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Published work

44 published item(s)

preprint2026arXiv

Offline Two-Player Zero-Sum Markov Games with KL Regularization

We study the problem of learning Nash equilibria in offline two-player zero-sum Markov games. While existing approaches often rely on explicit pessimism to address distribution shift, we show that KL regularization alone suffices to stabilize learning and guarantee convergence. We first introduce Regularized Offline Sequential Equilibrium (ROSE), a theoretical framework that achieves a fast $\widetilde{\mathcal{O}}(1/n)$ convergence rate under \textit{unilateral concentrability}, improving over the standard $\widetilde{\mathcal{O}}(1/\sqrt{n})$ rates in unregularized settings. We then propose Sequential Offline Self-play Mirror Descent (SOS-MD), a practical model-free algorithm based on least-squares value estimation and iterative self-play updates. We prove that the last iterate of SOS-MD attains the same $\widetilde{\mathcal{O}}(1/n)$ statistical rate up to a vanishing optimization error of order $\widetilde{\mathcal{O}}(1/\sqrt{T})$ in the number of self-play iterations $T$.

preprint2026arXiv

Out-of-Distribution Semantic Occupancy Prediction

3D semantic occupancy prediction is crucial for autonomous driving, providing a dense, semantically rich environmental representation. However, existing methods focus on in-distribution scenes, making them susceptible to Out-of-Distribution (OoD) objects and long-tail distributions, which increases the risk of undetected anomalies and misinterpretations, posing safety hazards. To address these challenges, we introduce Out-of-Distribution Semantic Occupancy Prediction, targeting OoD detection in 3D voxel space. To fill dataset gaps, we propose a Realistic Anomaly Augmentation that injects synthetic anomalies while preserving realistic spatial and occlusion patterns, enabling the creation of two datasets: VAA-KITTI and VAA-KITTI-360. Then, a novel framework that integrates OoD detection into 3D semantic occupancy prediction, OccOoD, is proposed, which uses Cross-Space Semantic Refinement (CSSR) to refine semantic predictions from complementary voxel and BEV representations, improving OoD detection. Experimental results demonstrate that OccOoD achieves state-of-the-art OoD detection with an AuROC of 65.50% and an AuPRCr of 31.83 within a 1.2m region, while maintaining competitive semantic occupancy prediction performance and generalization in real-world urban driving scenes. The established datasets and source code will be made publicly available at https://github.com/7uHeng/OccOoD.

preprint2026arXiv

Pessimism-Free Offline Learning in General-Sum Games via KL Regularization

Offline multi-agent reinforcement learning in general-sum settings is challenged by the distribution shift between logged datasets and target equilibrium policies. While standard methods rely on manual pessimistic penalties, we demonstrate that KL regularization suffices to stabilize learning and achieve equilibrium recovery. We propose General-sum Anchored Nash Equilibrium (GANE), which recovers regularized Nash equilibria at an accelerated statistical rate of $\widetilde{O}(1/n)$. For computational tractability, we develop General-sum Anchored Mirror Descent (GAMD), an iterative algorithm converging to a Coarse Correlated Equilibrium at the standard rate of $\widetilde{O}(1/\sqrt{n}+1/T)$. These results establish KL regularization as a standalone mechanism for pessimism-free offline learning that achieves equivalent or accelerated rates in multi-player general-sum games.

preprint2026arXiv

Rethinking Importance Sampling in LLM Policy Optimization: A Cumulative Token Perspective

Reinforcement learning, including reinforcement learning with verifiable rewards (RLVR), has emerged as a powerful approach for LLM post-training. Central to these approaches is the design of the importance sampling (IS) ratio used in off-policy policy-gradient estimation. Existing methods face a fundamental bias-variance dilemma: token-level IS ratios, as adopted by PPO (Schulman et al., 2017) and GRPO (Shao et al., 2024), introduce bias by ignoring prefix state distribution mismatch; full sequence ratios provide exact trajectory-level correction but suffer from high variance due to the multiplicative accumulation of per-token ratios, while GSPO (Zheng et al., 2025) improves numerical stability via length normalization at the cost of deviating from the exact full-sequence IS correction. In this work, we identify the cumulative token IS ratio, the product of per-token ratios up to position $t$, as a theoretically principled solution to this dilemma. We prove that, under the token-level policy-gradient formulation, this ratio provides an unbiased prefix correction for each token-level gradient term and has strictly lower variance than the full sequence ratio. Building on this insight, we propose CTPO (Cumulative Token Policy Optimization), which combines the cumulative token IS ratio with position-adaptive clipping that scales log-space clip bounds according to the natural $\sqrt{t}$ growth of the cumulative log-ratio. This yields more consistent regularization across token positions. We implement and evaluate CTPO in the tool-integrated reasoning setting on several challenging mathematical reasoning benchmarks, achieving the best average performance across both model scales compared with strong GRPO and GSPO baselines. Code will be available at https://github.com/horizon-llm/CTPO.

preprint2026arXiv

TagSpeech: End-to-End Multi-Speaker ASR and Diarization with Fine-Grained Temporal Grounding

We present TagSpeech, a unified LLM-based framework that utilizes Temporal Anchor Grounding for joint multi-speaker ASR and diarization. The framework is built on two key designs: (1) decoupled semantic and speaker streams fine-tuned via Serialized Output Training (SOT) to learn turn-taking dynamics; and (2) an interleaved time anchor mechanism that not only supports fine-grained timestamp prediction but also acts as a synchronization signal between semantic understanding and speaker tracking. Compared to previous works that primarily focus on speaker-attributed ASR or implicit diarization, TagSpeech addresses the challenge of fine-grained speaker-content alignment and explicitly models "who spoke what and when" in an end-to-end manner. Experiments on AMI and AliMeeting benchmarks demonstrate that our method achieves consistent improvements in Diarization Error Rate (DER) over strong end-to-end baselines, including Qwen-Omni and Gemini, particularly in handling complex speech overlaps. Moreover, TagSpeech employs a parameter-efficient training paradigm in which the LLM backbone is frozen and only lightweight projectors are trained, resulting in strong performance with low computational cost.

preprint2024arXiv

The Dust Attenuation Scaling Relation of Star-Forming Galaxies in the EAGLE Simulations

Dust attenuation in star-forming galaxies (SFGs), as parameterized by the infrared excess (IRX $\equiv L_{\rm IR}/L_{\rm UV}$), is found to be tightly correlated with star formation rate (SFR), metallicity and galaxy size, following a universal IRX relation up to $z=3$. This scaling relation can provide a fundamental constraint for theoretical models to reconcile galaxy star formation, chemical enrichment, and structural evolution across cosmic time. We attempt to reproduce the universal IRX relation over $0.1\leq z\leq 2.5$ using the EAGLE hydrodynamical simulations and examine sensitive parameters in determining galaxy dust attenuation. Our findings show that while the predicted universal IRX relation from EAGLE approximately aligns with observations at $z\leq 0.5$, noticeable disparities arise at different stellar masses and higher redshifts. Specifically, we investigate how modifying various galaxy parameters can affect the predicted universal IRX relation in comparison to the observed data. We demonstrate that the simulated gas-phase metallicity is the critical quantity for the shape of the predicted universal IRX relation. We find that the influence of the infrared luminosity and infrared excess is less important while galaxy size has virtually no significant effect. Overall, the EAGLE simulations are not able to replicate some of the observed characteristics between IRX and galaxy parameters of SFGs, emphasizing the need for further investigation and testing for our current state-of-the-art theoretical models.

preprint2023arXiv

Improved Algorithms for Neural Active Learning

We improve the theoretical and empirical performance of neural-network(NN)-based active learning algorithms for the non-parametric streaming setting. In particular, we introduce two regret metrics by minimizing the population loss that are more suitable in active learning than the one used in state-of-the-art (SOTA) related work. Then, the proposed algorithm leverages the powerful representation of NNs for both exploitation and exploration, has the query decision-maker tailored for $k$-class classification problems with the performance guarantee, utilizes the full feedback, and updates parameters in a more practical and efficient manner. These careful designs lead to an instance-dependent regret upper bound, roughly improving by a multiplicative factor $O(\log T)$ and removing the curse of input dimensionality. Furthermore, we show that the algorithm can achieve the same performance as the Bayes-optimal classifier in the long run under the hard-margin setting in classification problems. In the end, we use extensive experiments to evaluate the proposed algorithm and SOTA baselines, to show the improved empirical performance.

preprint2022arXiv

A Model-Adaptive Clustering Method for Low-Carbon Energy System Optimization

Intermittent renewable energy resources like wind and solar pose great uncertainty of multiple time scales, from minutes to years, on the design and operation of power systems. Energy system optimization models have been developed to find the least-cost solution to matching the uncertainty with flexibility resources. However, input data that capture such multi-time-scale uncertainty are characterized with a long time horizon and bring great difficulty to solving the optimization model. Here we propose an adaptive clustering method based on the decision variables of optimization model to alleviate the computational complexity, in which the energy system is optimized over selected representative time periods instead of the full time horizon. The proposed clustering method is adaptive to various energy system optimization models or settings, because it extracts features from the optimization models. Results show that the proposed clustering method can significantly lower the error in approximating the solution with the full time horizon, compared to traditional clustering methods.

preprint2022arXiv

Long-term variation of population exposure to PM2.5 in Eastern China: A perspective from SDG 11.6.2

Air pollution (e.g., PM2.5) has a negative effect on human health. Recently, the population-weighted annual mean PM2.5 concentration (PWAM) has been selected as an indicator 11.6.2 in Sustainable Development Goals (SDGs), for various countries to perfrom a long-term monitoring of population exposure to PM2.5 in cities. However, few studies have employed this indicator for a city-level analysis and also in a long-time series (e.g., for decades). To fill this research gap, this study investigates the long-term (2000-2020) variation of population exposure to PM2.5 in Eastern China (including 318 prefecture-level cities). Three categories of open geospatial data (including high-resolution and long-term PM2.5 and population data, and administrative boundary data of cities) are involved for analysis. We found that: 1) A considerable decrease has been observed for the PWAM during 2014-2020. 2) In 2020, the PWAM is for the first time lower than the interim target-1 (35 μg/m3) defined by the World Health Organization for 214 prefecture-level cities in Eastern China, which accounts for 67% of the total population. The results indicates a considerable improvement of air quality in Eastern China. More important, this study illustrates the feasibility of using open geospatial data to monitor the SDG indicator 11.6.2.

preprint2022arXiv

Streaming Algorithms with Large Approximation Factors

We initiate a broad study of classical problems in the streaming model with insertions and deletions in the setting where we allow the approximation factor $α$ to be much larger than $1$. Such algorithms can use significantly less memory than the usual setting for which $α= 1+ε$ for an $ε\in (0,1)$. We study large approximations for a number of problems in sketching and streaming and the following are some of our results. For the $\ell_p$ norm/quasinorm $\|x\|_p$ of an $n$-dimensional vector $x$, $0 < p \le 2$, we show that obtaining a $\poly(n)$-approximation requires the same amount of memory as obtaining an $O(1)$-approximation for any $M = n^{Θ(1)}$. For estimating the $\ell_p$ norm, $p > 2$, we show an upper bound of $O(n^{1-2/p} (\log n \allowbreak \log M)/α^{2})$ bits for an $α$-approximation, and give a matching lower bound, for almost the full range of $α\geq 1$ for linear sketches. For the $\ell_2$-heavy hitters problem, we show that the known lower bound of $Ω(k \log n\log M)$ bits for identifying $(1/k)$-heavy hitters holds even if we are allowed to output items that are $1/(αk)$-heavy, for almost the full range of $α$, provided the algorithm succeeds with probability $1-O(1/n)$. We also obtain a lower bound for linear sketches that is tight even for constant probability algorithms. For estimating the number $\ell_0$ of distinct elements, we give an $n^{1/t}$-approximation algorithm using $O(t\log \log M)$ bits of space, as well as a lower bound of $Ω(t)$ bits, both excluding the storage of random bits.

preprint2022arXiv

Submillimetre galaxies in two massive protoclusters at z = 2.24: witnessing the enrichment of extreme starbursts in the outskirts of HAE density peaks

Submillimetre galaxies represent a rapid growth phase of both star formation and massive galaxies. Mapping SMGs in galaxy protoclusters provides key insights into where and how these extreme starbursts take place in connections with the assembly of the large-scale structure in the early Universe. We search for SMGs at 850$\,μm$ using JCMT/SCUBA-2 in two massive protoclusters at $z=2.24$, BOSS1244 and BOSS1542, and detect 43 and 54 sources with $S_{850}>4\,$mJy at the $4σ$ level within an effective area of 264$\,$arcmin$^2$, respectively. We construct the intrinsic number counts and find that the abundance of SMGs is $2.0\pm0.3$ and $2.1\pm0.2$ times that of the general fields, confirming that BOSS1244 and BOSS1542 contain a higher fraction of dusty galaxies with strongly enhanced star formation. The volume densities of the SMGs are estimated to be $\sim15-$30 times the average, significantly higher than the overdensity factor ($\sim 6$) traced by H$α$ emission-line galaxies (HAEs). More importantly, we discover a prominent offset between the spatial distributions of the two populations in these two protoclusters -- SMGs are mostly located around the high-density regions of HAEs, and few are seen inside these regions. This finding may have revealed for the first time the occurrence of violent star formation enhancement in the outskirts of the HAE density peaks, likely driven by the boosting of gas supplies and/or starburst triggering events. Meanwhile, the lack of SMGs inside the most overdense regions at $z\sim2$ implies a transition to the environment disfavouring extreme starbursts.

preprint2022arXiv

Systematic biases in determining dust attenuation curves through galaxy SED fitting

While the slope of the dust attenuation curve ($δ$) is found to correlate with effective dust attenuation ($A_V$) as obtained through spectral energy distribution (SED) fitting, it remains unknown how the fitting degeneracies shape this relation. We examine the degeneracy effects by fitting SEDs of a sample of local star-forming galaxies (SFGs) selected from the Galaxy And Mass Assembly survey, in conjunction with mock galaxy SEDs of known attenuation parameters. A well-designed declining starburst star formation history is adopted to generate model SED templates with intrinsic UV slope ($β_0$) spanning over a reasonably wide range. The best-fitting $β_0$ for our sample SFGs shows a wide coverage, dramatically differing from the limited range of $β_0<-2.2$ for a starburst of constant star formation. Our results show that strong degeneracies between $β_0$, $δ$, and $A_V$ in the SED fitting induce systematic biases leading to a false $A_V$--$δ$ correlation. Our simulation tests reveal that this relationship can be well reproduced even when a flat $A_V$--$δ$ relation is taken to build the input model galaxy SEDs. The variations in best-fitting $δ$ are dominated by the fitting errors. We show that assuming a starburst with constant star formation in SED fitting will result in a steeper attenuation curve, smaller degeneracy errors, and a stronger $A_V$--$δ$ relation. Our findings confirm that the $A_V$--$δ$ relation obtained through SED fitting is likely driven by the systematic biases induced by the fitting degeneracies between $β_0$, $δ$, and $A_V$.

preprint2021arXiv

Convolutional Ordinal Regression Forest for Image Ordinal Estimation

Image ordinal estimation is to predict the ordinal label of a given image, which can be categorized as an ordinal regression problem. Recent methods formulate an ordinal regression problem as a series of binary classification problems. Such methods cannot ensure that the global ordinal relationship is preserved since the relationships among different binary classifiers are neglected. We propose a novel ordinal regression approach, termed Convolutional Ordinal Regression Forest or CORF, for image ordinal estimation, which can integrate ordinal regression and differentiable decision trees with a convolutional neural network for obtaining precise and stable global ordinal relationships. The advantages of the proposed CORF are twofold. First, instead of learning a series of binary classifiers \emph{independently}, the proposed method aims at learning an ordinal distribution for ordinal regression by optimizing those binary classifiers \emph{simultaneously}. Second, the differentiable decision trees in the proposed CORF can be trained together with the ordinal distribution in an end-to-end manner. The effectiveness of the proposed CORF is verified on two image ordinal estimation tasks, i.e. facial age estimation and image aesthetic assessment, showing significant improvements and better stability over the state-of-the-art ordinal regression methods.

preprint2020arXiv

Improving Robustness to Model Inversion Attacks via Mutual Information Regularization

This paper studies defense mechanisms against model inversion (MI) attacks -- a type of privacy attacks aimed at inferring information about the training data distribution given the access to a target machine learning model. Existing defense mechanisms rely on model-specific heuristics or noise injection. While being able to mitigate attacks, existing methods significantly hinder model performance. There remains a question of how to design a defense mechanism that is applicable to a variety of models and achieves better utility-privacy tradeoff. In this paper, we propose the Mutual Information Regularization based Defense (MID) against MI attacks. The key idea is to limit the information about the model input contained in the prediction, thereby limiting the ability of an adversary to infer the private training attributes from the model prediction. Our defense principle is model-agnostic and we present tractable approximations to the regularizer for linear regression, decision trees, and neural networks, which have been successfully attacked by prior work if not attached with any defenses. We present a formal study of MI attacks by devising a rigorous game-based definition and quantifying the associated information leakage. Our theoretical analysis sheds light on the inefficacy of DP in defending against MI attacks, which has been empirically observed in several prior works. Our experiments demonstrate that MID leads to state-of-the-art performance for a variety of MI attacks, target models and datasets.

preprint2020arXiv

Ordinal Distribution Regression for Gait-based Age Estimation

Computer vision researchers prefer to estimate age from face images because facial features provide useful information. However, estimating age from face images becomes challenging when people are distant from the camera or occluded. A person's gait is a unique biometric feature that can be perceived efficiently even at a distance. Thus, gait can be used to predict age when face images are not available. However, existing gait-based classification or regression methods ignore the ordinal relationship of different ages, which is an important clue for age estimation. This paper proposes an ordinal distribution regression with a global and local convolutional neural network for gait-based age estimation. Specifically, we decompose gait-based age regression into a series of binary classifications to incorporate the ordinal age information. Then, an ordinal distribution loss is proposed to consider the inner relationships among these classifications by penalizing the distribution discrepancy between the estimated value and the ground truth. In addition, our neural network comprises a global and three local sub-networks, and thus, is capable of learning the global structure and local details from the head, body, and feet. Experimental results indicate that the proposed approach outperforms state-of-the-art gait-based age estimation methods on the OULP-Age dataset.

preprint2020arXiv

The Secret Revealer: Generative Model-Inversion Attacks Against Deep Neural Networks

This paper studies model-inversion attacks, in which the access to a model is abused to infer information about the training data. Since its first introduction, such attacks have raised serious concerns given that training data usually contain privacy-sensitive information. Thus far, successful model-inversion attacks have only been demonstrated on simple models, such as linear regression and logistic regression. Previous attempts to invert neural networks, even the ones with simple architectures, have failed to produce convincing results. We present a novel attack method, termed the generative model-inversion attack, which can invert deep neural networks with high success rates. Rather than reconstructing private training data from scratch, we leverage partial public information, which can be very generic, to learn a distributional prior via generative adversarial networks (GANs) and use it to guide the inversion process. Moreover, we theoretically prove that a model's predictive power and its vulnerability to inversion attacks are indeed two sides of the same coin---highly predictive models are able to establish a strong correlation between features and labels, which coincides exactly with what an adversary exploits to mount the attacks. Our extensive experiments demonstrate that the proposed attack improves identification accuracy over the existing work by about 75\% for reconstructing face images from a state-of-the-art face recognition classifier. We also show that differential privacy, in its canonical form, is of little avail to defend against our attacks.

preprint2016arXiv

Dominant itinerant ferromagnetism in Eu0.5Sr0.5CoO3: evidences from both critical analysis and Rhodes-Wohlfarth's criterion

The critical behaviors of ferromagnet Eu0.5Sr0.5CoO3 arround TC=140.5K have been comprehensively investigated by analyzing a series of isothermal magnetization M(H) curves. Both Modified Arrott plot and Kouvel-Fisher methods give nearly the same critical exponents, which scale nicely the M(H) curves into two different branches below and above TC. The exponents γ=1.044 and δ=3.06 demonstrate the relevance of mean-field characters for this material. The conclusion of mean-field behavior proves a dominant itinerant ferromagnetism (FM) due to a long range exchange interaction in the system. Meanwhile, by using Rhodes-Wohlfarth's criterion [P. Rhodes and E. P. Wohlfarth, Proc. R. Soc. Lond. A 273, 247 (1963)], it is further confirmed that the itinerant FM dominates in the system.

preprint2016arXiv

Pressure induced re-emergence of superconductivity in superconducting topological insulator Sr0.065Bi2Se3

The recent-discovered Sr$_x$Bi$_2$Se$_3$ superconductor provides an alternative and ideal material base for investigating possible topological superconductivity. Here, we report that in Sr$_{0.065}$Bi$_{2}$Se$_3$, the ambient superconducting phase is gradually depressed upon the application of external pressure. At high pressure, a second superconducting phase emerges at above 6 GPa, with a maximum $T_c$ value of $\sim$8.3 K. The joint investigations of the high-pressure synchrotron x-ray diffraction and electrical transport properties reveal that the re-emergence of superconductivity in Sr$_{0.065}$Bi$_{2}$Se$_3$ is closely related to the structural phase transition from ambient rhombohedral phase to high-pressure monoclinic phase around 6 GPa, and further to another high-pressure tetragonal phase above 25 GPa.

preprint2016arXiv

Single Crystal Growth of the New Pressure-induced-superconductor CrAs via Chemical Vapor Transport

Mono-arsenide CrAs, endures a helical anti-ferromagnetic order transition at~ 265 K under ambient pressure. Recently, pressure-induced-superconductivity was discovered vicinity to the helical anti-ferromagnetic order in CrAs[Wei Wu et al., Nature Communications 5, 5508 (2014).]. However, the size of crystal grown via tin flux method is as small as 1 mm in longest dimension. In this work, we report the single crystal growth of CrAs with size of 1 * 5 * 1 mm3 via chemical vapor transport method and its physical properties.

preprint2016arXiv

Superconductivity and Charge Density Wave in ZrTe$_{3-x}$Se$_{x}$

Charge density wave (CDW), the periodic modulation of the electronic charge density, will open a gap on the Fermi surface that commonly leads to decreased or vanishing conductivity. On the other hand superconductivity, a commonly believed competing order, features a Fermi surface gap that results in infinite conductivity. Here we report that superconductivity emerges upon Se doping in CDW conductor ZrTe$_{3}$ when the long range CDW order is gradually suppressed. Superconducting critical temperature $T_c(x)$ in ZrTe$_{3-x}$Se$_x$ (${0\leq}x\leq0.1$) increases up to 4 K plateau for $0.04$$\leq$$x$$\leq$$0.07$. Further increase in Se content results in diminishing $T_{c}$ and filametary superconductivity. The CDW modes from Raman spectra are observed in $x$ = 0.04 and 0.1 crystals, where signature of ZrTe$_{3}$ CDW order in resistivity vanishes. The electronic-scattering for high $T_{c}$ crystals is dominated by local CDW fluctuations at high temperures, the resistivity is linear up to highest measured $T=300K$ and contributes to substantial in-plane anisotropy.

preprint2016arXiv

Transport evidence for the three-dimensional Dirac semimetal phase in ZrTe5

Topological Dirac semimetal is a newly discovered class of materials and has attracted intense attentions. This material can be viewed as a three-dimensional (3D) analogue of graphene and has linear energy dispersion in bulk, leading to a range of exotic transport properties. Here we report direct quantum transport evidence of 3D Dirac semimetal phase of layered material ZrTe5 by angular dependent magnetoresistance measurements under high magnetic fields up to 31 Tesla. We observed very clear negative longitudinal magnetoresistance induced by chiral anomaly under the condition of the magnetic field aligned only along the current direction. Pronounced Shubnikov-de Hass (SdH) quantum oscillations in both longitudinal magnetoresistance and transverse Hall resistance were observed, revealing anisotropic light cyclotron masses and high mobility of the system. In particular, a nontrivial π-Berry phase in the SdH gives clear evidence for 3D Dirac semimetal phase. Furthermore, we observed clear Landau Level splitting under high magnetic field, suggesting possible splitting of Dirac point into Weyl points due to broken time reversal symmetry. Our results indicate that ZrTe5 is an ideal platform to study 3D massless Dirac and Weyl fermions in a layered compound.

preprint2016arXiv

Weak localization effect in topological insulator micro flakes grown on insulating ferrimagnet BaFe12O19

Many exotic physics anticipated in topological insulators require a gap to be opened for their topologica surface states by breaking time reversal symmetry. The gap opening has been achieved by doping magnetic impurities, which however inevitably create extra carriers and disorder that undermine the electronic transport. In contrast, the proximity to a ferromagnetic/ferrimagnetic insulator may improve the device quality, thus promises a better way to open the gap while minimizing the side-effects. Here, we grow thin single-crystal Sb1.9Bi0.1Te3 micro flakes on insulating ferrimagnet BaFe12O19 by using the van der Waals epitaxy technique. The micro flakes show a negative magnetoresistance in weak perpendicular fields below 50 K, which can be quenched by increasing temperature. The signature implies the weak localization effect as its origin, which is absent in intrinsic topological insulators, unless a surface state gap is opened. The surface state gap is estimated to be 10 meV by using the theory of the gap-induced weak localization effect. These results indicate that the magnetic proximity effect may open the gap for the topological surface attached to BaM insulating ferrimagnet. This heterostructure may pave the way for the realization of new physical effects as well as the potential applications of spintronics devices.

preprint2015arXiv

A new topological semimetal with iso-energetic Weyl fermions in TaAs under high pressure

TaAs as one of the experimentally discovered topological Weyl semimetal has attracted intense interests recently. The ambient TaAs has two types of Weyl nodes which are not on the same energy level. As an effective way to tune lattice parameters and electronic interactions, high pressure is becoming a significant tool to explore new materials as well as their exotic states. Therefore, it is highly interesting to investigate the behaviors of topological Weyl fermions and possible structural phase transitions in TaAs under pressure. Here, with a combination of ab initio calculations and crystal structure prediction techniques, a new hexagonal P-6m2 phase is predicted in TaAs at pressure around 14 GPa. Surprisingly, this new phase is a topological semimetal with only single set of Weyl nodes exactly on the same energy level. The phase transition pressure from the experimental measurements, including electrical transport measurements and Raman spectroscopy, agrees with our theoretical prediction reasonably. Moreover, the P-6m2 phase seems to be quenched recoverable to ambient pressure, which increases the possibilities of further study on the exotic behaviors of single set of Weyl fermions, such as the interplay between surface states and other properties.

preprint2015arXiv

Edge-Mediated Skyrmion Chain and Its Collective Dynamics in a Confined Geometry

The emergence of a topologically nontrivial vortex-like magnetic structure, the magnetic skyrmion, has launched new concepts for memory devices. There, extensive studies have theoretically demonstrated the ability to encode information bits by using a chain of skyrmions in one-dimensional nanostripes. Here, we report the first experimental observation of the skyrmion chain in FeGe nanostripes by using high resolution Lorentz transmission electron microscopy. Under an applied field normal to the nanostripes plane, we observe that the helical ground states with distorted edge spins would evolves into individual skyrmions, which assemble in the form of chain at low field and move collectively into the center of nanostripes at elevated field. Such skyrmion chain survives even as the width of nanostripe is much larger than the single skyrmion size. These discovery demonstrates new way of skyrmion formation through the edge effect, and might, in the long term, shed light on the applications.

preprint2015arXiv

Electrical Probing of Field-Driven Cascading Quantized Transitions of Skyrmion Cluster States in MnSi Nanowires

Magnetic skyrmions are topologically stable whirlpool-like spin textures that offer great promise as information carriers for future ultra-dense memory and logic devices1-4. To enable such applications, particular attention has been focused on the skyrmions properties in highly confined geometry such as one dimensional nanowires5-8. Hitherto it is still experimentally unclear what happens when the width of the nanowire is comparable to that of a single skyrmion. Here we report the experimental demonstration of such scheme, where magnetic field-driven skyrmion cluster (SC) states with small numbers of skyrmions were demonstrated to exist on the cross-sections of ultra-narrow single-crystal MnSi nanowires (NWs) with diameters, comparable to the skyrmion lattice constant (18 nm). In contrast to the skyrmion lattice in bulk MnSi samples, the skyrmion clusters lead to anomalous magnetoresistance (MR) behavior measured under magnetic field parallel to the NW long axis, where quantized jumps in MR are observed and directly associated with the change of the skyrmion number in the cluster, which is supported by Monte Carlo simulations. These jumps show the key difference between the clustering and crystalline states of skyrmions, and lay a solid foundation to realize skyrmion-based memory devices that the number of skyrmions can be counted via conventional electrical measurements.

preprint2015arXiv

Pressure-driven dome-shaped superconductivity and electronic structural evolution in tungsten ditelluride

Tungsten ditelluride has attracted intense research interest due to the recent discovery of its large unsaturated magnetoresistance up to 60 Tesla. Motivated by the presence of a small, sensitive Fermi surface of 5d electronic orbitals, we boost the electronic properties by applying a high pressure, and introduce superconductivity successfully. Superconductivity sharply appears at a pressure of 2.5 GPa, rapidly reaching a maximum critical temperature (Tc) of 7 K at around 16.8 GPa, followed by a monotonic decrease in Tc with increasing pressure, thereby exhibiting the typical dome-shaped superconducting phase. From theoretical calculations, we interpret the low-pressure region of the superconducting dome to an enrichment of the density of states at the Fermi level and attribute the high-pressure decrease in Tc to possible structural instability. Thus, Tungsten ditelluride may provide a new platform for our understanding of superconductivity phenomena in transition metal dichalcogenides.

preprint2015arXiv

Pressure-induced semimetal to superconductor transition in a three-dimensional topological material ZrTe5

As a new type of topological materials, ZrTe5 shows many exotic properties under extreme conditions. Utilizing resistance and ac magnetic susceptibility measurements under high pressure, while the resistance anomaly near 128 K is completely suppressed at 6.2 GPa, a fully superconducting transition emerges surprisingly. The superconducting transition temperature Tc increases with applied pressure, and reaches a maximum of 4.0 K at 14.6 GPa, followed by a slight drop but remaining almost constant value up to 68.5 GPa. At pressures above 21.2 GPa, a second superconducting phase with the maximum Tc of about 6.0 K appears and coexists with the original one to the maximum pressure studied in this work. In situ high-pressure synchrotron X-ray diffraction and Raman spectroscopy combined with theoretical calculations indicate the observed two-stage superconducting behavior is correlated to the structural phase transition from ambient Cmcm phase to high-pressure C2/m phase around 6 GPa, and to a mixture of two high-pressure phases of C2/m and P-1 above 20 GPa. The combination of structure, transport measurement and theoretical calculations enable a complete understanding of the emerging exotic properties in three-dimensional topological materials happened under extreme environments.

preprint2015arXiv

Robust linear magnetoresistance in WTe2

Unsaturated magnetoresistance (MR) has been reported in WTe2, and remains irrepressible up to very high field. Intense optimization of the crystalline quality causes a squarely-increasing MR, as interpreted by perfect compensation of opposite carriers. Herein we report our observation of linear MR (LMR) in WTe2 crystals, the onset of which is first identified by constructing the mobility spectra of the MR at low fields. The LMR further intensifies and predominates at fields higher than 20 Tesla while the parabolic MR gradually decays. The LMR remains unsaturated up to a high field of 60 Tesla and persists, even at a high pressure of 6.2 GPa. Assisted by density functional theory calculations and detailed mobility spectra, we find the LMR to be robust against the applications of high field, broken carrier balance, and mobility suppression. Angle-resolved photoemission spectroscopy reveals a unique quasilinear energy dispersion near the Fermi level. Our results suggest that the robust LMR is the low bound of the unsaturated MR in WTe2.

preprint2015arXiv

Superconductivity with topological surface state in SrxBi2Se3

By intercalation of alkaline-earth metal Sr in Bi2Se3, superconductivity with large shielding volume fraction (~91.5% at 0.5 K) has been achieved in Sr0.065Bi2Se3. The analysis of the Shubnikov-de Hass oscillations confirms the 1/2-shift expected from a Dirac spectrum, giving transport evidence of the existence of surface states. Importantly, the SrxBi2Se3superconductor is stable under air, making the SrxBi2Se3 compound an ideal material base for investigating topological superconductivity.

preprint2014arXiv

Bulk superconductivity in single phase Bi3O2S3

We report the synthesis of single phase Bi3O2S3 sample and confirm the occurrence of bulk superconductivity with transition temperature at 5.8 K. The Bi3O2S3 super-conductor is categorized as the typical type-II supercon-ductor based on the results of both temperature and mag-netic field dependences of magnetization. Hall coefficient measurements give evidence of a multiband character, with a dominant conduction mainly by electron-like charge carriers. The charge carrier density is about 1.45 X 1019 cm3, suggesting that the system has very low charge carrier density.

preprint2014arXiv

Evidence of topological two-dimensional metallic surface states in thin bismuth nanoribbons

Understanding of the exotic quantum phenomena in bulk bismuth beyond its ultraquantum limit still remains controversial and gives rise to a renewed interest. The focus of the issues is whether these quantum properties have a conventional bulk nature or just the surface effect due to the significant spin-orbital interaction and in relation to the Bi-based topological insulators. Here, we present angular-dependent magnetoresistance (AMR) measurements on single-crystal bismuth nanoribbons of different thickness with magnetic fields up to 31 T. In thin nanoribbons with thickness of ~40 nm, a two-fold rational symmetry of the low field AMR spectra and two sets of 1/2-shifted (i.e. γ=1/2) Shubnikov-de Haas (SdH) quantum oscillations with exact two- dimensional (2D) character were obtained. However, when the thickness of the ribbon increases, a 3D bulk-like SdH oscillations with γ=0 and a four-fold rotational symmetry of the AMR spectra appear. These results unambiguously provided the first transport evidence of the topological 2D metallic surface states in thinner nanoribbons with an insulating bulk. Our observations provide a promising pathway to understand the quantum phenomena in Bi arising from the surface states.

preprint2014arXiv

Superconducting properties of novel BiSe$_{2}$-based layered LaO$_{1-x}$F$_{x}$BiSe$_{2}$ single crystals

F-doped LaOBiSe$_{2}$ superconducting single crystals with typical size of 2$\times$4$\times$0.2 mm$^{3}$ are successfully grown by flux method and the superconducting properties are studied. Both the superconducting transition temperature and the shielding volume fraction are effectively improved with fluorine doping. The LaO$_{0.48}$F$_{0.52}$BiSe$_{1.93}$ sample exhibits zero-resistivity at 3.7 K, which is higher than that of the LaO$_{0.5}$F$_{0.5}$BiSe$_{2}$ polycrystalline sample (2.4K). Bulk superconductivity is confirmed by a clear specific-heat jump at the associated temperature. The samples exhibit strong anisotropy and the anisotropy parameter is about 30, as estimated by the upper critical field and effective mass model

preprint2013arXiv

Giant exchange bias in a single-phase magnet with two magnetic sublattices

Exchange bias phenomenon is generally ascribed to the exchange coupling at the interfaces between ferromagnetic and antiferromagnetic layers. Here, we propose a bulk form of exchange bias in a single-phase magnet where the coupling between two magnetic sublattices induces a significant shift of the coercive field after a field cooling. Our experiments in a complicated magnet YbFe2O4 demonstrate a giant exchange bias at low temperature when the coupling between the Yb3+ and Fe2+/Fe3+ sublattices take places. The cooling magnetic field dependence and the training effect of exchange bias are consistent with our model. In strong contrast to conventional interfacial exchange bias, this bulk form of exchange bias can be huge, reaching the order of a few Tesla.

preprint2013arXiv

Oxygen-Vacancy-Induced Antiferromagnetism to Ferromagnetism Transformation in Multiferroic Thin Films

Oxygen vacancies (VOs) effects on magnetic ordering in Eu0.5Ba0.5TiO3-δ (EBTO3-δ) thin films have been investigated using a combination of experimental measurements and first-principles density-functional calculations. Two kinds of EBTO3-δthin films with different oxygen deficiency have been fabricated. A nuclear resonance backscattering spectrometry technique has been used to quantitatively measure contents of the VOs. Eu0.5Ba0.5TiO3 ceramics have been known to exhibit ferroelectric (FE) and G-type antiferromagnetic (AFM) properties. While, a ferromagnetic (FM) behavior with a Curie temperature of 1.85 K has been found in the EBTO3-δ thin films. Spin-polarized Ti3+ ions, which originated from the VOs, has been proven to mediate a FM coupling between the local Eu 4f spins and were believed to be responsible for the great change of the magnetic ordering. Our work opens up a new avenue for developing FM-FE materials by manipulating the oxygen deficiency in AFM-FE multiferroics.

preprint2013arXiv

Single Crystal Growth, Transport, and Electronic Band Structure of YCoGa$_5$

Single crystal of YCoGa5 has been grown via Ga self-flux. In this paper, we report the single crystal growth, crystallographic parameters, resistivity, heat capacity, and band structure results of YCoGa5. YCoGa5 accommodates the HoCoGa5 type structure (space group P4/mmm (No. 123), Z = 1, a = 4.2131(6) A, c = 6.7929(13) A, which is isostructural to the extensively studied heavy fermion superconductor system CeMIn5 (M = Co, Rh, Ir) and the unconventional superconductor PuCoGa5 with Tc = 18.5 K. No superconductivity is observed down to 1.75 K. Band structure calculation results show that its band at the Fermi level is mainly composed of Co-3d and Ga-4p electrons states, which explains its similarity of physical properties to YbCoGa5 and LuCoGa5.

preprint2013arXiv

Spin-phonon coupling probed by infrared transmission spectroscopy in the double perovskite Ba$_2$YMoO$_6$

In this work, we investigate the local structural distortion of the double perovskite Ba$_2$YMoO$_6$ by means of infrared transmission spectroscopy. At 300 K, three bands are observed at $\sim$ 255.1 cm$^{-1}$, $\sim$ 343.4 cm$^{-1}$, and $\sim$ 561.5 cm$^{-1}$, which are related to the motion between the cation Ba$^{2+}$ and the anion YMO$_6^{-2}$, the Y-O stretching motion and the stretching vibration of the MoO$_6$ octahedron, respectively. These modes continue to harden upon cooling owing to the shrink of the lattice constant. When the temperature decreases to $T \leq$ 130 K around which the spin singlet dimer begins to form, an additional phonon mode appears at $\sim$ 611 cm$^{-1}$, suggesting the occurrence of local distortion of MoO$_6$ octahedra. With further decrease of the temperature, its intensity enhances and its peak position keeps unchanged. These results indicate that the formation of the spin singlet dimers is accompanied with the occurrence of the local structure distortion of MoO$_6$ octahedra, providing evidence for the strong spin-phonon coupling in the double perovskite Ba$_2$YMoO$_6$.

preprint2013arXiv

Superconducting fiber with transition temperature up to 7.43 K in Nb2PdxS5-delta (0< x <0.6)

Wiring systems powered by high-efficient superconductors have long been a dream of scientists, but researchers have faced practical challenges such as finding flexible materials. Here we report superconductivity in Nb2PdxS5-delta fibers with transition temperature up to 7.43 K, which have typical diameters of 0.3-3 micrometer. Superconductivity occurs in a wide range of Pd and S contents, suggesting that the superconductivity in this system is very robust. Long fibers with suitable size provide a new route to high-power transmission cables and electronic devices.

preprint2013arXiv

The effect of Al doping on the structure and magnetism in cobaltite CaBaCo4O7

We report the effects of Al-doping on the structure and magnetic properties in CaBa(Co$_{1-x}$Al$_{x}$)$_4$O$_7$ (0$\leq$x$\leq$0.25). The system exhibits a structural transition from an orthorhombic symmetry to a hexagonal symmetry when the Al content exceeds $x =$ 0.1. The Curie temperature and the value of the magnetization decrease with increasing Al doping level, indicating that the ferrimagnetic ground state is gradually suppressed. The ground state eventually transits into a spin-glass state for $x >$ 0.1. Moreover, the short-range magnetic correlations, which occur at high temperatures in CaBaCo$_4$O$_7$, are found to be gradually suppressed with increasing Al content and eventually disappear for $x =$ 0.25. By comparing our results with other Co-site doping cases, we suggest that the lattice and the spin degrees of freedom are relatively decoupled in CaBaCo$_4$O$_7$.

preprint2012arXiv

Field-Driven Evolution of Chiral Spin Textures in Thin Nanodisk of the Helimagnets

The magnetic field-driven evolution of chiral spin textures in thin helimagnet nanodisk with varied size are investigated by means of Monte Carlo simulation. It is demonstrated that the complex spin texture may simply be regarded as the superposition of the edged state with in plane spin orientation perpendicular or parallel to the edge and the bulk state with the features similar to two-dimensional chiral magnetic films. With the increase of the external field, the proportion of the parallel spins of the edge state increases, and the spin textures finally transfers into edged magnetic vortex. The arrangement of skyrmions strongly depends on the disk size. In addition, the uniaxial anisotropy and dipolar coupling in certain ranges are able to stabilize a special magnetic vortex with Skyrmionic core while the disk size is comparable with the wavelength of helix state.

preprint2012arXiv

Magnetic Vortex with Skyrmionic Core in Thin Nanodisk of the Chiral Magnets

A type of vortex spin texture with skyrmionic core and a series of circle spin stripes was obtained in thin nanodisk of the chiral magnets with Dzyaloshinskii-Moriya interaction and uniaxial anisotropy by means of micromagnetic approach and Monte Carlo simulation. The size of skyrmionic core can be modulated continuously by controlling the disk size. Moreover, in some certain values of the disk size, this vortex state may be spontaneous ground state even without the help of the external magnetic field and thermal fluctuation. In addition, the uniaxial anisotropy is able to stabilize this vortex spin texture. We anticipate that the present work will inspire further experimental studies for exploring the spin structure.

preprint2012arXiv

Surface-induced Magnetism Fluctuations in Single Crystal of NiBi3 Superconductor

We report anistropy in superconducting and normal state of NiBi3 single crystals with Tc = 4.06 K. The magnetoresistance results indicate the absence of scattering usually associated with ferromagnetic metals, suggesting the absence of bulk long range magnetic order below 300 K. However, the electron spin resonance results demonstrate that ferromagnetism fluctuations exist on the surface of the crystal below 150K.

preprint2011arXiv

Magnetic properties of the ferrimagnetic cobaltite CaBaCo4O7

The magnetic properties of the ferrimagnetic cobaltite CaBaCo$_4$O$_7$ are systematically investigated. We find that the susceptibility exhibits a downward deviation below $\sim$ 360 K, suggesting the occurrence of short range magnetic correlations at temperature well above $T_C$. The effective moment is determined to be 4.5 $μ_B$/f.u, which is consistent with that expected for the Co$^{2+}$/Co$^{3+}$ high spin species. Using a criterion given by Banerjee [Phys. Lett. \textbf{12}, 16 (1964)], we demonstrate that the paramagnetic to ferrimagnetic transition in CaBaCo$_4$O$_7$ has a first order character.

preprint2011arXiv

Single crystal growth of BaFe$_{2-x}$Co$_x$As$_2$ without fluxing agent

We report a simple, reliable method to grow high quality BaFe$_{2-x}$Co$_x$As$_2$ single crystal samples without using any fluxing agent. The starting materials for the single crystal growth come from well-crystallized polycrystalline samples and the highest growing temperature can be 1493 K. The as-grown crystals have typical dimensions of 4$\times3\times$0.5 mm$^3$ with c-axis perpendicular to the shining surface. We find that the samples have very large current carrying ability, indicating that the samples have good potential technological applications.

preprint2011arXiv

Spin dynamics in triangular lattice antiferromagnets CuCr$_{1-x}$Mg$_x$O$_2$

The electron spin resonance (ESR) spectroscopy was employed to investigate the spin dynamics in triangular lattice antiferromagnets CuCr$_{1-x}$Mg$_{x}$O$_2$ with $x =$ 0 and 0.02. All spectra can be well fitted by a single Lorentzian lineshape. The analysis of the $g$ factor, the linewidth $\bigtriangleup H$, and the ESR intensity $I$ as a function of temperature suggests the development of significant antiferromagnetic (AFM) spin fluctuations at temperature well above $T_N$ in both samples. However, the evolution of the AFM spin fluctuations is different for each sample. For undoped sample the ESR intensity $I$ is almost temperature independent between $\sim$ 100 K and 50 K and then drops rapidly below 50 K. But for $x =$ 0.02, the $I$ monotonously increases with cooling and reduces rapidly only below $T_N$. These results indicate that the AFM spin fluctuations are extremely strong in the undoped sample and appear to be suppressed upon Mg doping.