Abstract

We report that Bi doping drives Prx_xBi2−x_{2-x}Ru2_2O7_7 from an antiferromagnetic insulator (x=2x=2) to a metallic paramagnet (x≈1x\approx 1) with a broad low TT maximum in C/TC/T. Neutron scattering reveals local low energy spin excitations (ℏω≈1\hbarω\approx 1 meV) with a spectrum that is unaffected by heating to kBT>>ℏωk_BT>>\hbarω. We show that a continuous distribution of splittings of the non-Kramers Pr3+^{3+} ground state doublet such as might result from various types of lattice strain can account for all the data.

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