Surface state at BaSnO3BaSnO_3 evidenced by angle-resolved photoemission spectroscopy and ab initio calculations

preprint2021arXivOpen access

Abstract

Perovskite alkaline earth stannates, such as BaSnO3BaSnO_3 and SrSnO3SrSnO_3, showing light transparency and high electrical conductivity (when doped), have become promising candidates for novel optoelectrical devices. Such devices are mostly based on hetero-structures and understanding of their electronic structure, which usually deviates from the bulk, is mandatory for exploring a full application potential. Employing angle-resolved photoemission spectroscopy and ab initio calculations we reveal the existence of a 2-dimensional metallic state at the SnO2SnO_2-terminated surface of a 1\% La-doped BaSnO3BaSnO_3 thin film. The observed surface state is characterized by distinct carrier density and a smaller effective mass in comparison with the corresponding bulk values. The small surface effective mass of about 0.12me0.12m_e can cause an improvement of the electrical conductivity of BSO based heterostructures.

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