$ molecules. One geometry involves an SO$_2$ molecule bonded through its sulfur atom to the oxygen atom of the paddle-wheel building unit and its two oxygen atoms to the C-H groups of the organic linkers by formation of hydrogen bonds. Such a configuration results in a distortion of the benzene rings, which is consistent with the experimentally observed shift of the ring deformation mode. In the other geometry, SO$_2$ establishes hydrogen bonding with -CH$_2$ group of the ted linker through its two oxygen atoms simultaneously. The vdW-DF-simulated frequency shifts of the SO$_2$ stretching bands in these two configurations are similar and in good agreement with spectroscopically measured values of physisorbed SO$_2$.In addition, the IR spectra reveal the presence of another minor species, characterized by stretching modes at 1242 and 1105 cm$^{-1}$ and causing significant perturbations of MOFs vibrational modes (CH$_x$ and carboxylate groups). This species is more strongly bound, requiring a higher temperature ($\sim$150 $^\circ$C) to remove it than for the main physisorbed species.

preprint2013arXiv

Nonlocal actin orientation models select for a unique orientation pattern

Many models have been developed to study the role of branching actin networks in motility. One important component of those models is the distribution of filament orientations relative to the cell membrane. Two mean-field models previously proposed are generalized and analyzed. In particular, we find that both models uniquely select for a dominant orientation pattern. In the linear case, the pattern is the eigenfunction associated with the principal eigenvalue. In the nonlinear case, we show there exists a unique equilibrium and that the equilibrium is locally stable. Approximate techniques are then used to provide evidence for global stability.

preprint2013arXiv

Temperature and composition dependence of short-range order and entropy, and statistics of bond length: the semiconductor alloy (GaN)$_{1-x}$(ZnO)$_x$

We present total energy and force calculations on the (GaN)$_{1-x}$(ZnO)$_{x}$ alloy. Site-occupancy configurations are generated by Monte Carlo (MC) simulations, based on a cluster expansion (CE) model proposed in a previous study. Surprisingly large local atomic coordinate relaxations are found by density-functional calculations using a 432-atom periodic supercell, for three representative configurations at $x=0.5$. These are used to generate bond length distributions. The configurationally averaged composition- and temperature-dependent short-range order (SRO) parameters of the alloys are discussed. Entropy is approximated in terms of pair distribution statistics and thus related to SRO parameters. This approximate entropy is compared with accurate numerical values from MC. An empirical model for the dependence of bond length on local chemical environments is proposed.

preprint2013arXiv

Tuning the Competition between Ferromagnetism and Antiferromagnetism in a Half-doped Manganite through Magnetoelectric Coupling

We investigate the possibility of controlling the magnetic phase transition of the heterointerface between a half-doped manganite La$_{0.5}$Ca$_{0.5}$MnO$_{3}$ and a multiferroic BiFeO$_{3}$ through magnetoelectric coupling. Using macroscopic magnetometry and element-selective x-ray magnetic circular dichroism at the Mn and Fe \emph{L}-edges, we discover that the ferroelectric polarization of BFO controls simultaneously the magnetization of BFO and LCMO. X-ray absorption spectra at oxygen \emph{K}-edge and linear dichroism at Mn \emph{L}-edge suggest that the interfacial coupling is mainly derived from the superexchange between Mn and Fe \emph{t}$_{2g}$ spins. The combination of x-ray absorption spectroscopy and mean field theory calculations reveals that the \emph{d}-electron modulation of Mn cations changes the magnetic coupling in LCMO, which controls the enhanced canted moments of interfacial BFO via the interfacial coupling. Our results demonstrate that the competition between ferromagnetic and antiferromagnetic instability can be modulated by an electric field at the heterointerface, providing another pathway for the electrical field control of magnetism.

preprint2013arXiv

Tuning the electronic properties of J_eff=1/2 correlated semimetal in epitaxial perovskite SrIrO3

We investigated the electronic properties of epitaxially stabilized perovskite SrIrO3 and demonstrated the effective strain-control on its electronic structure. Comprehensive transport measurements showed that the strong spin-orbit coupling renders a novel semimetallic phase for the J_eff=1/2 electrons rather than an ordinary correlated metal, elucidating the nontrivial mechanism underlying the dimensionality-controlled metal-insulator transition in iridates. The electron-hole symmetry of this correlated semimetal was found to exhibit drastic variation when subject to bi-axial strain. Under compressive strain, substantial electron-hole asymmetry is observed in contrast to the tensile side, where the electron and hole effective masses are comparable, illustrating the susceptivity of the J_eff=1/2 to structural distortion. Tensile strain also shrinks the Fermi surface, indicative of an increasing degree of correlation which is consistent with optical measurements. These results pave a pathway to investigate and manipulate the electronic states in spin-orbit-coupled correlated oxides, and lay the foundation for constructing 5d transition metal heterostructures.

preprint2013arXiv

Very Low Mass Stellar and Substellar Companions to Solar-like Stars From MARVELS IV: A Candidate Brown Dwarf or Low-Mass Stellar Companion to HIP 67526

We report the discovery of a candidate brown dwarf or a very low mass stellar companion (MARVELS-5b) to the star HIP 67526 from the Multi-object APO Radial Velocity Exoplanet Large-area Survey (MARVELS). The radial velocity curve for this object contains 31 epochs spread over 2.5 years. Our Keplerian fit using a Markov Chain Monte Carlo approach, reveals that the companion has an orbital period of $90.2695^{+0.0188}_{-0.0187}$ days, an eccentricity of $0.4375 \pm 0.0040$ and a semi-amplitude of $2948.14^{+16.65}_{-16.55}$ m s$^{-1}$. Using additional high-resolution spectroscopy, we find the host star has an effective temperature $T_{\rm{eff}}=6004 \pm 34$ K, a surface gravity $\log g$ [cgs] $=4.55 \pm 0.17$ and a metallicity [Fe/H] $=+0.04 \pm 0.06$. The stellar mass and radius determined through the empirical relationship of Torres et al. (2010), yields 1.10$\pm$0.09 $M_{\sun}$ and 0.92$\pm$0.19 $R_{\sun}$. The minimum mass of MARVELS-5b is $65.0 \pm 2.9 M_{Jup}$, indicating that it is likely to be either a brown dwarf or a very low mass star, thus occupying a relatively sparsely-populated region of the mass function of companions to solar-type stars. The distance to this system is 101$\pm$10 pc from the astrometric measurements of Hipparcos. No stellar tertiary is detected in the high-contrast images taken by either FastCam lucky imaging or Keck adaptive optics imaging, ruling out any star with mass greater than 0.2$M_{\sun}$ at a separation larger than 40 AU.

preprint2013arXiv

Very Low Mass Stellar and Substellar Companions to Solar-Like Stars From MARVELS V: A Low Eccentricity Brown Dwarf from the Driest Part of the Desert, MARVELS-6b

We describe the discovery of a likely brown dwarf (BD) companion with a minimum mass of 31.7 +/- 2.0 M_Jup to GSC 03546-01452 from the MARVELS radial velocity survey, which we designate as MARVELS-6b. For reasonable priors, our analysis gives a probability of 72% that MARVELS-6b has a mass below the hydrogen-burning limit of 0.072 M_Sun, and thus it is a high-confidence BD companion. It has a moderately long orbital period of 47.8929 +0.0063/-0.0062 days with a low eccentricty of 0.1442 +0.0078/-0.0073, and a semi-amplitude of 1644 +12/-13 m/s. Moderate resolution spectroscopy of the host star has determined the following parameters: T_eff = 5598 +/- 63, log g = 4.44 +/- 0.17, and [Fe/H] = +0.40 +/- 0.09. Based upon these measurements, GSC 03546-01452 has a probable mass and radius of M_star = 1.11 +/- 0.11 M_Sun and R_star = 1.06 +/- 0.23 R_Sun with an age consistent with less than ~6 Gyr at a distance of 219 +/- 21 pc from the Sun. Although MARVELS-6b is not observed to transit, we cannot definitively rule out a transiting configuration based on our observations. There is a visual companion detected with Lucky Imaging at 7.7 arcsec from the host star, but our analysis shows that it is not bound to this system. The minimum mass of MARVELS-6b exists at the minimum of the mass functions for both stars and planets, making this a rare object even compared to other BDs.

preprint2013arXiv

Water Transport through Carbon Nanotubes with the Radial Breathing Mode

Molecular dynamics simulations are performed to investigate the water permeation across the single-walled carbon nanotube (SWCNT) with the radial breathing mode (RBM) vibration. It is found that the RBM can play a significant role in breaking hydrogen bonds of the water chain, accordingly increasing the net flux dramatically, and reducing drastically the average number of water molecules inside the tube with the frequency ranging from 5000 to 11000 GHz, while far away from this frequency region the transport properties of water molecules are almost unaffected by the RBM. This phenomenon can be understood as the resonant response of the water molecule chain to the RBM. Our findings are expected to be helpful for the design of high-flux nanochannels and the understanding of biological activities especially the water channelling.

preprint2012arXiv

Determining Seebeck coefficient of heavily doped La:SrTiO3 from density functional calculations

A new approach is developed to calculate temperature dependent Seebeck coefficient of heavily doped systems by using Boltzmann transport theory and electron density of states (DOS) obtained from density functional calculations. This approach is applied to heavily doped La:STO with DOS from tetrahedral method and Fermi energy using Fermi integrals. The calculated Seebeck coefficient agrees with the experimental data nearly quantitatively, which proved the accuracy of this approach. The influence of the Fermi energy and asymmetry of DOS on the Seebeck coefficient is analyzed.

preprint2012arXiv

Metal-insulator transition and orbital reconstruction in Mott quantum wells of NdNiO$_{3}$

The metal-insulator transition (MIT) and the underlying electronic and orbital structure in $e_{g}^{1}$ quantum wells based on NdNiO$_{3}$ was investigated by d.c. transport and resonant soft x-ray absorption spectroscopy. By comparing quantum wells of the same dimension but with two different confinement structures, we explicitly demonstrate that the quantum well boundary condition of correlated electrons is critical to selecting the many-body ground state. In particular, the long-range orderings and the MIT are found to be strongly enhanced under quantum confinement by sandwiching NdNiO$_{3}$ with the wide-gap dielectric LaAlO$_{3}$, while they are suppressed when one of the interfaces is replaced by a surface (interface with vacuum). Resonant spectroscopy reveals that the reduced charge fluctuations in the sandwich structure are supported by the enhanced propensity to charge ordering due to the suppressed $e_g$ orbital splitting when interfaced with the confining LaAlO$_{3}$ layer.

preprint2012arXiv

Orbital control in strained ultra-thin LaNiO$_3$/LaAlO$_3$ superlattices

In pursuit of rational control of orbital polarization, we present a combined experimental and theoretical study of single unit cell superlattices of the correlated metal LaNiO$_3$ and the band insulator LaAlO$_3$. Polarized x-ray absorption spectra show a distinct asymmetry in the orbital response under strain. A splitting of orbital energies consistent with octahedral distortions is found for the case of compressive strain. In sharp contrast, for tensile strain, no splitting is found although a strong orbital polarization is present. Density functional theory calculations including a Hubbard U term reveal that this asymmetry is a result of the interplay of strain and confinement induces octahedral rotations and distortions and altered covalency in the bonding across the interfacial Ni-O-Al apical oxygen, leading to a charge disporportionation at the Ni sites for tensile strain.

preprint2012arXiv

Very Low-Mass Stellar and Substellar Companions to Solar-Like Stars from MARVELS I: A Low Mass Ratio Stellar Companion to TYC 4110-01037-1 in a 79-day Orbit

TYC 4110-01037-1 has a low-mass stellar companion, whose small mass ratio and short orbital period are atypical amongst solar-like (Teff ~< 6000 K) binary systems. Our analysis of TYC 4110-01037-1 reveals it to be a moderately aged (~<5 Gyr) solar-like star having a mass of 1.07 +/- 0.08 MSun and radius of 0.99 +/- 0.18 RSun. We analyze 32 radial velocity measurements from the SDSS-III MARVELS survey as well as 6 supporting radial velocity measurements from the SARG spectrograph on the 3.6m TNG telescope obtained over a period of ~2 years. The best Keplerian orbital fit parameters were found to have a period of 78.994 +/- 0.012 days, an eccentricity of 0.1095 +/- 0.0023, and a semi-amplitude of 4199 +/- 11 m/s. We determine the minimum companion mass (if sin i = 1) to be 97.7 +/- 5.8 MJup. The system's companion to host star mass ratio, >0.087 +/- 0.003, places it at the lowest end of observed values for short period stellar companions to solar-like (Teff ~< 6000 K) stars. One possible way to create such a system would be if a triple-component stellar multiple broke up into a short period, low q binary during the cluster dispersal phase of its lifetime. A candidate tertiary body has been identified in the system via single-epoch, high contrast imagery. If this object is confirmed to be co-moving, we estimate it would be a dM4 star. We present these results in the context of our larger-scale effort to constrain the statistics of low mass stellar and brown dwarf companions to FGK-type stars via the MARVELS survey.

preprint2012arXiv

Very Low-mass Stellar and Substellar Companions to Solar-like Stars from MARVELS II: A Short-period Companion Orbiting an F Star with Evidence of a Stellar Tertiary And Significant Mutual Inclination

We report the discovery via radial velocity of a short-period (P = 2.430420 \pm 0.000006 days) companion to the F-type main sequence star TYC 2930-00872-1. A long-term trend in the radial velocities indicates the presence of a tertiary stellar companion with $P > 2000$ days. High-resolution spectroscopy of the host star yields T_eff = 6427 +/- 33 K, log(g) = 4.52 +/- 0.14, and [Fe/H]=-0.04 +/- 0.05. These parameters, combined with the broad-band spectral energy distribution and parallax, allow us to infer a mass and radius of the host star of M_1=1.21 +/- 0.08 M_\odot and R_1=1.09_{-0.13}^{+0.15} R_\odot. We are able to exclude transits of the inner companion with high confidence. The host star's spectrum exhibits clear Ca H and K core emission indicating stellar activity, but a lack of photometric variability and small v*sin(I) suggest the primary's spin axis is oriented in a pole-on configuration. The rotational period of the primary from an activity-rotation relation matches the orbital period of the inner companion to within 1.5 σ, suggesting they are tidally locked. If the inner companion's orbital angular momentum vector is aligned with the stellar spin axis, as expected through tidal evolution, then it has a stellar mass of M_2 ~ 0.3-0.4 M_\odot. Direct imaging limits the existence of stellar companions to projected separations < 30 AU. No set of spectral lines and no significant flux contribution to the spectral energy distribution from either companion are detected, which places individual upper mass limits of M < 1.0 M_\odot, provided they are not stellar remnants. If the tertiary is not a stellar remnant, then it likely has a mass of ~0.5-0.6 M_\odot, and its orbit is likely significantly inclined from that of the secondary, suggesting that the Kozai-Lidov mechanism may have driven the dynamical evolution of this system.

preprint2012arXiv

Very Low-mass Stellar and Substellar Companions to Solar-like Stars from Marvels III: A Short-Period Brown Dwarf Candidate Around An Active G0Iv Subgiant

We present an eccentric, short-period brown dwarf candidate orbiting the active, slightly evolved subgiant star TYC 2087-00255-1, which has effective temperature T_eff = 5903+/-42 K, surface gravity log (g) = 4.07+/-0.16 (cgs), and metallicity [Fe/H] = -0.23+/-0.07. This candidate was discovered using data from the first two years of the Multi-object APO Radial Velocity Exoplanets Large-area Survey (MARVELS), which is part of the third phase of Sloan Digital Sky Survey. From our 38 radial velocity measurements spread over a two-year time baseline, we derive a Keplerian orbital fit with semi-amplitude K=3.571+/-0.041 km/s, period P=9.0090+/-0.0004 days, and eccentricity e=0.226+/-0.011. Adopting a mass of 1.16+/-0.11 Msun for the subgiant host star, we infer that the companion has a minimum mass of 40.0+/-2.5 M_Jup. Assuming an edge-on orbit, the semimajor axis is 0.090+/-0.003 AU. The host star is photometrically variable at the \sim1% level with a period of \sim13.16+/-0.01 days, indicating that the host star spin and companion orbit are not synchronized. Through adaptive optics imaging we also found a point source 643+/-10 mas away from TYC 2087-00255-1, which would have a mass of 0.13 Msun if it is physically associated with TYC 2087-00255-1 and has the same age. Future proper motion observation should be able to resolve if this tertiary object is physically associated with TYC 2087-00255-1 and make TYC 2087-00255-1 a triple body system. Core Ca II H and K line emission indicate that the host is chromospherically active, at a level that is consistent with the inferred spin period and measured v_{rot}*sin i, but unusual for a subgiant of this T_eff. This activity could be explained by ongoing tidal spin-up of the host star by the companion.

preprint2011arXiv

Asymmetric orbital-lattice interactions in ultra-thin correlated oxide films

Using resonant X-ray spectroscopies combined with density functional calculations, we find an asymmetric bi-axial strain-induced $d$-orbital response in ultra-thin films of the correlated metal LaNiO$_3$ which are not accessible in the bulk. The sign of the misfit strain governs the stability of an octahedral "breathing" distortion, which, in turn, produces an emergent charge-ordered ground state with an altered ligand-hole density and bond covalency. Control of this new mechanism opens a pathway to rational orbital engineering, providing a platform for artificially designed Mott materials.

preprint2011arXiv

Branching actin network remodeling governs the force-velocity relationship

Actin networks, acting as an engine pushing against an external load, are fundamentally important to cell motility. A measure of the effectiveness of an engine is the velocity the engine is able to produce at a given force, the force-velocity curve. One type of force-velocity curve, consisting of a concave region where velocity is insensitive to increasing force followed by a decrease in velocity, is indicative of an adaptive response. In contrast, an engine whose velocity rapidly decays as a convex curve in response to increasing force would indicate a lack of adaptive response. Even taken outside of a cellular context, branching actin networks have been observed to exhibit both concave and convex force-velocity curves. The exact mechanism that can explain both force-velocity curves is not yet known. We carried out an agent-based stochastic simulation to explore such a mechanism. Our results suggest that upon loading, branching actin networks are capable of remodeling by increasing the number filaments growing against the load. Our model provides a mechanism that can account for both convex and concave force-velocity relationships observed in branching actin networks. Finally, our model gives a potential explanation to the experimentally observed force history dependence for actin network velocity.

preprint2011arXiv

Dynamics of competing ideas in complex social systems

Individuals accepting an idea may intentionally or unintentionally impose influences in a certain neighborhood area, making other individuals within the area less likely or even impossible to accept other competing ideas. Depending on whether such influences strictly prohibit neighborhood individuals from accepting other ideas or not, we classify them into exclusive and non-exclusive influences, respectively. Our study reveals for the first time the rich and complex dynamics of two competing ideas with neighborhood influences in scale-free social networks: depending on whether they have exclusive or non-exclusive influences, the final state varies from multiple coexistence to founder control to exclusion, with different sizes of population accepting each of the ideas respectively. Such results provide insights helpful for better understanding the spread (and the control of spread) of ideas in human society.

preprint2011arXiv

Epitaxial Stabilization of Ultrathin Films of Rare-Earth Nickelates

We report on the synthesis of ultrathin films of highly distorted EuNiO3 (ENO) grown by interrupted pulse laser epitaxy on YAlO3 (YAO) substrates. Through mapping the phase space of nickelate thin film epitaxy, the optimal growth temperatures were found to scale linearly with the Goldschmidt tolerance factor. Considering the gibbs energy of the expanding film, this empirical trend is discussed in terms of epitaxial stabilization and the escalation of the lattice energy due to lattice distortions and decreasing symmetry. These findings are fundamental to other complex oxide perovskites, and provide a route to the synthesis of other perovskite structures in ultrathin-film form.

preprint2011arXiv

Quantum confinement of Mott electrons in ultrathin LaNiO3/LaAlO3 superlattice

We investigate the electronic reconstruction in (LaNiO$_{3}$)$_n$/(LaAlO$_{3}$)$_3$ (n=3, 5 and 10) superlattices due to the quantum confinement (QC) by d.c. transport and resonant soft x-ray absorption spectroscopy. In proximity to the QC limit, a Mott-type transition from an itinerant electron behavior to a localized state is observed. The system exhibits tendency towards charge-order during the transition. ab initio cluster calculations are in good agreement with the absorption spectra, indicating that the apical ligand hole density is highly suppressed resulting in a strong modification of the electronic structure. At the dimensional crossover cellular dynamical-mean-field calculations support the emergence of a Mott insulator ground state in the heterostructured ultra-thin slab of LaNiO$_{3}$.

preprint2011arXiv

Reciprocating Preferences Stablize Matching: College Admissions Revisited

In considering the college admissions problem, almost fifty years ago, Gale and Shapley came up with a simple abstraction based on preferences of students and colleges. They introduced the concept of stability and optimality; and proposed the deferred acceptance (DA) algorithm that is proven to lead to a stable and optimal solution. This algorithm is simple and computationally efficient. Furthermore, in subsequent studies it is shown that the DA algorithm is also strategy-proof, which means, when the algorithm is played out as a mechanism for matching two sides (e.g. colleges and students), the parties (colleges or students) have no incentives to act other than according to their true preferences. Yet, in practical college admission systems, the DA algorithm is often not adopted. Instead, an algorithm known as the Boston Mechanism (BM) or its variants are widely adopted. In BM, colleges accept students without deferral (considering other colleges' decisions), which is exactly the opposite of Gale-Shapley's DA algorithm. To explain and rationalize this reality, we introduce the notion of reciprocating preference to capture the influence of a student's interest on a college's decision. This model is inspired by the actual mechanism used to match students to universities in Hong Kong. The notion of reciprocating preference defines a class of matching algorithms, allowing different degrees of reciprocating preferences by the students and colleges. DA and BM are but two extreme cases (with zero and a hundred percent reciprocation) of this set. This model extends the notion of stability and optimality as well. As in Gale-Shapley's original paper, we discuss how the analogy can be carried over to the stable marriage problem, thus demonstrating the model's general applicability.

preprint2011arXiv

SDSS-III: Massive Spectroscopic Surveys of the Distant Universe, the Milky Way Galaxy, and Extra-Solar Planetary Systems

Building on the legacy of the Sloan Digital Sky Survey (SDSS-I and II), SDSS-III is a program of four spectroscopic surveys on three scientific themes: dark energy and cosmological parameters, the history and structure of the Milky Way, and the population of giant planets around other stars. In keeping with SDSS tradition, SDSS-III will provide regular public releases of all its data, beginning with SDSS DR8 (which occurred in Jan 2011). This paper presents an overview of the four SDSS-III surveys. BOSS will measure redshifts of 1.5 million massive galaxies and Lya forest spectra of 150,000 quasars, using the BAO feature of large scale structure to obtain percent-level determinations of the distance scale and Hubble expansion rate at z<0.7 and at z~2.5. SEGUE-2, which is now completed, measured medium-resolution (R=1800) optical spectra of 118,000 stars in a variety of target categories, probing chemical evolution, stellar kinematics and substructure, and the mass profile of the dark matter halo from the solar neighborhood to distances of 100 kpc. APOGEE will obtain high-resolution (R~30,000), high signal-to-noise (S/N>100 per resolution element), H-band (1.51-1.70 micron) spectra of 10^5 evolved, late-type stars, measuring separate abundances for ~15 elements per star and creating the first high-precision spectroscopic survey of all Galactic stellar populations (bulge, bar, disks, halo) with a uniform set of stellar tracers and spectral diagnostics. MARVELS will monitor radial velocities of more than 8000 FGK stars with the sensitivity and cadence (10-40 m/s, ~24 visits per star) needed to detect giant planets with periods up to two years, providing an unprecedented data set for understanding the formation and dynamical evolution of giant planet systems. (Abridged)

preprint2010arXiv

Discovery of a Low-Mass Companion to a Metal-Rich F Star with the MARVELS Pilot Project

We report the discovery of a low-mass companion orbiting the metal-rich, main sequence F star TYC 2949-00557-1 during the MARVELS (Multi-object APO Radial Velocity Exoplanet Large-area Survey) Pilot Project. The host star has an effective temperature T_eff = 6135 +/- 40 K, log(g) = 4.4 +/- 0.1 and [Fe/H] = 0.32 +/- 0.01, indicating a mass of M = 1.25 +/- 0.09 M_\odot and R = 1.15 +/- 0.15 R_\odot. The companion has an orbital period of 5.69449 +/- 0.00023 days and straddles the hydrogen burning limit with a minimum mass of 64 M_J, and may thus be an example of the rare class of brown dwarfs orbiting at distances comparable to those of "Hot Jupiters." We present relative photometry that demonstrates the host star is photometrically stable at the few millimagnitude level on time scales of hours to years, and rules out transits for a companion of radius greater than 0.8 R_J at the 95% confidence level. Tidal analysis of the system suggests that the star and companion are likely in a double synchronous state where both rotational and orbital synchronization have been achieved. This is the first low-mass companion detected with a multi-object, dispersed, fixed-delay interferometer.

preprint2010arXiv

Effect of polar discontinuity on the growth of LaNiO3/LaAlO3 superlattices

We have conducted a detailed microscopic investigation of [LaNiO3(1 u.c.)/LaAlO3(1 u.c.)]N superlattices grown on (001) SrTiO3 and LaAlO3 to explore the influence of polar mismatch on the resulting electronic and structural properties. Our data demonstrate that the initial growth on the non-polar SrTiO3 surface leads to a rough morphology and unusual 2+ valence of Ni in the first LaNiO3 layer, which is not observed after growth on the polar surface of LaAlO3. A newly devised model suggests that the polar mismatch can be resolved if the perovskite layers grow with an excess of LaO, which also accounts for the observed electronic, chemical, and structural effects.

preprint2010arXiv

Local Electronic and Magnetic Studies of an Artificial La2FeCrO6 Double Perovskite

Through the utilization of element-resolved polarized x-ray probes, the electronic and magnetic state of an artificial La2FeCrO6 double perovskite were explored. Applying unit-cell level control of thin film growth on SrTiO3 (111), the rock salt double perovskite structure can be created for this system, which does not have an ordered perovskite phase in the bulk. We find that the Fe and Cr are in the proper 3+ valence state, but, contrary to previous studies, the element-resolved magnetic studies find the moments in field are small and show no evidence of a sizable magnetic moment in the remanent state.

preprint2010arXiv

MARVELS-1b: A Short-Period, Brown Dwarf Desert Candidate from the SDSS-III MARVELS Planet Search

We present a new short-period brown dwarf candidate around the star TYC 1240-00945-1. This candidate was discovered in the first year of the Multi-object APO Radial Velocity Exoplanets Large-area Survey (MARVELS), which is part of the third phase of the Sloan Digital Sky Survey (SDSS-III), and we designate the brown dwarf as MARVELS-1b. MARVELS uses the technique of dispersed fixed-delay interferometery to simultaneously obtain radial velocity measurements for 60 objects per field using a single, custom-built instrument that is fiber fed from the SDSS 2.5-m telescope. From our 20 radial velocity measurements spread over a ~370 d time baseline, we derive a Keplerian orbital fit with semi-amplitude K=2.533+/-0.025 km/s, period P=5.8953+/-0.0004 d, and eccentricity consistent with circular. Independent follow-up radial velocity data confirm the orbit. Adopting a mass of 1.37+/-0.11 M_Sun for the slightly evolved F9 host star, we infer that the companion has a minimum mass of 28.0+/-1.5 M_Jup, a semimajor axis 0.071+/-0.002 AU assuming an edge-on orbit, and is probably tidally synchronized. We find no evidence for coherent instrinsic variability of the host star at the period of the companion at levels greater than a few millimagnitudes. The companion has an a priori transit probability of ~14%. Although we find no evidence for transits, we cannot definitively rule them out for companion radii ~<1 R_Jup.

preprint2010arXiv

Mathematical Modeling of Competition in Sponsored Search Market

Sponsored search mechanisms have drawn much attention from both academic community and industry in recent years since the seminal papers of [13] and [14]. However, most of the existing literature concentrates on the mechanism design and analysis within the scope of only one search engine in the market. In this paper we propose a mathematical framework for modeling the interaction of publishers, advertisers and end users in a competitive market. We first consider the monopoly market model and provide optimal solutions for both ex ante and ex post cases, which represents the long-term and short-term revenues of search engines respectively. We then analyze the strategic behaviors of end users and advertisers under duopoly and prove the existence of equilibrium for both search engines to co-exist from ex-post perspective. To show the more general ex ante results, we carry out extensive simulations under different parameter settings. Our analysis and observation in this work can provide useful insight in regulating the sponsored search market and protecting the interests of advertisers and end users.

preprint2010arXiv

Optical probe of strong correlations in LaNiO$_{3} $ thin films

The optical properties of LaNiO$_3$ thin films are investigated over a wide energy and temperature range. Thin films of varying thickness were epitaxially grown by pulsed laser deposition on LaAlO$_3$ and SrTiO$_3$ substrates. The optical conductivity data of the films reveal a number of interband transitions above 1 eV which are in good agreement with band structure calculations. No well defined Drude peak is observed however, in stark contrast with LDA theory predicting a finite density of states at the Fermi energy. This experimental finding of a vanishing Drude spectral weight, compared to a finite electron kinetic energy obtained from band structure calculations, highlights the importance of strong electronic correlations in LaNiO$_3$.

preprint2010arXiv

Strain-mediated metal-insulator transition in epitaxial ultra-thin films of NdNiO3

We have synthesized epitaxial NdNiO$_{3}$ ultra-thin films in a layer-by-layer growth mode under tensile and compressive strain on SrTiO$_{3}$ (001) and LaAlO$_3$ (001), respectively. A combination of X-ray diffraction, temperature dependent resistivity, and soft X-ray absorption spectroscopy has been applied to elucidate electronic and structural properties of the samples. In contrast to the bulk NdNiO$_{3}$, the metal-insulator transition under compressive strain is found to be completely quenched, while the transition remains under the tensile strain albeit modified from the bulk behavior.

preprint2010arXiv

Sub-monolayer nucleation and growth of complex oxide heterostructures at high supersaturation and rapid flux modulation

We report on the non-trivial nanoscale kinetics of the deposition of novel complex oxide heterostructures composed of a unit-cell thick correlated metal LaNiO3 and dielectric LaAlO3. The multilayers demonstrate exceptionally good crystallinity and surface morphology maintained over the large number of layers, as confirmed by AFM, RHEED, and synchrotron X-ray diffraction. To elucidate the physics behind the growth, the temperature of the substrate and the deposition rate were varied over a wide range and the results were treated in the framework of a two-layer model. These results are of fundamental importance for synthesis of new phases of complex oxide heterostructures.

preprint2010arXiv

Thermal Transport Properties of Bechgaard Salts (TMTSF)2PF6 and (TMTSF)2ClO4: Implication of Spin-Charge Separation

We report thermal transport measurements performed on the quasi-one-dimensional Bechgaard salts (TMTSF)2ClO4 and (TMTSF)2PF6 along the a-direction. For both salts, magnon-drag effects are found to contribute considerably to thermopower above 80 K. These results imply spin-charge separation in the metallic state for both salts. Moreover, a linear temperature-dependent thermal conductivity is found to be unaffected by anion disorder below an anion ordering transition temperature TAO~25 K in (TMTSF)2ClO4.

preprint2010arXiv

Visualizing nanoscale electronic band alignment at the La$_{2/3}$Ca$_{1/3}$MnO$_{3}$/Nb:SrTiO$_{3}$ interface

Cross-sectional scanning tunnelling microscopy and spectroscopy (XSTM/S) were used to map out the band alignment across the complex oxide interface of La$_{2/3}$Ca$_{1/3}$MnO$_{3}$/Nb-doped SrTiO$_{3}$. By a controlled cross-sectional fracturing procedure, unit-cell high steps persist near the interface between the thin film and the substrate in the non-cleavable perovskite materials. The abrupt changes of the mechanical and electronic properties were visualized directly by XSTM/S. Using changes in the DOS as probe by STM, the electronic band alignment across the heterointerface was mapped out providing a new approach to directly measure the electronic properties at complex oxide interfaces.