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Amit Agarwal

Amit Agarwal contributes to research discovery and scholarly infrastructure.

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Published work

31 published item(s)

preprint2026arXiv

GSM-SEM: Benchmark and Framework for Generating Semantically Variant Augmentations

Benchmarks like GSM8K are popular measures of mathematical reasoning, but leaderboard gains can overstate true capability due to memorization of fixed test sets. Most robustness variants apply surface-level perturbations (paraphrases, renamings, number swaps, distractors) that largely preserve the underlying facts, and static releases can themselves become memorization targets over time. We introduce GSM-SEM, a reusable and stochastic framework for generating semantically diverse benchmark variants with substantially higher semantic variance than prior approaches. GSM-SEM perturbs problem statements by modifying entities, attributes, and/or relationships, frequently altering underlying facts and requiring models to recompute solutions under new conditions, while constraining generation to preserve the original calculations/answer and approximate problem difficulty. GSM-SEM generates fresh variants on each run without requiring re-annotation, reducing reliance on static public benchmarks for evaluation and thereby lowering the bias of memorization. We apply GSM-SEM on GSM8K and two existing variation suites (GSM-Symbolic and GSM-Plus), producing GSM8K-SEM, GSM-Symbolic-SEM, and GSM-Plus-SEM. Evaluating 14 SOTA LLMs, we observe consistent performance drops with larger decline when semantic perturbations are coupled with symbolic/plus variations (average drop rate 28% in maximum strictness configuration of GSM-SEM). We publicly release the three SEM variants as fully human-validated datasets. Finally, to demonstrate applicability beyond GSM-style math problems, we apply GSM-SEM to additional benchmarks including BigBenchHard, LogicBench, and NLR-BIRD.

preprint2026arXiv

Intrinsic Gyrotropic Magnetic Current of Orbital Origin

In gyrotropic crystals, an oscillating magnetic field induces a charge response known as the gyrotropic magnetic current. While its conventional origin is attributed to magnetic field modified band energy and shift in the Fermi-surface, a recent study identified an additional spin-driven magnetic displacement contribution. Here, we complete the picture by identifying the orbital counterpart of the magnetic displacement current. Using a density-matrix formulation that incorporates both minimal coupling and spin-Zeeman interactions, we derive the electronic equations of motion in the presence of an oscillating magnetic field and uncover a previously unexplored orbital contribution to the wavepacket velocity. Physically, this contribution arises from the time variation of the magnetic-field induced charge polarization. In the low frequency transport regime, this mechanism becomes purely intrinsic. We illustrate this intrinsic gyrotropic current of orbital origin in the ${\cal P}{\cal T}$-symmetric antiferromagnet CuMnAs. We show that the intrinsic gyrotropic magnetic current reverses sign upon Néel vector reversal, establishing it as a direct probe of antiferromagnetic order in CuMnAs and other $\mathcal{PT}$-symmetric antiferromagnets.

preprint2026arXiv

LLM-Guided Lifecycle-Aware Clustering of Multi-Turn Customer Support Conversations

Clustering customer chat data is vital for cloud providers handling multi service queries. Traditional methods struggle with overlapping concerns and create broad, static clusters that degrade over time. Reclustering disrupts continuity, making issue tracking difficult. We propose an adaptive system that segments multi turn chats into service specific concerns and incrementally refines clusters as new issues arise. Cluster quality is tracked via DaviesBouldin Index and Silhouette Scores, with LLM based splitting applied only to degraded clusters. Our method improves Silhouette Scores by over 100\% and reduces DBI by 65.6\% compared to baselines, enabling scalable, real time analytics without full reclustering.

preprint2026arXiv

Observation of Time-Reversal Symmetry Breaking in the Type-I Superconductor YbSb$_2$

The spontaneous breaking of time-reversal symmetry is a hallmark of unconventional superconductivity, typically observed in type-II superconductors. Here, we report evidence of time-reversal symmetry breaking in the type-I superconductor YbSb$_2$. Zero-field $μ$SR measurements reveal spontaneous internal magnetic fields emerging just below the superconducting transition, while transverse-field $μ$SR confirms a fully gapped type-I superconducting state. Our first-principles calculations identify YbSb$_2$ as a ${\mathbb Z}_2$ topological metal hosting a Dirac nodal line near the Fermi level. Symmetry analysis within the Ginzburg Landau framework indicates an internally antisymmetric nonunitary triplet (INT) state as the most probable superconducting ground state. Calculations based on an effective low-energy model further demonstrate that this INT state hosts gapless Majorana surface modes, establishing YbSb$_2$ as a topological superconductor. Our results highlight YbSb$_2$ as a unique material platform where type-I superconductivity coexists with triplet-pairing and nontrivial topology.

preprint2026arXiv

Pushing on Multilingual Reasoning Models with Language-Mixed Chain-of-Thought

Recent frontier models employ long chain-of-thought reasoning to explore solution spaces in context and achieve stonger performance. While many works study distillation to build smaller yet capable models, most focus on English and little is known about language-specific reasoning. To bridge this gap, we first introduct **Language-Mixed CoT**, a reasoning schema that switches between English and a target language, using English as an anchor to excel in reasoning while minimizing translation artificats. As a Korean case study, we curate **Yi-Sang**: 5.79M native-Korean prompts from web Q&A, exams, STEM, and code; 3.7M long reasoning traces generated from Qwen3-32B; and a targeted 260k high-yield subset. We train ninve models (4B-35B) across six families (Qwen2.5, Llama-3.1, Gemma-3, etc). Our best model, **KO-REAson-35B**, achieves state-of-the-art performance, with the highest overall average score (64.0 \pm 25), ranking first on 5/9 benchmarks and second on the remainder. Samller and mid-sized models also benefit substantially, with an average improvement of +18.6 points across teh evaluated nine benchmarks. Ablations show **Language-Mixed CoT** is more effective than monolingual CoT, also resulting in cross-lingual and mult-modal performance gains. We release our data-curation pipeline, evaluation system, datasets, and models to advance research on language-specific reasoning. Data and model collection: https://huggingface.co/KOREAson.

preprint2026arXiv

RECOR: Reasoning-focused Multi-turn Conversational Retrieval Benchmark

Existing benchmarks treat multi-turn conversation and reasoning-intensive retrieval separately, yet real-world information seeking requires both. To bridge this gap, we present a benchmark for reasoning-based conversational information retrieval comprising 707 conversations (2,971 turns) across eleven domains. To ensure quality, our Decomposition-and-Verification framework transforms complex queries into fact-grounded multi-turn dialogues through multi-level validation, where atomic facts are verified against sources and explicit retrieval reasoning is generated for each turn. Comprehensive evaluation reveals that combining conversation history with reasoning doubles retrieval performance (Baseline .236 $\rightarrow$ History+Reasoning .479 nDCG@10), while reasoning-specialized models substantially outperform dense encoders. Despite these gains, further analysis highlights that implicit reasoning remains challenging, particularly when logical connections are not explicitly stated in the text.

preprint2025arXiv

Band Geometry Induced Third-Harmonic Generation

Third-harmonic generation (THG) is a key nonlinear optical process for ultrafast imaging, terahertz (THz) signal generation, and symmetry-sensitive probes, often dominating in centrosymmetric materials where lower-order responses vanish. Yet, the role of band geometry, Fermi surface effects, and disorder in enabling large and tunable THG remains poorly understood. Here, we develop a finite-frequency quantum kinetic theory of THG based on the density matrix formalism, deriving the third-harmonic conductivity tensor. Our framework isolates five distinct band-geometric contributions to interband and intraband processes, separates Fermi sea from Fermi surface terms, and incorporates disorder effects phenomenologically. We further provide a complete symmetry classification of THG for all 122 magnetic point groups. Applying the theory to the spin-split altermagnet RuO$_2$, we trace its THG response to specific geometric terms. These results establish a predictive foundation for designing materials with enhanced and tunable THG in the finite-frequency regime.

preprint2025arXiv

Modulation of quantum geometry and its coupling to pseudo-electric field by dynamic strain

Two-dimensional materials are a fertile ground for exploring quantum geometric phenomena, with Berry curvature and its first moment, the Berry curvature dipole, playing a central role in their electronic response. These geometric properties influence electronic transport and result in the anomalous and nonlinear Hall effects, and are typically controlled using static electric fields or strain. However, the possibility of modulating quantum geometric quantities in real-time remains unexplored. Here, we demonstrate the dynamic modulation of Berry curvature and its moments, as well as the generation of a pseudo-electric field using time-dependent strain. By placing heterostructures on a membrane, we introduce oscillatory strain together with an in-plane AC electric field and measure Hall signals that are modulated at linear combinations of the frequencies of strain and electric field. Our measurements reveal modulation of Berry curvature and its first moment. Notably, we provide direct experimental evidence of pseudo-electric field that results in an unusual dynamic strain-induced Hall response. This approach opens up a new pathway for controlling quantum geometry on demand, moving beyond conventional static perturbations. The pseudo-electric field provides a framework for external electric field-free anomalous Hall response and opens new avenues for probing the topological properties.

preprint2025arXiv

Odd-parity longitudinal magnetoconductivity in time-reversal symmetry broken materials

Magnetotransport measurements are a sensitive probe of symmetry and electronic structure in quantum materials. While conventional metals exhibit longitudinal magnetoconductivity that is even in a magnetic field ($B$) for small $B$, we show that magnetic materials which intrinsically break time-reversal symmetry (TRS) show an {\it odd-parity magnetoconductivity} (OMC), with a leading linear-$B$ response. Using semiclassical transport theory, we derive explicit expressions for the longitudinal and transverse conductivities and identify their origin in Berry curvature and orbital magnetic moment. Crystalline symmetry analysis shows that longitudinal OMC follows the same point-group constraints as the anomalous Hall effect, while transverse OMC obeys distinct rules, providing an independent probe of TRS breaking. In the large $B$ quantum oscillation regime, we uncover both odd- and even-$B$ contributions, demonstrating OMC beyond the semiclassical picture. Explicit calculations in valley-polarized gapped graphene show that OMC peaks near the band edges, vanish in the band gap and follow the temperature dependence of the magnetic order parameter. Our results explain the odd-parity magnetoresistance recently observed in magnetized graphene and establish OMC as a robust transport signature of intrinsic TRS breaking in metals.

preprint2022arXiv

A New Framework for Quantum Oblivious Transfer

We present a new template for building oblivious transfer from quantum information that we call the "fixed basis" framework. Our framework departs from prior work (eg., Crepeau and Kilian, FOCS '88) by fixing the correct choice of measurement basis used by each player, except for some hidden trap qubits that are intentionally measured in a conjugate basis. We instantiate this template in the quantum random oracle model (QROM) to obtain simple protocols that implement, with security against malicious adversaries: 1. Non-interactive random-input bit OT in a model where parties share EPR pairs a priori. 2. Two-round random-input bit OT without setup, obtained by showing that the protocol above remains secure even if the (potentially malicious) OT receiver sets up the EPR pairs. 3. Three-round chosen-input string OT from BB84 states without entanglement or setup. This improves upon natural variations of the CK88 template that require at least five rounds. Along the way, we develop technical tools that may be of independent interest. We prove that natural functions like XOR enable seedless randomness extraction from certain quantum sources of entropy. We also use idealized (i.e. extractable and equivocal) bit commitments, which we obtain by proving security of simple and efficient constructions in the QROM.

preprint2022arXiv

Collective plasmonic modes in the chiral multifold fermionic material CoSi

Plasmonics in topological semimetals offers exciting opportunities for fundamental physics exploration as well as for technological applications. Here, we investigate plasmons in the exemplar chiral crystal CoSi, which hosts a variety of multifold fermionic excitations. We show that CoSi hosts two distinct plasmon modes in the infrared regime at 0.1 eV and 1.1 eV in the long-wavelength limit. The 0.1 eV plasmon is found to be highly dispersive, and originates from intraband collective oscillations associated with a double spin-1 excitation, while the 1.1 eV plasmon is dispersionless and it involves interband correlations. Both plasmon modes lie outside the particle-hole continuum and possess long lifetime. Our study indicates that the CoSi class of materials will provide an interesting materials platform for exploring fundamental and technological aspects of topological plasmonics.

preprint2022arXiv

Large nonsaturating magnetoresistance, weak anti-localization and non-trivial topological states in SrAl$_2$Si$_2$

We explore the electronic and topological properties of single crystal SrAl$_2$Si$_2$ using magnetotransport experiments in conjunction with first-principle calculations. We find that the temperature-dependent resistivity shows a pronounced peak near 50 K. We observe several remarkable features at low temperatures, such as large non-saturating magnetoresistance, Shubnikov-de Haas oscillations and cusp-like magneto-conductivity. The maximum value of magnetoresistance turns out to be 459\% at 2 K and 12 T. The analysis of the cusp-like feature in magneto-conductivity indicates a clear signature of weak anti-localization. Our Hall resistivity measurements confirm the presence of two types of charge carriers in SrAl$_2$Si$_2$, with low carrier density.

preprint2022arXiv

Magnetically tunable Dirac and Weyl fermions in the Zintl materials family

Recent classification efforts encompassing crystalline symmetries have revealed rich possibilities for solid-state systems to support a tapestry of exotic topological states. However, finding materials that realize such states remains a daunting challenge. Here we show how the interplay of topology, symmetry, and magnetism combined with doping and external electric and magnetic field controls can be used to drive the previously unreported SrIn$_2$As$_2$ materials family into a variety of topological phases. Our first-principles calculations and symmetry analysis reveal that SrIn$_2$As$_2$ is a dual topological insulator with $Z_2=(1;000)$ and mirror Chern number $C_M= -1$. Its isostructural and isovalent antiferromagnetic cousin EuIn$_2$As$_2$ is found to be an axion insulator with $Z_4= 2$. The broken time-reversal symmetry via Eu doping in Sr$_{1-x}$Eu$_x$In$_2$As$_2$ results in a higher-order or topological crystalline insulator state depending on the orientation of the magnetic easy axis. We also find that antiferromagnetic EuIn$_2$P$_2$ is a trivial insulator with $Z_4= 0$, and that it undergoes a magnetic field-driven transition to an ideal Weyl fermion or nodal fermion state with $Z_4= 1$ with applied magnetic field. Our study identifies Sr$_{1-x}$Eu$_x$In$_2$(As, P)$_2$ as a new tunable materials platform for investigating the physics and applications of Weyl and nodal fermions in the scaffolding of crystalline and axion insulator states.

preprint2022arXiv

Nonlinear magnetoconductivity in Weyl and multi-Weyl semimetal in quantizing magnetic field

Magnetotransport and magneto-optics experiments offer a very powerful probe for studying the physical properties of materials. Here, we investigate the second-order nonlinear magnetoconductivity of tilted type-I Weyl and multi-Weyl semimetal. In contrast to the presence of chiral anomaly in the linear response regime, we show that Weyl semimetal do not host chiral charge pumping in the nonlinear transport regime. We predict that an inversion symmetry broken and tilted Weyl semimetal can support finite longitudinal nonlinear magnetoconductivity, which is otherwise absent in untilted Weyl semimetal. The nonlinear magnetoconductivity vanishes in the ultra-quantum limit, oscillates in the intermediate magnetic field regime and saturates in the semiclassical limit. The nonlinear magnetoconductivity depends intricately on the tilt orientation, and it can be used to determine the tilt orientation in Weyl and multi-Weyl semimetals, via nonlinear magnetoresistivity or second harmonic generation experiments.

preprint2022arXiv

Strain-tunable in-plane ferroelectricity and lateral tunnel junction in monolayer group-IV monochalcogenides

2D Ferroelectric materials are promising for designing low-dimensional memory devices. Here, we explore strain tunable ferroelectric properties of group-IV monochalcogenides MX (M=Ge, Sn; X=S, Se) and their potential application in lateral field tunnel junction devices. We find that these monolayers have in-plane ferroelectricity, with their ferroelectric parameters being on par with other known 2D ferroelectric materials. Amongst SnSe, SnS, GeSe, and GeS, we find that GeS has the best ferroelectric parameters for device applications, which can be improved further by applying uniaxial tensile strain. We use the calculated ferroelectric properties of these materials to study the tunneling electroresistance (TER) of a 4 nm device based on lateral ferroelectric tunnel junction. We find a substantial TER ratio $10^3-10^5$ in the devices based on these materials, which can be further improved up to a factor of 40 on the application of tensile strain.

preprint2022arXiv

Strongly bound excitons in monolayer MoSi$_2$Z$_4$ (Z = pnictogen)

Reduced dielectric screening in two-dimensional materials enables bound excitons, which modifies their optical absorption and optoelectronic response even at room temperature. Here, we demonstrate the existence of excitons in the bandgap of the monolayer family of the newly discovered synthetic MoSi$_2$Z$_4$ (Z = N, P, and As) series of materials. All three monolayers support several bright and strongly bound excitons with binding energies varying from 1 eV to 1.35 eV for the lowest energy exciton resonances. On increasing the pump fluence, the exciton binding energies get renormalized, leading to a redshift-blueshift crossover. Our study shows that the MoSi$_2$Z$_4$ series of monolayers offer an exciting test-bed for exploring the physics of strongly bound excitons and their non-equilibrium dynamics.

preprint2022arXiv

Topological states in superlattices of HgTe-class materials for engineering three-dimensional flat bands

In search of materials with three-dimensional flat band dispersions, using {\em ab-initio} computations, we investigate how topological phases evolve as a function of hydrostatic pressure and uniaxial strain in two types of superlattices: HgTe/CdTe and HgTe/HgSe. In short-period HgTe/CdTe superlattices, our analysis unveils the presence of isoenergetic nodal lines, which could host strain-induced three-dimensional flat bands at the Fermi level without requiring doping, when fabricated, for instance, as core-shell nanowires. In contrast, HgTe/HgSe short-period superlattices are found to harbor a rich phase diagram with a plethora of topological phases. Notably, the unstrained superlattice realizes an ideal Weyl semimetal with Weyl points situated at the Fermi level. A small-gap topological insulator with multiple band inversions can be obtained by tuning the volume: under compressive uniaxial strain, the material transitions sequentially into a Dirac semimetal to a nodal-line semimetal, and finally into a topological insulator with a single band inversion.

preprint2022arXiv

Two-dimensional MoSi2N4: An Excellent 2D Semiconductor for Transistors

We report the performance of field-effect transistors (FETs), comprised of mono-layer of recently synthesized layered two-dimensional MoSi2N_4 as channel material, using the first principles quantum transport simulations. The devices' performance is assessed as per the International Roadmap for Devices and Systems (IRDS) 2020 roadmap for the year 2034 and compared to advanced silicon-based FETs, carbon nanotube-based FETs, and other promising two-dimensional materials based FETs. Finally, we estimate the figure of merits of a combinational and a sequential logic circuit based on our double gate devices and benchmark against promising alternative logic technologies. The performance of our devices and circuits based on them are encouraging, and competitive to other logic alternatives.

preprint2021arXiv

Berry curvature induced nonlinear magnetoresistivity in two dimensional systems

The band geometric properties of quantum materials play an elemental role in the linear and nonlinear transport of electrons. In this paper, we propose that the interplay of the Berry curvature, the orbital magnetic moment and the Lorentz force can induce a finite nonlinear resistivity in two dimensional systems in presence of a perpendicular magnetic field. The induced nonlinear magnetoresistivity scales linearly with the magnetic field and is purely quantum mechanical in origin. This novel transport signature can be used as an additional experimental probe for the geometric quantities in intrinsically time reversal symmetric systems.

preprint2021arXiv

Observation of Dynamic Screening in the Excited Exciton States in Multi-layered MoS$_2$

Excitonic resonance and binding energies can be altered by controlling the environmental screening of the attractive Coulomb potential. Although this screening response is often assumed to be static, the time evolution of the excitonic quasiparticles manifests a frequency-dependence in its Coulomb screening efficacy. In this letter, we investigate a ground (1s) and first excited exciton state (2s) in a multi-layered transition metal dichalcogenide (MoS$_2$) upon ultrafast photo-excitation. We explore the dynamic screening effects on the latter and show its resonance frequency is the relevant frequency at which screening from the smaller-sized 1s counterparts is effective. Our finding sheds light on new avenues of external tuning on excitonic properties.

preprint2020arXiv

Chiral anomalies induced transport in Weyl semimetals in quantizing magnetic field

Weyl semimetals host relativistic chiral quasiparticles, which display quantum anomalies in the presence of external electromagnetic fields. Here, we study the manifestations of chiral anomalies in the longitudinal and planar magneto-transport coefficients of Weyl semimetals, in the presence of a quantizing magnetic field. We present a general framework for calculating all the transport coefficients in the regime where multiple Landau levels are occupied. We explicitly show that all the longitudinal and planar transport coefficients show Shubnikov-de Haas like quantum oscillations which are periodic in 1/B. Our calculations recover the quadratic-B dependence in the semiclassical regime, and predict a linear-B dependence in the ultra-quantum limit for all the transport coefficients.

preprint2020arXiv

K$_2$CoS$_2$: A new two-dimensional in-plane antiferromagnetic insulator

The recent discovery of two-dimensional (2D) magnetic materials has brought magnetism to the flatland. This has opened up exciting opportunities for the exploration of fundamental physics as well as for novel device applications. Here, we predict a new thermodynamically stable 2D magnetic material, K$_2$CoS$_2$, which retains its in-plane anti-ferromagnetic order down to the monolayer and bilayer limits. We find that the magnetic moments ($2.5 μ_B/$Co) are aligned along the intra-Co chains, from monolayer to bulk. The non-magnetic electronic spectrum of both the monolayer and bilayer films is found to host flat bands and van-Hove singularities, which in instrumental in giving rise to the the magnetic ground state. Based on classical Monte-Carlo simulations, we estimate the Neel temperature for the antiferromagnetic monolayer to be $\approx 15$K. Our study thus establishes that K$_2$CoS$_2$ hosts a robust antiferromagnetic state which persists from the monolayer limit to the bulk material.

preprint2020arXiv

Magnetic field-dependent resistance crossover and logarithmic to non-saturating magnetoresistance in topological insulator Bi$_2$Te$_3$

We report a metal-insulator like transition in single crystalline 3D topological insulator Bi2Te3 at a temperature of 230K in presence of an external magnetic field applied normal to the surface. This transition becomes more prominent at larger magnetic field strength with the residual resistance value increasing linearly with the magnetic field. At low temperature, the magnetic field dependence of the magnetoresistance shows a transition from logarithmic to linear behavior and the onset magnetic field value for this transition decreases with increasing temperature. The logarithmic magnetoresistance indicates the weak anti-localization of the surface Dirac electrons while the high temperature behavior originates from the bulk carriers due to intrinsic impurities. At even higher temperatures beyond~230 K, a completely classical Lorentz model type quadratic behavior of the magnetoresistance is observed. We also show that the experimentally observed anomalies at ~230K in the magneto-transport properties do not originate from any stacking fault in Bi2Te3.

preprint2020arXiv

Magnetotransport properties of the topological nodal-line semimetal CaCdSn

Topological nodal-line semimetals support protected band crossings which form nodal lines or nodal loops between the valence and conduction bands and exhibit novel transport phenomena. Here we address the topological state of the nodal-line semimetal candidate material, CaCdSn, and report magnetotransport properties of its single crystals grown by the self-flux method. Our first-principles calculations show that the electronic structure of CaCdSn harbors a single nodal loop around the $Γ$ point in the absence of spin-orbit coupling (SOC) effects. The nodal crossings in CaCdSn are found to lie above the Fermi level and yield a Fermi surface that consists of both electron and hole pockets. CaCdSn exhibits high mobility ($μ\approx 3.44\times 10^4$ cm$^2$V$^{-1}$s$^{-1}$) and displays a field-induced metal-semiconductor like crossover with a plateau in resistivity at low temperature. We observe an extremely large and quasilinear non-saturating transverse as well as longitudinal magnetoresistance (MR) at low temperatures ($\approx 7.44\times 10^3 \%$ and $\approx 1.71\times 10^3\%$, respectively, at 4K). We also briefly discuss possible reasons behind such a large quasilinear magnetoresistance and its connection with the nontrivial band structure of CaCdSn.

preprint2020arXiv

Observation of gapped state in rare-earth monopnictide HoSb

The rare-earth monopnictide family is attracting an intense current interest driven by its unusual extreme magnetoresistance (XMR) property and the potential presence of topologically non-trivial surface states. The experimental observation of non-trivial surface states in this family of materials are not ubiquitous. Here, using high-resolution angle-resolved photoemission spectroscopy (ARPES), magnetotransport, and parallel first-principles modeling, we examine the nature of electronic states in HoSb. Although we find the presence of bulk band gaps at the G and X-symmetry points of the Brillouin zone (BZ), we do not find these gaps to exhibit band inversion so that HoSb does not host a Dirac semimetal state. Our magnetotransport measurements indicate that HoSb can be characterized as a correlated nearly-complete electron-hole-compensated semimetal. Our analysis reveals that the nearly perfect electron-hole compensation could drive the appearance of non-saturating XMR effect in HoSb.

preprint2020arXiv

Saddle-point von Hove singularity and dual topological insulator state in Pt$_2$HgSe$_3$

Saddle-point van Hove singularities in the topological surface states are interesting because they can provide a new pathway for accessing exotic correlated phenomena in topological materials. Here, based on first-principles calculations combined with a $\mathbf {k \cdot p}$ model Hamiltonian analysis, we show that the layered platinum mineral jacutingaite (Pt$_2$HgSe$_3$) harbours saddle-like topological surface states with associated van Hove singularities. Pt$_2$HgSe$_3$ is shown to host two distinct types of nodal lines without spin-orbit coupling (SOC) which are protected by combined inversion ($I$) and time-reversal ($T$) symmetries. Switching on the SOC gaps out the nodal lines and drives the system into a topological insulator state with nonzero weak topological invariant $Z_2=(0;001)$ and mirror Chern number $n_M=2$. Surface states on the naturally cleaved (001) surface are found to be nontrivial with a unique saddle-like energy dispersion with type II van Hove singularities. We also discuss how modulating the crystal structure can drive Pt$_2$HgSe$_3$ into a Dirac semimetal state with a pair of Dirac points. Our results indicate that Pt$_2$HgSe$_3$ is an ideal candidate material for exploring the properties of topological insulators with saddle-like surface states.

preprint2020arXiv

Topological Dirac Semimetal Phase in Bismuth Based Anode Materials for Sodium-Ion Batteries

Bismuth has recently attracted interest in connection with Na-ion battery anodes due to its high volumetric capacity. It reacts with Na to form Na$_3$Bi which is a prototypical Dirac semimetal with a nontrivial electronic structure. Density-functional-theory based first-principles calculations are playing a key role in understanding the fascinating electronic structure of Na$_3$Bi and other topological materials. In particular, the strongly-constrained-and-appropriately-normed (SCAN) meta-generalized-gradient-approximation (meta-GGA) has shown significant improvement over the widely used generalized-gradient-approximation (GGA) scheme in capturing energetic, structural, and electronic properties of many classes of materials. Here, we discuss the electronic structure of Na$_3$Bi within the SCAN framework and show that the resulting Fermi velocities and {\it s}-band shift around the $Γ$ point are in better agreement with experiments than the corresponding GGA predictions. SCAN yields a purely spin-orbit-coupling (SOC) driven Dirac semimetal state in Na$_3$Bi in contrast with the earlier GGA results. Our analysis reveals the presence of a topological phase transition from the Dirac semimetal to a trivial band insulator phase in Na$_{3}$Bi$_{x}$Sb$_{1-x}$ alloys as the strength of the SOC varies with Sb content, and gives insight into the role of the SOC in modulating conduction properties of Na$_3$Bi.

preprint2019arXiv

A novel undamped gapless plasmon mode in tilted type-II Dirac semimetal

We predict the existence of a novel long-lived gapless plasmon mode in a type-II Dirac semimetal (DSM). This gapless mode arises from the out-of-phase oscillations of the density fluctuations in the electron and the hole pockets of a type-II DSM. It originates beyond a critical wave-vector along the direction of the tilt axis, owing to the momentum separation of the electron and hole pockets. A similar out-of-phase plasmon mode arises in other multi-component charged fluids as well, but generally it is Landau damped and lies within the particle-hole continuum. In the case of a type-II DSM, the open Fermi surface prohibits low-energy finite momentum single-particle excitations, creating a `gap' in the particle-hole continuum. The gapless plasmon mode lies within this particle-hole continuum gap and, thus, it is protected from Landau damping.

preprint2019arXiv

Thermal and gravitational chiral anomaly induced magneto-transport in Weyl semimetals

Quantum anomalies in Weyl semimetal (for either ${\bf E}\cdot{\bf B} \neq 0$ or ${\bf \nabla}T\cdot{\bf B} \neq 0$) leads to chiral charge and energy pumping between the opposite chirality nodes. This results in chiral charge and energy imbalance between the Weyl nodes which manifests in several intriguing magneto-transport phenomena. Here, we investigate the role of electrical-, thermal-, and gravitational chiral anomaly on magneto-transport in Weyl semimetals. We predict the planar Ettinghausen and Righi-Leduc effect to be a distinct signature of these quantum anomalies. We also demonstrate a significant enhancement in the thermo-electric conductivity, Seebeck effect, Nernst effect and thermal conductivity with increasing temperature. Interestingly, this anomaly induced transport violates the Wiedemann-Franz law and Mott relation.

preprint2011arXiv

Persistent spin oscillations in a spin-orbit-coupled superconductor

Quasi-two-dimensional superconductors with tunable spin-orbit coupling are very interesting systems with properties that are also potentially useful for applications. In this manuscript we demonstrate that these systems exhibit undamped collective spin oscillations that can be excited by the application of a supercurrent. We propose to use these collective excitations to realize persistent spin oscillators operating in the frequency range of 10 GHz - 1 THz.

preprint2010arXiv

Plasmon mass and Drude weight in strongly spin-orbit-coupled 2D electron gases

Spin-orbit-coupled two-dimensional electron gases (2DEGs) are a textbook example of helical Fermi liquids, i.e. quantum liquids in which spin (or pseudospin) and momentum degrees-of-freedom at the Fermi surface have a well-defined correlation. Here we study the long-wavelength plasmon dispersion and the Drude weight of archetypical spin-orbit-coupled 2DEGs. We first show that these measurable quantities are sensitive to electron-electron interactions due to broken Galileian invariance and then discuss in detail why the popular random phase approximation is not capable of describing the collective dynamics of these systems even at very long wavelengths. This work is focussed on presenting approximate microscopic calculations of these quantities based on the minimal theoretical scheme that captures the basic physics correctly, i.e. the time-dependent Hartree-Fock approximation. We find that interactions enhance the "plasmon mass" and suppress the Drude weight. Our findings can be tested by inelastic light scattering, electron energy loss, and far-infrared optical-absorption measurements.