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Published work

64 published item(s)

preprint2026arXiv

DeepSeek-R1: Incentivizing Reasoning Capability in LLMs via Reinforcement Learning

General reasoning represents a long-standing and formidable challenge in artificial intelligence. Recent breakthroughs, exemplified by large language models (LLMs) and chain-of-thought prompting, have achieved considerable success on foundational reasoning tasks. However, this success is heavily contingent upon extensive human-annotated demonstrations, and models' capabilities are still insufficient for more complex problems. Here we show that the reasoning abilities of LLMs can be incentivized through pure reinforcement learning (RL), obviating the need for human-labeled reasoning trajectories. The proposed RL framework facilitates the emergent development of advanced reasoning patterns, such as self-reflection, verification, and dynamic strategy adaptation. Consequently, the trained model achieves superior performance on verifiable tasks such as mathematics, coding competitions, and STEM fields, surpassing its counterparts trained via conventional supervised learning on human demonstrations. Moreover, the emergent reasoning patterns exhibited by these large-scale models can be systematically harnessed to guide and enhance the reasoning capabilities of smaller models.

preprint2026arXiv

First Cosmological Constraints from the Joint Analysis of Galaxy Clustering and the Kinetic Sunyaev-Zel'dovich Effect

We perform the first joint analysis of galaxy clustering (GC) and the kinetic Sunyaev-Zel'dovich (kSZ) effect to simultaneously constrain cosmological and astrophysical parameters in this work, utilizing a combination of the Atacama Cosmology Telescope (ACT) Data Release 6 (DR6) map and the Constant Stellar Mass (CMASS) galaxy sample. As a complementary probe to the galaxy density power spectrum, we incorporate the pairwise kSZ power spectrum detected with a high signal-to-noise ratio (S/N $\sim 7$) to derive constraints on cosmological parameters ($H_0 = 70.82^{+4.94}_{-5.01}$, $Ω_{\rm m} = 0.290^{+0.092}_{-0.068}$, $w_0 = -1.038^{+0.245}_{-0.437}$) and the average optical depth of the galaxy sample ($\lg\barτ = -4.24 \pm 0.10$). Compared to the GC-only analysis, the joint analysis yields tighter constraints on these cosmological parameters: the Figures of Merit improve by 20.5\%, 19.7\% and 10.0\% for the $H_0$--$Ω_{\rm m}$, $H_0$--$w_0$ and $Ω_{\rm m}$--$w_0$ contours, respectively. For the first time, we demonstrate the complementary applicability of the kSZ effect in constraining cosmological parameters from real observational data.

preprint2026arXiv

Toward Natural and Companionable Virtual Agents via Cross-Temporal Emotional Modeling

Recent advances in foundation models have enabled conversational agents that aim for sustained companionship rather than mere task completion. Yet most still remain unable to support natural, long-term companion-like interactions, resulting in experiences that feel episodic and inauthentic. We argue that current agents overlooked cross-temporal modeling of agents' social behaviors and internal emotions: generated behaviors rarely influence an agent's emotional state, and emotional states seldom shape subsequent behaviors. We present Cross-Temporal Emotion Modeling (CTEM), a framework that links long-term behavioral history to moment-to-moment emotional expression. CTEM establishes a closed loop where past experiences update an evolving emotional state; this state conditions immediate interactions; and user feedback continually revises both memory and emotional state, enabling reflection and anticipation. We instantiate CTEM as Auri, a companion agent on an instant-messaging platform, and report a 21-day in-the-wild study showing that CTEM shows improvements in perceived naturalness, coherence, and emotional harmony.

preprint2023arXiv

Critical assessment of water enthalpy characterization through dark environment evaporation

Comparative evaporation rate testing in the absence of solar irradiation is a widely adopted method for establishing and characterizing a reduced vaporization enthalpy of water within an interfacial solar evaporator. However, the assumption of equal energy input between cases is not generally valid, and renders this characterization method misleading. Larger evaporation rates result from interfacial evaporators in dark conditions, mostly due to expanded surface areas. This causes greater evaporation rates, more evaporative cooling, and larger temperature differentials with the environment. We provide theoretical and experimental evidence to prove that these temperature differences cause large differences in environmental energy input, such that equal energy input cannot be assumed. Evaluation of our data within a transient analytical model enables quantification of the energy input differences and calculation of the vaporization enthalpy. This shows that differences in evaporation rate correspond to differences in energy input, and that vaporization enthalpy is not reduced below the theoretical value. The magnitude of increased energy input also agrees well with the increase of dark environment evaporation rates typically reported for interfacial evaporators, providing an alternative explanation for previous literature results. Further, we exemplify that the results of this characterization method contradict differential scanning calorimetry results, which are often used to make conclusions about vaporization enthalpy reduction and water state modification within evaporator materials. Thus, we conclude that this method should not be used to make conclusions about vaporization enthalpy reductions within interfacial evaporator materials. These results emphasize that the current understanding of vaporization enthalpy reduction within evaporator materials requires re-evaluation.

preprint2022arXiv

A graph-transformer for whole slide image classification

Deep learning is a powerful tool for whole slide image (WSI) analysis. Typically, when performing supervised deep learning, a WSI is divided into small patches, trained and the outcomes are aggregated to estimate disease grade. However, patch-based methods introduce label noise during training by assuming that each patch is independent with the same label as the WSI and neglect overall WSI-level information that is significant in disease grading. Here we present a Graph-Transformer (GT) that fuses a graph-based representation of an WSI and a vision transformer for processing pathology images, called GTP, to predict disease grade. We selected $4,818$ WSIs from the Clinical Proteomic Tumor Analysis Consortium (CPTAC), the National Lung Screening Trial (NLST), and The Cancer Genome Atlas (TCGA), and used GTP to distinguish adenocarcinoma (LUAD) and squamous cell carcinoma (LSCC) from adjacent non-cancerous tissue (normal). First, using NLST data, we developed a contrastive learning framework to generate a feature extractor. This allowed us to compute feature vectors of individual WSI patches, which were used to represent the nodes of the graph followed by construction of the GTP framework. Our model trained on the CPTAC data achieved consistently high performance on three-label classification (normal versus LUAD versus LSCC: mean accuracy$= 91.2$ $\pm$ $2.5\%$) based on five-fold cross-validation, and mean accuracy $= 82.3$ $\pm$ $1.0\%$ on external test data (TCGA). We also introduced a graph-based saliency mapping technique, called GraphCAM, that can identify regions that are highly associated with the class label. Our findings demonstrate GTP as an interpretable and effective deep learning framework for WSI-level classification.

preprint2022arXiv

Bayesian decision theory for tree-based adaptive screening tests with an application to youth delinquency

Crime prevention strategies based on early intervention depend on accurate risk assessment instruments for identifying high risk youth. It is important in this context that the instruments be convenient to administer, which means, in particular, that they should also be reasonably brief; adaptive screening tests are useful for this purpose. Adaptive tests constructed using classification and regression trees are becoming a popular alternative to traditional Item Response Theory (IRT) approaches for adaptive testing. However, tree-based adaptive tests lack a principled criterion for terminating the test. This paper develops a Bayesian decision theory framework for measuring the trade-off between brevity and accuracy, when considering tree-based adaptive screening tests of different lengths. We also present a novel method for designing tree-based adaptive tests, motivated by this framework. The framework and associated adaptive test method are demonstrated through an application to youth delinquency risk assessment in Honduras; it is shown that an adaptive test requiring a subject to answer fewer than 10 questions can identify high risk youth nearly as accurately as an unabridged survey containing 173 items.

preprint2022arXiv

Cosmological constraints from the density gradient weighted correlation function

The mark weighted correlation function (MCF) $W(s,μ)$ is a computationally efficient statistical measure which can probe clustering information beyond that of the conventional 2-point statistics. In this work, we extend the traditional mark weighted statistics by using powers of the density field gradient $|\nabla ρ/ρ|^α$ as the weight, and use the angular dependence of the scale-averaged MCFs to constrain cosmological parameters. The analysis shows that the gradient based weighting scheme is statistically more powerful than the density based weighting scheme, while combining the two schemes together is more powerful than separately using either of them. Utilising the density weighted or the gradient weighted MCFs with $α=0.5,\ 1$, we can strengthen the constraint on $Ω_m$ by factors of 2 or 4, respectively, compared with the standard 2-point correlation function, while simultaneously using the MCFs of the two weighting schemes together can be $1.25$ times more statistically powerful than using the gradient weighting scheme alone. The mark weighted statistics may play an important role in cosmological analysis of future large-scale surveys. Many issues, including the possibility of using other types of weights, the influence of the bias on this statistics, as well as the usage of MCFs in the tomographic Alcock-Paczynski method, are worth further investigations.

preprint2022arXiv

Delving Deep into Regularity: A Simple but Effective Method for Chinese Named Entity Recognition

Recent years have witnessed the improving performance of Chinese Named Entity Recognition (NER) from proposing new frameworks or incorporating word lexicons. However, the inner composition of entity mentions in character-level Chinese NER has been rarely studied. Actually, most mentions of regular types have strong name regularity. For example, entities end with indicator words such as "company" or "bank" usually belong to organization. In this paper, we propose a simple but effective method for investigating the regularity of entity spans in Chinese NER, dubbed as Regularity-Inspired reCOgnition Network (RICON). Specifically, the proposed model consists of two branches: a regularity-aware module and a regularityagnostic module. The regularity-aware module captures the internal regularity of each span for better entity type prediction, while the regularity-agnostic module is employed to locate the boundary of entities and relieve the excessive attention to span regularity. An orthogonality space is further constructed to encourage two modules to extract different aspects of regularity features. To verify the effectiveness of our method, we conduct extensive experiments on three benchmark datasets and a practical medical dataset. The experimental results show that our RICON significantly outperforms previous state-of-the-art methods, including various lexicon-based methods.

preprint2022arXiv

Enhanced brain structure-function tethering in transmodal cortex revealed by high-frequency eigenmodes

The brain's structural connectome supports signal propagation between neuronal elements, shaping diverse coactivation patterns that can be captured as functional connectivity. While the link between structure and function remains an ongoing challenge, the prevailing hypothesis is that the structure-function relationship may itself be gradually decoupled along a macroscale functional gradient spanning unimodal to transmodal regions. However, this hypothesis is strongly constrained by the underlying models which may neglect requisite signaling mechanisms. Here, we transform the structural connectome into a set of orthogonal eigenmodes governing frequency-specific diffusion patterns and show that regional structure-function relationships vary markedly under different signaling mechanisms. Specifically, low-frequency eigenmodes, which are considered sufficient to capture the essence of the functional network, contribute little to functional connectivity reconstruction in transmodal regions, resulting in structure-function decoupling along the unimodal-transmodal gradient. In contrast, high-frequency eigenmodes, which are usually on the periphery of attention due to their association with noisy and random dynamical patterns, contribute significantly to functional connectivity prediction in transmodal regions, inducing gradually convergent structure-function relationships from unimodal to transmodal regions. Although the information in high-frequency eigenmodes is weak and scattered, it effectively enhances the structure-function correspondence by 35% in unimodal regions and 56% in transmodal regions. Altogether, our findings suggest that the structure-function divergence in transmodal areas may not be an intrinsic property of brain organization, but can be narrowed through multiplexed and regionally specialized signaling mechanisms.

preprint2022arXiv

Multi-Level Attention for Unsupervised Person Re-Identification

The attention mechanism is widely used in deep learning because of its excellent performance in neural networks without introducing additional information. However, in unsupervised person re-identification, the attention module represented by multi-headed self-attention suffers from attention spreading in the condition of non-ground truth. To solve this problem, we design pixel-level attention module to provide constraints for multi-headed self-attention. Meanwhile, for the trait that the identification targets of person re-identification data are all pedestrians in the samples, we design domain-level attention module to provide more comprehensive pedestrian features. We combine head-level, pixel-level and domain-level attention to propose multi-level attention block and validate its performance on for large person re-identification datasets (Market-1501, DukeMTMC-reID and MSMT17 and PersonX).

preprint2022arXiv

Sensitivity tests of cosmic velocity fields to massive neutrinos

We investigate impacts of massive neutrinos on the cosmic velocity fields, employing high-resolution cosmological $N$-body simulations provided by the information-optimized CUBE code, where cosmic neutrinos are evolved using collisionless hydrodynamics and their perturbations can be accurately resolved. In this study we focus, for the first time, on the analysis of massive-neutrino induced suppression effects in various cosmic velocity field components of velocity magnitude, divergence, vorticity and dispersion. By varying the neutrino mass sum $M_ν$ from 0 -- 0.4 eV, the simulations show that, the power spectra of vorticity -- exclusively sourced by non-linear structure formation that is affected by massive neutrinos significantly -- is very sensitive to the mass sum, which potentially provide novel signatures in detecting massive neutrinos. Furthermore, using the chi-square statistic, we quantitatively test the sensitivity of the density and velocity power spectra to the neutrino mass sum. Indeed, we find that, the vorticity spectrum has the highest sensitivity, and the null hypothesis of massless neutrinos is incompatible with both vorticity and divergence spectra from $M_ν=0.1$ eV at high significance ($p$-value $= 0.03$ and $0.07$, respectively). These results demonstrate clearly the importance of peculiar velocity field measurements, in particular of vorticity and divergence components, in determination of neutrino mass and mass hierarchy.

preprint2022arXiv

Toward practical weak measurement wavefront sensing: spatial resolution and achromatism

The weak measurement wavefront sensor detects the phase gradient of light like the Shack-Hartmann sensor does. However, the use of one thin birefringent crystal to displace light beams results in a wavelength-dependent phase difference between the two polarization components, which limits the practical application. Using a Savart plate which consists of two such crystals can compensate for the phase difference and realize achromatic wavefront sensing when combined with an achromatic retarder. We discuss the spatial resolution of the sensor and experimentally reconstruct a wavefront modulated by a pattern. Then we obtain the Zernike coefficients with three different wavelengths before and after modulation. Our work makes this new wavefront sensor more applicable to actual tasks like biomedical imaging.

preprint2021arXiv

A General 3D Non-Stationary Massive MIMO GBSM for 6G Communication Systems

A general three-dimensional (3D) non-stationary massive multiple-input multiple-output (MIMO) geometry-based stochastic model (GBSM) for the sixth generation (6G) communication systems is proposed in the paper. The novelty of the model is that the model is designed to cover a variety of channel characteristics, including space-time-frequency (STF) non-stationarity, spherical wavefront, spatial consistency, channel hardening, etc. Firstly, the introduction of the twin-cluster channel model is given in detail. Secondly, the key statistical properties such as space-time-frequency correlation function (STFCF), space cross-correlation function (CCF), temporal autocorrelation function (ACF), frequency correlation function (FCF), and performance indicators, e.g., singular value spread (SVS), and channel capacity are derived. Finally, the simulation results are given and consistent with some measurements in relevant literatures, which validate that the proposed channel model has a certain value as a reference to model massive MIMO channel characteristics.

preprint2021arXiv

Electronic Self-passivation of Single Vacancy in Black Phosphorus via a Controlled Ionization

We report that mono-elemental black phosphorus presents a new electronic self-passivation scheme of single vacancy (SV). By means of low-temperature scanning tunneling microscopy and bond-resolved non-contact atomic force microscopy, we demonstrate that the local reconstruction and ionization of SV into negatively charged $\mathrm{SV}^-$ leads to the passivation of dangling bonds and thus the quenching of in-gap states, which can be achieved by mild thermal annealing or STM tip manipulation. SV exhibits a strong and symmetric Friedel oscillation (FO) pattern, while $\mathrm{SV}^-$ shows an asymmetric FO pattern with local perturbation amplitude reduced by one order of magnitude and a faster decay rate. The enhanced passivation by forming $\mathrm{SV}^-$ can be attributed to its weak dipole-like perturbation, consistent with density-functional theory and numerical calculations. Therefore, self-passivated $\mathrm{SV}^-$ is electronically benign and acts as a much weaker scattering center, which may hold the key to further enhance the charge mobility of BP and its analogs.

preprint2021arXiv

Inheritance-guided Hierarchical Assignment for Clinical Automatic Diagnosis

Clinical diagnosis, which aims to assign diagnosis codes for a patient based on the clinical note, plays an essential role in clinical decision-making. Considering that manual diagnosis could be error-prone and time-consuming, many intelligent approaches based on clinical text mining have been proposed to perform automatic diagnosis. However, these methods may not achieve satisfactory results due to the following challenges. First, most of the diagnosis codes are rare, and the distribution is extremely unbalanced. Second, existing methods are challenging to capture the correlation between diagnosis codes. Third, the lengthy clinical note leads to the excessive dispersion of key information related to codes. To tackle these challenges, we propose a novel framework to combine the inheritance-guided hierarchical assignment and co-occurrence graph propagation for clinical automatic diagnosis. Specifically, we propose a hierarchical joint prediction strategy to address the challenge of unbalanced codes distribution. Then, we utilize graph convolutional neural networks to obtain the correlation and semantic representations of medical ontology. Furthermore, we introduce multi attention mechanisms to extract crucial information. Finally, extensive experiments on MIMIC-III dataset clearly validate the effectiveness of our method.

preprint2021arXiv

Summarising Historical Text in Modern Languages

We introduce the task of historical text summarisation, where documents in historical forms of a language are summarised in the corresponding modern language. This is a fundamentally important routine to historians and digital humanities researchers but has never been automated. We compile a high-quality gold-standard text summarisation dataset, which consists of historical German and Chinese news from hundreds of years ago summarised in modern German or Chinese. Based on cross-lingual transfer learning techniques, we propose a summarisation model that can be trained even with no cross-lingual (historical to modern) parallel data, and further benchmark it against state-of-the-art algorithms. We report automatic and human evaluations that distinguish the historic to modern language summarisation task from standard cross-lingual summarisation (i.e., modern to modern language), highlight the distinctness and value of our dataset, and demonstrate that our transfer learning approach outperforms standard cross-lingual benchmarks on this task.

preprint2020arXiv

A method for detecting text of arbitrary shapes in natural scenes that improves text spotting

Understanding the meaning of text in images of natural scenes like highway signs or store front emblems is particularly challenging if the text is foreshortened in the image or the letters are artistically distorted. We introduce a pipeline-based text spotting framework that can both detect and recognize text in various fonts, shapes, and orientations in natural scene images with complicated backgrounds. The main contribution of our work is the text detection component, which we call UHT, short for UNet, Heatmap, and Textfill. UHT uses a UNet to compute heatmaps for candidate text regions and a textfill algorithm to produce tight polygonal boundaries around each word in the candidate text. Our method trains the UNet with groundtruth heatmaps that we obtain from text bounding polygons provided by groundtruth annotations. Our text spotting framework, called UHTA, combines UHT with the state-of-the-art text recognition system ASTER. Experiments on four challenging and public scene-text-detection datasets (Total-Text, SCUT-CTW1500, MSRA-TD500, and COCO-Text) show the effectiveness and generalization ability of UHT in detecting not only multilingual (potentially rotated) straight but also curved text in scripts of multiple languages. Our experimental results of UHTA on the Total-Text dataset show that UHTA outperforms four state-of-the-art text spotting frameworks by at least 9.1 percent points in the F-measure, which suggests that UHTA may be used as a complete text detection and recognition system in real applications.

preprint2020arXiv

Blackbody-cavity Ideal Solar Absorbers

Spectrally selective solar absorbers (SSAs), harvesting sunlight into heat, are the key to the concentrated solar thermal systems. Current SSAs' designs using photonic crystals, metamaterials, or cermets are either cost-inefficient or have limited applicability due to complicated nanofabrication methods and poor thermal stability at high temperatures. We present a scalable-manufactured blackbody cavity solar absorber design with nearly ideal properties. The unity solar absorptivity and nearly zero infrared emissivity allow for a stagnation temperature of 880C under 10 suns. The performance surpasses those state-of-the-art SSAs manufactured by nanofabrication methods. This design relies on traditional fabricating methods, such as machining, casting, and polishing. This makes it easy for large-scale industrial applications, and the "blackbody cavity" feature enables its fast-integration to existing concentrated solar thermal systems.

preprint2020arXiv

Cartoon Face Recognition: A Benchmark Dataset

Recent years have witnessed increasing attention in cartoon media, powered by the strong demands of industrial applications. As the first step to understand this media, cartoon face recognition is a crucial but less-explored task with few datasets proposed. In this work, we first present a new challenging benchmark dataset, consisting of 389,678 images of 5,013 cartoon characters annotated with identity, bounding box, pose, and other auxiliary attributes. The dataset, named iCartoonFace, is currently the largest-scale, high-quality, richannotated, and spanning multiple occurrences in the field of image recognition, including near-duplications, occlusions, and appearance changes. In addition, we provide two types of annotations for cartoon media, i.e., face recognition, and face detection, with the help of a semi-automatic labeling algorithm. To further investigate this challenging dataset, we propose a multi-task domain adaptation approach that jointly utilizes the human and cartoon domain knowledge with three discriminative regularizations. We hence perform a benchmark analysis of the proposed dataset and verify the superiority of the proposed approach in the cartoon face recognition task. We believe this public availability will attract more research attention in broad practical application scenarios.

preprint2020arXiv

Cosmological Information from the Small-scale Redshift Space Distortions

The redshift-space distortion (RSD) in the observed distribution of galaxies is known as a powerful probe of cosmology. Observations of large-scale RSD have given tight constraints on the linear growth rate of the large-scale structures in the universe. On the other hand, the small-scale RSD, caused by galaxy random motions inside clusters, has not been much used in cosmology, but also has cosmological information because universes with different cosmological parameters have different halo mass functions and virialized velocities. We focus on the projected correlation function $w(r_p)$ and the multipole moments $ξ_l$ on small scales ($1.4$ to $30\ h^{-1}\rm{Mpc}$). Using simulated galaxy samples generated from a physically motivated most bound particle (MBP)-galaxy correspondence scheme in the Multiverse Simulation, we examine the dependence of the small-scale RSD on the cosmological matter density parameter $Ω_m$, the satellite velocity bias with respect to MBPs, $b_v^s$, and the merger-time-scale parameter $α$. We find that $α=1.5$ gives an excellent fit to the $w(r_p)$ and $ξ_l$ measured from the SDSS-KIAS value added galaxy catalog. We also define the ``strength'' of Fingers-of-God as the ratio of the parallel and perpendicular size of the contour in the two-point correlation function set by a specific threshold value and show that the strength parameter helps constraining $(Ω_m, b_v^s, α)$ by breaking the degeneracy among them. The resulting parameter values from all measurements are $(Ω_m,b_v^s)=(0.272\pm0.013,0.982\pm0.040)$, indicating a slight reduction of satellite galaxy velocity relative to the MBP. However, considering that the average MBP speed inside haloes is $0.94$ times the dark matter velocity dispersion, the main drivers behind the galaxy velocity bias are gravitational interactions, rather than baryonic effects.

preprint2020arXiv

Dynamic Tuning of Near-field Radiative Thermal Rectification

Taking advantage of phase-transition and reconfigurable metamaterials, dynamic control of nanoscale thermal modulation can be achieved through the near-field radiative thermal rectification devices. In this work, an active-tuning near-field thermal rectifier using reconfigurable phase-transition metamaterials is explored. The rectifier has two terminals separated by vacuum, working under a controllable operational temperature around the critical temperature of the phase-transition material VO2. One of the terminals is a stretchable structure made of PDMS thin film and grating consisting of various types of phase-transition material. The effects of various inclusion forms and all the related geometric parameters are well analyzed. The controllable nanoscale thermal modulation can be achieved and the ultrahigh rectification ratios of 23.7 and 19.8, the highest values ever predicted, can be obtained for two deformation scenarios, respectively. It will shed light on the dynamic tuning of small-scale thermal transport and light manipulation.

preprint2020arXiv

Efficient Solar-driven Steam Generation Enabled by An Ultra-black Paint

Solar-driven interfacial steam generation for desalination has attracted broad attention. However, a significant challenge still remains for achieving a higher evaporation rate and high water quality, together with a cost-effective and easy-to-manufacture device to provide a feasible solar-driven steam generation system. In this study, a novel ultra-black paint, Black 3.0, serving as a perfect solar absorber is introduced into the hot-pressed melamine foam networks, allowing us to construct an ultra-black (99% absorptance in the solar region) and self-floating evaporation device. The high performing features of effective solar absorptance and salt-rejection capability contribute to a high-to-date evaporation rate of freshwater at 2.48 kg m-2 h-1 under one sun (1 kW m-2). This interfacial solar evaporator has a daily drinkable water yield of 2.8 kg m-2 even in cloudy winter weather and maintains stability in water with a wide range of acidity and alkalinity (pH 1~14). These features will enable the construction of a facilely fabricated, robust, highly-efficient, and cost-effective solar steam generation system for freshwater production.

preprint2020arXiv

Harvesting Energy from Sun, Outer Space, and Soil

While solar power systems have offered a wide variety of electricity generation approaches including photovoltaics, solar thermal power systems, and solar thermoelectric generators, the ability of generating electricity at both the daytime and nighttime with no necessity of energy storage still remains challenging. Here, we propose and verify a strategy of harvesting solar energy by solar heating during the daytime and harnessing the coldness of the outer space through radiative cooling to produce electricity at night using a commercial thermoelectric module. It enables electricity generation for 24 hours a day. We experimentally demonstrate a peak power density of 37 mW/m2 at night and a peak value of 723 mW/m2 during the daytime. A theoretical model that accurately predicts the performance of the device is developed and validated. The feature of 24-hour electricity generation shows great potential energy applications of off-grid and battery-free lighting and sensing.

preprint2020arXiv

High-temperature and Abrasion Resistant Selective Solar Absorber under Ambient Environment

Selective solar absorbers (SSAs) with high performance are the key to concentrated solar power systems. Optical metamaterials are emerging as a promising strategy to enhance selective photon absorption, however, the high-temperature resistance (>500C) remains as one of the main challenges for their practical applications. Here, a multilayered metamaterial system (Al2O3/W/SiO2/W) based on metal-insulator-metal (MIM) resonance effect has been demonstrated with high solar absorptance over 92%, low thermal emittance loss below 6%, and significant high-temperature resistance: it has been proved that the optical performance remains 93.6% after 1-hour thermal annealing under ambient environment up to 500C, and 94.1% after 96-hour thermal cycle test at 400C, which is also confirmed by the microscopic morphology characterization. The spectral selectivity of fabricated SSAs is angular independent and polarization insensitive. Outdoor tests demonstrate that a peak temperature rise (193.5C) can be achieved with unconcentrated solar irradiance and surface abrasion resistance test yields that SSAs have a robust resistance to abrasion attack for engineering applications.

preprint2020arXiv

Homophone-based Label Smoothing in End-to-End Automatic Speech Recognition

A new label smoothing method that makes use of prior knowledge of a language at human level, homophone, is proposed in this paper for automatic speech recognition (ASR). Compared with its forerunners, the proposed method uses pronunciation knowledge of homophones in a more complex way. End-to-end ASR models that learn acoustic model and language model jointly and modelling units of characters are necessary conditions for this method. Experiments with hybrid CTC sequence-to-sequence model show that the new method can reduce character error rate (CER) by 0.4% absolutely.

preprint2020arXiv

Self-cleaning and self-cooling paper

The technique of passive daytime radiative cooling (PDRC) is used to cool an object down by simultaneously reflecting sunlight and thermally radiating heat to the cold outer space through the Earth's atmospheric window. However, for practical applications, current PDRC materials are facing unprecedented challenges such as complicated and expensive fabrication approaches and performance degradation arising from surface contamination. Here, we develop a scalable paper-based material with excellent self-cleaning and self-cooling capabilities, through air-spraying ethanolic polytetrafluoroethylene (PTFE) microparticles suspensions embedded within the micropores of the paper. The formed superhydrophobic PTFE coating not only protects the paper from water wetting and dust contamination for real-life applications but also reinforces its solar reflectance by sunlight backscattering. The paper fibers, when enhanced with PTFE particles, efficiently reflect sunlight and strongly radiate heat through the atmospheric window, resulting in a sub-ambient cooling performance of 5$^{\circ}$C and radiative cooling power of 104 W/m$^2$ under direct solar irradiance of 834 W/m$^2$ and 671 W/m$^2$, respectively. The self-cleaning surface of the cooling paper extends its lifespan and keep its good cooling performance for outdoor applications. Additionally, dyed papers are experimentally studied for broad engineering applications. They can absorb appropriate visible wavelengths to display specific colors and effectively reflect near-infrared lights to reduce solar heating, which synchronously achieves effective radiative cooling and aesthetic varieties in a cost-effective, scalable, and energy-efficient way.

preprint2020arXiv

Spectrally Selective Solar Absorbers with High-temperature Insensitivity

It is of significance to incorporate spectral selectivity technology into solar thermal engineering, especially at high operational temperatures. This work demonstrates spectrally selective solar absorbers made of multilayer tungsten, silica, and alumina thin films that are angular insensitive and polarization-independent. An overall absorptance of 88.1% at solar irradiance wavelength, a low emittance of 7.0% at infrared thermal wavelength, and a high solar to heat efficiency of 79.9% are identified. Additionally, it shows the annealed samples maintain an extremely high absorption in solar radiation regime over at least 600 C and the solar absorbers after thermal annealing at 800 C still work well in a CSP system with an even high concentration factor of over 100.

preprint2020arXiv

Tunable Topological Energy Bands in 2D Dialkali-Metal Monoxides

2D materials with nontrivial energy bands are highly desirable for exploring various topological phases of matter, as low dimensionality opens unprecedented opportunities for manipulating the quantum states. Here, it is reported that monolayer (ML) dialkali-metal monoxides, in the well-known 2H-MoS$_2$ type lattice, host multiple symmetry-protected topological phases with emergent fermions, which can be effectively tuned by strain engineering. Based on first-principles calculations, it is found that in the equilibrium state, ML Na$_2$O is a 2D double Weyl semimetal, while ML K$_2$O is a 2D pseudospin-1 metal. These exotic topological states exhibit a range of fascinating effects, including universal optical absorbance, super Klein tunneling, and super collimation effect. By introducing biaxial or uniaxial strain, a series of quantum phase transitions between 2D double Weyl semimetal, 2D Dirac semimetal, 2D pseudospin-1 metal, and semiconductor phases can be realized. The results suggest monolayer dialkali-metal monoxides as a promising platform to explore fascinating physical phenomena associated with novel 2D emergent fermions.

preprint2020arXiv

Using the Mark Weighted Correlation Functions to Improve the Constraints on Cosmological Parameters

We used the mark weighted correlation functions (MCFs), $W(s)$, to study the large scale structure of the Universe. We studied five types of MCFs with the weighting scheme $ρ^α$, where $ρ$ is the local density, and $α$ is taken as $-1,\ -0.5,\ 0,\ 0.5$, and 1. We found that different MCFs have very different amplitudes and scale-dependence. Some of the MCFs exhibit distinctive peaks and valleys that do not exist in the standard correlation functions. Their locations are robust against the redshifts and the background geometry, however it is unlikely that they can be used as ``standard rulers'' to probe the cosmic expansion history. Nonetheless we find that these features may be used to probe parameters related with the structure formation history, such as the values of $σ_8$ and the galaxy bias. Finally, after conducting a comprehensive analysis using the full shapes of the $W(s)$s and $W_{Δs}(μ)$s, we found that, combining different types of MCFs can significantly improve the cosmological parameter constraints. Compared with using only the standard correlation function, the combinations of MCFs with $α=0,\ 0.5,\ 1$ and $α=0,\ -1,\ -0.5,\ 0.5,\ 1$ can improve the constraints on $Ω_m$ and $w$ by $\approx30\%$ and $50\%$, respectively. We find highly significant evidence that MCFs can improve cosmological parameter constraints.

preprint2019arXiv

Dynamical symmetry in quantum dissipative models

We show that the dynamical symmetry exists in dissipative quantum many-body systems. Under constraints on both Hamiltonian and dissipation parts, the time evolution of particular observables can be symmetric between repulsive and attractive interactions in the Hubbard model, or symmetric between ferromagnetic and anti-ferromagnetic interactions in the Ising model with external fields. We present a theorem to determine the existence of the dynamical symmetry in dissipative systems. This theorem is also responsible for the symmetry of steady states, even without the constraint on the initial state. We demonstrate the applications of our theorem with numerical simulations using tensor network algorithms.

preprint2019arXiv

Ergodic control of diffusions with compound Poisson jumps under a general structural hypothesis

We study the ergodic control problem for a class of controlled jump diffusions driven by a compound Poisson process. This extends the results of [SIAM J. Control Optim. 57 (2019), no. 2, 1516-1540] to running costs that are not near-monotone. This generality is needed in applications such as optimal scheduling of large-scale parallel server networks. We provide a full characterization of optimality via the Hamilton-Jacobi-Bellman (HJB) equation, for which we additionally exhibit regularity of solutions under mild hypotheses. In addition, we show that optimal stationary Markov controls are a.s. pathwise optimal. Lastly, we show that one can fix a stable control outside a compact set and obtain near-optimal solutions by solving the HJB on a sufficiently large bounded domain. This is useful for constructing asymptotically optimal scheduling policies for multiclass parallel server networks.

preprint2019arXiv

Homophily on social networks changes evolutionary advantage in competitive information diffusion

Competitive information diffusion on large-scale social networks reveals fundamental characteristics of rumor contagions and has profound influence on public opinion formation. There has been growing interest in exploring dynamical mechanisms of the competing evolutions recently. Nevertheless, the impacts of population homophily, which determines powerful collective human behaviors, remains unclear. In this paper, we incorporate homophily effects into a modified competitive ignorant-spreader-ignorant (SIS) rumor diffusion model with generalized population preference. Using microscopic Markov chain approach, we first derive the phase diagram of competing diffusion results and examine how competitive information spreads and evolves on social networks. We then explore the detailed effects of homophily, which is modeled by a rewiring mechanism. Results show that homophily promotes the formation of divided "echo chambers" and protects the disadvantaged information from extinction, which further changes or even reverses the evolutionary advantage, i.e., the difference of final proportions of the competitive information. We highlight the conclusion that the reversals may happen only when the initially disadvantaged information has stronger transmission ability, owning diffusion advantage over the other one. Our framework provides profound insight into competing dynamics with population homophily, which may pave ways for further controlling misinformation and guiding public belief systems. Moreover, the reversing condition sheds light on designing effective competing strategies in many real scenarios.

preprint2019arXiv

Loop update for infinite projected entangled-pair states in two spatial dimensions

We propose an improved approach to carry out the imaginary time evolution of infinite projected entangled-pair states (iPEPS), especially for systems with criticality. A cyclic optimal truncation is introduced to update the tensors along a closed loop, aiming to remove the redundant internal correlations. We demonstrate the algorithm by considering an elaborate evolution based on simple update on a small plaquette. This scheme can also be applied to a full update strategy. We demonstrate their performances on simulating the ground states of the spin-$1/2$ anti-ferromagnetic Heisenberg model and the transverse field Ising model on a square lattice.

preprint2016arXiv

5G 3GPP-like Channel Models for Outdoor Urban Microcellular and Macrocellular Environments

For the development of new 5G systems to operate in bands up to 100 GHz, there is a need for accurate radio propagation models at these bands that currently are not addressed by existing channel models developed for bands below 6 GHz. This document presents a preliminary overview of 5G channel models for bands up to 100 GHz. These have been derived based on extensive measurement and ray tracing results across a multitude of frequencies from 6 GHz to 100 GHz, and this document describes an initial 3D channel model which includes: 1) typical deployment scenarios for urban microcells (UMi) and urban macrocells (UMa), and 2) a baseline model for incorporating path loss, shadow fading, line of sight probability, penetration and blockage models for the typical scenarios. Various processing methodologies such as clustering and antenna decoupling algorithms are also presented.

preprint2016arXiv

Giant Linear Magneto-resistance in Nonmagnetic PtBi2

We synthesized nonmagnetic PtBi$_2$ single crystals and observed a giant linear magneto-resistance (MR) up to 684\% under a magnetic field $μ_0H$ = 15 T at $T$ = 2 K. The linear MR decreases with increasing temperature, but it is still as large as 61\% under $μ_0H$ of 15 T at room temperature. Such a giant linear MR is unlikely to be described by the quantum model as the quantum condition is not satisfied. Instead, we found that the slope of MR scales with the Hall mobility, and it can be well explained by a classical disorder model.

preprint2016arXiv

Helicity protected ultrahigh mobility Weyl fermions in NbP

Non-centrosymmetric transition metal monopnictides, including TaAs, TaP, NbAs, and NbP, are emergent topological Weyl semimetals (WSMs) hosting exotic relativistic Weyl fermions. In this letter, we elucidate the physical origin of the unprecedented charge carrier mobility of NbP, which can reach $1\times10^{7}$ cm $^{2}$V$^{-1}$s$^{-1}$ at 1.5 K. Angle- and temperature-dependent quantum oscillations, supported by density function theory calculations, reveal that NbP has the coexistence of p- and n-type WSM pockets in the $k_{z}$=1.16$π$/c plane (W1-WSM) and in the $k_{z}$=0 plane near the high symmetry points $Σ$ (W2-WSM), respectively. Uniquely, each W2-WSM pocket forms a large dumbbell-shaped Fermi surface (FS) enclosing two neighboring Weyl nodes with the opposite chirality. The magneto-transport in NbP is dominated by these highly anisotropic W2-WSM pockets, in which Weyl fermions are well protected from defect backscattering by real spin conservation associated to the chiral nodes. However, with a minimal doping of $\sim$1\% Cr, the mobility of NbP is degraded by more than two order of magnitude, due to the invalid of helicity protection to magnetic impurities. Helicity protected Weyl fermion transport is also manifested in chiral anomaly induced negative magnetoresistance, controlled by the W1-WSM states. In the quantum regime below 10 K, the intervalley scattering time by impurities becomes a large constant, producing the sharp and nearly identical conductivity enhancement at low magnetic field.

preprint2016arXiv

Negative Magnetoresistance in Topological Semimetals of Transition-Metal Dipnictides with Nontrivial Z2 Indices

Negative magnetoresistance (NMR) induced by the Adler-Bell-Jackiw anomaly is regarded as the most prominent quantum signature of Weyl semimetals when electrical field $E$ is collinear with the external magnetic field $B$. In this article, we report universal NMR in nonmagnetic, centrosymmetric transition metal dipnictides MPn$_{2}$ (M=Nb and Ta; Pn=As and Sb), in which the existence of Weyl fermions can be explicitly excluded. Using temperature-dependent magnetoresistance, Hall and thermoelectric coefficients of Nernst and Seebeck effects, we determine that the emergence of the NMR phenomena in MPn$_{2}$ is coincident with a Lifshitz transition, corresponding to the formation of unique electron-hole-electron ($e$-$h$-$e$) pockets along the $I-L-I'$ direction. First-principles calculations reveal that, along the $I-L-I'$ line, the $d_{xy}$ and $d_{x^{2}-y^{2}}$ orbitals of the transition metal form tilted nodal rings of band crossing well below the Fermi level. Strong spin-orbital coupling gaps all the crossing points and creates the characteristic $e$-$h$-$e$ structure, making MPn$_{2}$ a topological semimetal with $\mathbb{Z}_2$ indices of [0;(111)]. By excluding the weak localization contribution of the bulk states, we conclude that the universal NMR in MPn$_{2}$ may have an exotic origin in topological surface states, which appears in pairs with opposite spin-momentum locking on nontrivial surfaces.

preprint2016arXiv

Study on the mapping of dark matter clustering from real space to redshift space

The mapping of dark matter clustering from real space to redshift space introduces the anisotropic property to the measured density power spectrum in redshift space, known as the redshift space distortion effect. The mapping formula is intrinsically non-linear, which is complicated by the higher order polynomials due to indefinite cross correlations between the density and velocity fields, and the Finger-of-God effect due to the randomness of the peculiar velocity field. Whilst the full higher order polynomials remain unknown, the other systematics can be controlled consistently within the same order truncation in the expansion of the mapping formula, as shown in this paper. The systematic due to the unknown non-linear density and velocity fields is removed by separately measuring all terms in the expansion directly using simulations. The uncertainty caused by the velocity randomness is controlled by splitting the FoG term into two pieces, 1) the "one-point" FoG term being independent of the separation vector between two different points, and 2) the "correlated" FoG term appearing as an indefinite polynomials which is expanded in the same order as all other perturbative polynomials. Using 100 realizations of simulations, we find that the Gaussian FoG function with only one scale-independent free parameter works quite well, and that our new mapping formulation accurately reproduces the observed 2-dimensional density power spectrum in redshift space at the smallest scales by far, up to $k\sim 0.2h$Mpc, considering the resolution of future experiments.

preprint2016arXiv

The DESI Experiment Part I: Science,Targeting, and Survey Design

DESI (Dark Energy Spectroscopic Instrument) is a Stage IV ground-based dark energy experiment that will study baryon acoustic oscillations (BAO) and the growth of structure through redshift-space distortions with a wide-area galaxy and quasar redshift survey. To trace the underlying dark matter distribution, spectroscopic targets will be selected in four classes from imaging data. We will measure luminous red galaxies up to $z=1.0$. To probe the Universe out to even higher redshift, DESI will target bright [O II] emission line galaxies up to $z=1.7$. Quasars will be targeted both as direct tracers of the underlying dark matter distribution and, at higher redshifts ($ 2.1 < z < 3.5$), for the Ly-$α$ forest absorption features in their spectra, which will be used to trace the distribution of neutral hydrogen. When moonlight prevents efficient observations of the faint targets of the baseline survey, DESI will conduct a magnitude-limited Bright Galaxy Survey comprising approximately 10 million galaxies with a median $z\approx 0.2$. In total, more than 30 million galaxy and quasar redshifts will be obtained to measure the BAO feature and determine the matter power spectrum, including redshift space distortions.

preprint2016arXiv

The DESI Experiment Part II: Instrument Design

DESI (Dark Energy Spectropic Instrument) is a Stage IV ground-based dark energy experiment that will study baryon acoustic oscillations and the growth of structure through redshift-space distortions with a wide-area galaxy and quasar redshift survey. The DESI instrument is a robotically-actuated, fiber-fed spectrograph capable of taking up to 5,000 simultaneous spectra over a wavelength range from 360 nm to 980 nm. The fibers feed ten three-arm spectrographs with resolution $R= λ/Δλ$ between 2000 and 5500, depending on wavelength. The DESI instrument will be used to conduct a five-year survey designed to cover 14,000 deg$^2$. This powerful instrument will be installed at prime focus on the 4-m Mayall telescope in Kitt Peak, Arizona, along with a new optical corrector, which will provide a three-degree diameter field of view. The DESI collaboration will also deliver a spectroscopic pipeline and data management system to reduce and archive all data for eventual public use.

preprint2016arXiv

Topological phase transition induced extreme magnetoresistance in TaSb$_{2}$

We report extremely large positive magnetoresistance of 1.72 million percent in single crystal TaSb$_{2}$ at moderate conditions of 1.5 K and 15 T. The quadratic growth of magnetoresistance (MR $\propto\,B^{1.96}$) is not saturating up to 15 T, a manifestation of nearly perfect compensation with $<0.1\%$ mismatch between electron and hole pockets in this semimetal. The compensation mechanism is confirmed by temperature-dependent MR, Hall and thermoelectric coefficients of Nernst and Seebeck, revealing two pronounced Fermi surface reconstruction processes without spontaneous symmetry breaking, \textit{i.e.} Lifshitz transitions, at around 20 K and 60 K, respectively. Using quantum oscillations of magnetoresistance and magnetic susceptibility, supported by density-functional theory calculations, we determined that the main hole Fermi surface of TaSb$_{2}$ forms a unique shoulder structure along the $F-L$ line. The flat band top of this shoulder pocket is just a few meV above the Fermi level, leading to the observed topological phase transition at 20 K when the shoulder pocket disappears. Further increase in temperature pushes the Fermi level to the band top of the main hole pocket, induced the second Lifshitz transition at 60 K when hole pocket vanishes completely.

preprint2015arXiv

Chiral anomaly induced negative magnetoresistance in topological Weyl semimetal NbAs

In this paper, we report the intercone transport of Weyl fermions in NbAs with external magnetic field in parallel to electric field, a quantum phenomenon known as the Adler-Bell-Jackiw anomaly. Surprisingly, the resulting negative magnetoresistance (MR) in NbAs shows significant difference from NbP. The observed low-field positive MR dip, which is missing in NbP at low temperatures, indicates that the spin-orbital coupling (SOC) is significantly stronger in NbAs than in the former. The results imply that the contribution of arsenic to SOC in TaAs and NbAs is not negligible.

preprint2015arXiv

Determination of the large scale volume weighted halo velocity bias in simulations

A profound assumption in peculiar velocity cosmology is $b_v=1$ at sufficiently large scales, where $b_v$ is the volume weighted halo(galaxy) velocity bias with respect to the matter velocity field. However, this fundamental assumption has not been robustly verified in numerical simulations. Furthermore, it is challenged by structure formation theory (BBKS, 1986, ApJ; Desjacques and Sheth, 2010, PRD), which predicts the existence of velocity bias (at least for proto-halos) due to the fact that halos reside in special regions (local density peaks). The major obstacle to measure the volume weighted velocity from N-body simulations is an unphysical sampling artifact. It is entangled in the measured velocity statistics and becomes significant for sparse populations. With recently improved understanding of the sampling artifact (Zhang, Zheng and Jing, 2015, PRD; Zheng, Zhang and Jing, 2015, PRD), for the first time we are able to {\it appropriately correct this sampling artifact and then robustly measure the volume weighted halo velocity bias}. (1) We verify $b_v=1$ within $2\%$ model uncertainty at $k\lesssim 0.1h/$Mpc and $z=0$-$2$ for halos of mass $\sim 10^{12}$-$10^{13} h^{-1} M_\odot$, and, therefore, consolidates a foundation of the peculiar velocity cosmology. (2) We also find statistically significant signs of $b_v\neq 1$ at $k\gtrsim 0.1h/$Mpc. Unfortunately, whether this is real or caused by residual sampling artifact requires further investigation. Nevertheless, cosmology based on $k\gtrsim 0.1h/$Mpc velocity data shall be careful this potential velocity bias.

preprint2015arXiv

Sampling Artifact in Volume Weighted Velocity Measurement.--- I. Theoretical Modelling

Cosmology based on large scale peculiar velocity preferes volume weighted velocity statistics. However, measuring the volume weighted velocity statistics from inhomogeneously distributed galaxies (simulation particles/halos) suffer from an inevitable and significant sampling artifact. We study this sampling artifact in the velocity power spectrum measured by the nearest-particle (NP) velocity assignment method(Zheng et al. 2013, PRD). We derive the analytical expression of leading and higher order terms. We find that the sampling artifact suppresses the $z=0$ E-mode velocity power spectrum by $\sim 10\%$ at $k=0.1h/$Mpc , for samples with number density $10^{-3}({\rm Mpc}/h)^{-3}$. This suppression becomes larger for larger $k$ and for sparser samples. We argue that, this source of systematic errors in peculiar velocity cosmology, albeit severe, can be self-calibrated in the framework of our theoretical modelling. We also work out the sampling artifact in the density-velocity cross power spectrum measurement. More robust evaluation of related statistics through simulations will be presented in a companion paper (Zheng, Zhang & Jing, 2015, PRD). We also argue that similar sampling artifact exists in other velocity assignment methods and hence must be carefully corrected to avoid systematic bias in peculiar velocity cosmology.

preprint2015arXiv

Sampling Artifact in Volume Weighted Velocity Measurement.--- II. Detection in simulations and comparison with theoretical modelling

Measuring the volume weighted velocity power spectrum suffers from a severe systematic error, due to imperfect sampling of the velocity field from inhomogeneous distribution of dark matter particles/halos in simulations or galaxies with velocity measurement. This "sampling artifact" depends on both the mean particle number density $\bar{n}_P$ and the intrinsic large scale structure (LSS) fluctuation in the particle distribution. (1) We report robust detection of this sampling artifact in N-body simulations. It causes $\sim 12$% underestimation of the velocity power spectrum at $k=0.1$h/Mpc for samples with $\bar{n}_P=6\times10^{-3}$ (Mpc/h)$^{-3}$. This systematic underestimation increases with decreasing $\bar{n}_P$ and increasing $k$. Its dependence on the intrinsic LSS fluctuations is also robustly detected. (2) All these findings are expected by our theoretical modelling in paper I \cite{Zhang14}. In particular, the leading order theoretical approximation agrees quantitatively well with simulation result for $\bar{n}_P\gtrsim6\times 10^{-4}$(Mpc/h)$^{-3}$. Furthermore, we provide an ansatz to take high order terms into account. It improves the model accuracy to $\lesssim1$% at $k\lesssim0.1$h/Mpc over 3 orders of magnitude in $\bar{n}_P$ and over typical LSS clustering from $z=0$ to $z=2$. (3) The sampling artifact is determined by the deflection ${\bf D}$ field, which is straightforwardly available in both simulations and data of galaxy velocity. Hence the sampling artifact in the velocity power spectrum measurement can be self-calibrated within our framework. By applying such self-calibration in simulations, it becomes promising to determine the {\it real} large scale velocity bias of $10^{13}M_\odot$ halos with $\sim 1$% accuracy, and that of lower mass halos by better accuracy. ...[abridged]

preprint2014arXiv

Radiative energy and momentum transfer for various spherical shapes: a single sphere, a bubble, a spherical shell and a coated sphere

We use fluctuational electrodynamics to determine emissivity and van der Waals contribution to surface energy for various spherical shapes, such as a sphere, a bubble, a spherical shell and a coated sphere, in a homogeneous and isotropic medium. Near-field radiative transfer and momentum transfer between flat plates and curved surfaces have been studied for the past decades, however the investigation of radiative heat transfer and van der Waals stress due to fluctuations of electromagnetic fields for a single object is missing from literature. The dyadic Green's function formalism of radiative energy and fluctuation-induced van der Waals stress for different spherical configurations have been developed. We show (1) emission spectra of micro and nano-sized spheres display several emissivity sharp peaks as the size of object reduces, and (2) surface energy becomes size dependent due to van der Waals phenomena when size of object is reduced to a nanoscopic length scale.

preprint2014arXiv

Review of fluctuational electrodynamics and its applications to radiative momentum, energy and entropy transport

Quantum and thermal fluctuations of electromagnetic fields, which give rise to Planck's law of blackbody radiation, are also responsible for van der Waals and Casimir forces, as well as near-field radiative energy transfer between objects. Electromagnetic waves transport energy, momentum, and entropy. For classical thermal radiation, the dependence of the above mentioned quantities on the temperature is well-known mainly due to Planck's work. When near-field effects, namely the collective influence of diffraction, interference, and tunneling of waves, become important, Planck's theory is no longer valid. Of momentum, energy, and entropy transfer, the role of near-field effects on momentum transfer between two half-spaces separated by a vacuum gap (van der Waals pressure in the vacuum gap) was first determined by Lifshitz, using Rytov's theory of fluctuational electrodynamics in 1956. Subsequently, Dzyaloshinskii, Lifshitz, and Pitaevskii, employing sophisticated methods from quantum field theory, generalized Lifshitz' result for van der Waals pressure in a vacuum layer to the case of van der Waals pressure in a dissipative layer between two half-spaces. The influence of near-field effects on radiative transfer was appreciated only in the late 1960s and, subsequently, in the last two decades because of the enhancement in radiative transfer due to electromagnetic surface waves. The role played by near-field effects on entropy transfer has not been investigated so far, at least when the temperature distribution is non-uniform.

preprint2014arXiv

Topological bands in one-dimensional periodic potentials

We study the properties of the quantum states in the one-dimensional system with a shifted periodic potential in both the discrete model and the continuous model. With open boundary conditions, the edge states appear in the energy gaps which indicate non-trivial topological structures. The Chern numbers with respect to the Bloch vector and the potential shift angle are computed. In the limit of the continuous model, the Chern number of each band is exactly one. We demonstrate the particle number pumped by the adiabatically shift of the potential is directly related to the topological invariants.

preprint2013arXiv

A Green's function formalism of energy and momentum transfer in fluctuational electrodynamics

Radiative energy and momentum transfer due to fluctuations of electromagnetic fields arising due to temperature difference between objects is described in terms of the cross-spectral densities of the electromagnetic fields. We derive relations between thermal non-equilibrium contributions to energy and momentum transfer and surface integrals of tangential components of the dyadic Green's functions of the vector Helmholtz equation. The expressions derived here are applicable to objects of arbitrary shapes, dielectric functions, as well as magnetic permeabilities. For the case of radiative transfer, we derive expressions for the generalized transmissivity and generalized conductance that are shown to obey reciprocity and agree with theory of black body radiative transfer in the appropriate limit.

preprint2013arXiv

Fully Automatic Liquid Metal Printer towards Personal Electronics Manufacture

Printed electronics is quickly emerging with tremendous value in a wide variety of latest electrical engineering areas. However, restricted to the rather limited conductive inks and printing strategies, the currently existing electronics manufacturing tools are generally complicated, expensive, time, material, water and energy consuming, and thus mainly restricted to the industrial use. Here from an alternative way, the present article demonstrated for the first time an entirely automatic printing system for personal electronics manufacturing through introducing a composite liquid metal ink delivery and printing mechanism to overcome the large surface tension facing the solution, and integrating it with the notebook computer controlling algorithm. With the developed printer, any desired electronically conductive patterns spanning from single wires to various complex structures like integrated circuit (IC), antenna, PCB, RFID, electronic greeting cards, decoration arts, classical buildings (White House, Great Wall etc.) or more do-it-yourself (DIY) circuits were demonstrated to be printed out in a moment with high precision. And the total cost for the whole system has reached personal affordability, which is hard to offer by so far the state of the art technologies. Some fundamental fluid dynamics mechanisms related to the proposed tapping mode enabled reliable printing and adhesion of the liquid metal electronics on the flexible substrate was systematically disclosed through theoretical interpretation and experimental measurements. This clearly beyond-the-lab technology and pervasively available liquid metal printer opens the way for large scale home level electronics making in the coming time.

preprint2013arXiv

Graphene-Ferroelectric Hybrid Structure for Flexible Transparent Electrodes

Graphene has exceptional optical, mechanical and electrical properties, making it an emerging material for novel optoelectronics, photonics and for flexible transparent electrode applications. However, the relatively high sheet resistance of graphene is a major constrain for many of these applications. Here we propose a new approach to achieve low sheet resistance in large-scale CVD monolayer graphene using non-volatile ferroelectric polymer gating. In this hybrid structure, large-scale graphene is heavily doped up to 3{\times}1013 cm-2 by non-volatile ferroelectric dipoles, yielding a low sheet resistance of 120 Ω{\Box} at ambient conditions. The graphene-ferroelectric transparent conductors (GFeTCs) exhibit more than 95% transmittance from the visible to the near infrared range owing to the highly transparent nature of the ferroelectric polymer. Together with its excellent mechanical flexibility, chemical inertness and the simple fabrication process of ferroelectric polymers, the proposed GFeTCs represent a new route towards large-scale graphene based transparent electrodes and optoelectronics.

preprint2013arXiv

Peculiar Velocity Decomposition, Redshift Space Distortion and Velocity Reconstruction in Redshift Surveys - I. The Methodology

Massive spectroscopic surveys will measure the redshift space distortion (RSD) induced by galaxy peculiar velocity to unprecedented accuracy. We develop a new method to improve the RSD modeling and to carry out robust reconstruction of the 3D large scale peculiar velocity through galaxy redshift surveys, in light of RSD. (1) We propose a mathematically unique and physically motivated decomposition of peculiar velocity into three eigen-components of different origins, different scale dependences and different impacts on RSD. (2) This decomposition has the potential to simplify and improve the RSD modeling. We derive a new formula for the redshift space power spectrum. Under the velocity decomposition scheme, all high order Gaussian corrections and non-Gaussian correction of order $δ^3$ can be taken into account without introducing extra model uncertainties. We find that the leading order contribution $\propto (1+f\tilde{W}(k)u^2)^2$ differs from the Kaiser formula by a function $\tilde{W}(k)\leq 1$. We hence identify a significant systematic error causing underestimation of the structure growth parameter $f$ by as much as $O(10%)$ even at relatively large scale $k=0.1h/$Mpc. The velocity decomposition also reveals the three origins of the finger of God (FOG) effect. (3) The velocity decomposition clarifies issues in peculiar velocity reconstruction through 3D galaxy distribution. We discuss two possible ways to carry out the velocity reconstruction. Both use the otherwise troublesome RSD in velocity reconstruction as a valuable source of information. Both have the advantage to render the reconstruction of a stochastic 3D field into the reconstruction of a deterministic window function $W^s(k,u)$ of limited degrees of freedom...[abridged]

preprint2013arXiv

Pervasive liquid metal direct writing electronics with roller-ball pen

A roller-ball pen enabled direct writing electronics via room temperature liquid metal ink was proposed. With the rolling to print mechanism, the metallic inks were smoothly written on flexible polymer substrate to form conductive tracks and electronic devices. The contact angle analyzer and scanning electron microscope were implemented to probe the inner property of the obtained electronics. An ever high writing resolution with line width and thickness as 200μm and 80μm, respectively was realized. Further, with the administration of external writing pressure, GaIn24.5 droplets embody increasing wettability on polymer which demonstrates the pervasive adaptability of the roller-ball pen electronics.

preprint2013arXiv

Quasi-Periodic Nanoripples in Graphene Grown by Chemical Vapor Deposition and Its Impact on Charge Transport

The technical breakthrough in synthesizing graphene by chemical vapor deposition methods (CVD) has opened up enormous opportunities for large-scale device applications. In order to improve the electrical properties of CVD graphene grown on copper (Cu-CVD graphene), recent efforts have focussed on increasing the grain size of such polycrystalline graphene films to 100 micrometers and larger. While an increase in grain size and hence, a decrease of grain boundary density is expected to greatly enhance the device performance, here we show that the charge mobility and sheet resistance of Cu-CVD graphene is already limited within a single grain. We find that the current high-temperature growth and wet transfer methods of CVD graphene result in quasi-periodic nanoripple arrays (NRAs). Electron-flexural phonon scattering in such partially suspended graphene devices introduces anisotropic charge transport and sets limits to both the highest possible charge mobility and lowest possible sheet resistance values. Our findings provide guidance for further improving the CVD graphene growth and transfer process.

preprint2013arXiv

Seeding ice growth at ambient conditions using nano graphene oxide

Water wetting on a hydrophobic surface at ambient conditions is disallowed by the nonpolar nature of the surface and high vapor pressure of water. However, the presence of sub-millimeter sized hydrophilic patches allows the waxy wings of desert beetles to become wettable by morning mist. Here, we show that a sprinkle of graphene oxide nanoflakes (nanoGOs) is effective in condensing water nanodroplets and seeding ice epitaxy on graphite at ambient conditions. By controlling relative humidity and nanoGO density, we are able to study the formation of a complete ice wetting layer on a time scale of 20 hours. This presents an unprecedented opportunity to visualize ice nucleation and growth in real time using non-contact atomic force microscopy. The stages of crystallization, as proposed by Ostwald in 1897, is fully unfolded at a microscopic level for the first time. We obtain real-time imaging of sequential phase transition from amorphous ice to a transient cubic ice Ic stage and finally to the stable hexagonal ice Ih. Most interestingly, we discover that ice nucleation and growth can be influenced by modifying the functional groups of nanoGO, and by intermolecular hydrogen-bonding between nanoGOs. This affords a strategy to control heterogenous ice nucleation and snow crystal formation.

preprint2012arXiv

Analysis of Dual-beam Asymmetrical Torsional Bi-Material Cantilever for Temperature Sensing Applications

An extremely sensitive temperature measurement MEMS device is developed based on the principle of structural deflection in a bi-material cantilever caused by a difference in thermal expansion coefficients. A dual-beam asymmetrical geometry is used to produce a torsional response from the device. An analytical model is developed to predict the performance and optimize the free parameters of the device. In this work, it is performed to analyze the flexural and torsional eigenfrequencies as well as confirm the theoretical predictions of DC and AC response. Lastly, a procedure is developed to allow fabrication of the device using equipment available in the Columbia University clean room.

preprint2012arXiv

Calculation of Droplet Size and Formation Time in Electrohydrodynamic Based Pulsatile Drug Delivery System

Electrohydrodynamic (EHD) generation, a commonly used method in BioMEMS, plays a significant role in the pulsed-release drug delivery system for a decade. In this paper, an EHD based drug delivery system is well designed, which can be used to generate a single drug droplet as small as 2.83 nL in 8.5 ms with a total device of 2x2x3 mm^3, and an external supplied voltage of 1500 V. Theoretically, we derive the expressions for the size and the formation time of a droplet generated by EHD method, while taking into account the drug supply rate, properties of liquid, gap between electrodes, nozzle size, and charged droplet neutralization. This work proves a repeatable, stable and controllable droplet generation and delivery system based on EHD method.

preprint2012arXiv

Entropy density and entropy flux in near-field thermal radiation

We propose a method to evaluate the entropy density and entropy flux in a vacuum gap between two half-spaces that takes into account influence of near-field effects, i.e., interference, diffraction, and tunneling of waves. The method developed is used to determine the maximum work that can be extracted through near-field radiative transfer between two half-spaces at different temperatures.

preprint2012arXiv

Pulsatile Drug Delivery System Based on Electrohydrodynamic Method

Electrohydrodynamic (EHD) generation, a commonly used method in BioMEMS, plays a significant role in the pulsatile drug delivery system for a decade. In this paper, an EHD based drug delivery system is well designed, which can be used to generate a single drug droplet as small as 2.83 nL in 8.5 ms with a total device of 2\times2\times3 mm^3, and an external supplied voltage of 1500 V. Theoretically, we derive the expressions for the size and the formation time of a droplet generated by EHD method, while taking into account the drug supply rate, properties of liquid, gap between two electrodes, nozzle size, and charged droplet neutralization. This work proves a repeatable, stable and controllable droplet generation and delivery system based on EHD method experimentally as well as theoretically.

preprint2011arXiv

Wafer-scale graphene/ferroelectric hybrid devices for low-voltage electronics

Preparing graphene and its derivatives on functional substrates may open enormous opportunities for exploring the intrinsic electronic properties and new functionalities of graphene. However, efforts in replacing SiO$_{2}$ have been greatly hampered by a very low sample yield of the exfoliation and related transferring methods. Here, we report a new route in exploring new graphene physics and functionalities by transferring large-scale chemical vapor deposition single-layer and bilayer graphene to functional substrates. Using ferroelectric Pb(Zr$_{0.3}$Ti$_{0.7}$)O$_{3}$ (PZT), we demonstrate ultra-low voltage operation of graphene field effect transistors within $\pm1$ V with maximum doping exceeding $10^{13}\,\mathrm{cm^{-2}}$ and on-off ratios larger than 10 times. After polarizing PZT, switching of graphene field effect transistors are characterized by pronounced resistance hysteresis, suitable for ultra-fast non-volatile electronics.

preprint2010arXiv

30 inch Roll-Based Production of High-Quality Graphene Films for Flexible Transparent Electrodes

We report that 30-inch scale multiple roll-to-roll transfer and wet chemical doping considerably enhance the electrical properties of the graphene films grown on roll-type Cu substrates by chemical vapor deposition. The resulting graphene films shows a sheet resistance as low as ~30 Ohm/sq at ~90 % transparency which is superior to commercial transparent electrodes such as indium tin oxides (ITO). The monolayer of graphene shows sheet resistances as low as ~125 Ohm/sq with 97.4% optical transmittance and half-integer quantum Hall effect, indicating the high-quality of these graphene films. As a practical application, we also fabricated a touch screen panel device based on the graphene transparent electrodes, showing extraordinary mechanical and electrical performances.

preprint2010arXiv

Graphene field effect transistors with ferroelectric gating

Recent experiments on ferroelectric gating have introduced a novel functionality, i.e. nonvolatility, in graphene field effect transistors. A comprehensive understanding in the non-linear, hysteretic ferroelectric gating and an effective way to control it are still absent. In this letter, we quantitatively characterize the hysteretic ferroelectric gating using the reference of an independent background doping (nBG) provided by normal dielectric gating. More importantly, we prove that nBG can be used to control the ferroelectric gating by unidirectionally shifting the hysteretic ferroelectric doping in graphene. Utilizing this electrostatic effect, we demonstrate symmetrical bit writing in graphene-ferroelectric FETs with resistance change over 500% and reproducible no-volatile switching over 10^5 cycles.

preprint2010arXiv

Lifshitz theory of van der Waals pressure in dissipative media

We derive a first--principles method of determining the van der Waals or Casimir pressure in a dissipative and dispersive planar multilayered system by calculating the Maxwell stress tensor in a fictitious layer of vacuum, that is eventually made to vanish, introduced in the structure. This is illustrated by calculating the van der Waals pressure in a thin film with dissipative properties embedded between two semi--infinite media.

preprint2004arXiv

Collective molecule formation in a degenerate Fermi gas via a Feshbach resonance

We model collisionless collective conversion of a degenerate Fermi gas into bosonic molecules via a Feshbach resonance, treating the bosonic molecules as a classical field and seeding the pairing amplitudes with random phases. A dynamical instability of the Fermi sea against association into molecules initiates the conversion. The model qualitatively reproduces several experimental observations {[Regal et al., Nature {\bf 424}, 47 (2003)]}. We predict that the initial temperature of the Fermi gas sets the limit for the efficiency of atom-molecule conversion.