Superconductivity at 2.5 K in new transition-metal chalcogenide Ta2PdSe5

preprint2015arXivOpen access

Abstract

We report the synthesis and superconducting properties of a new transition-metal chalcogenide Ta2_2PdSe5_5. The measurements of resistivity, magnetization, and specific heat reveal that Ta2_2PdSe5_5 is a bulk superconductor with TcT_c ≃\simeq 2.5 K. The zero-field electronic specific heat in the superconducting state can be fitted with a two-gap BCS model. The upper critical field Hc2H_{c2} shows a linear temperature dependence, and the value of Hc2H_{c2}(0) is much higher than the estimated Pauli limiting field Hc2PH_{c2}^{P} and orbital limiting field Hc2orbH_{c2}^{orb}. All these results of specific heat and upper critical field suggest that Ta2_2PdSe5_5 is a multi-band superconductor.

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