Abstract

Magnetic excitations in the spin chain candidate Sr2_2V3_3O9_9 have been investigated by inelastic neutron scattering on a single crystal sample. A spinon continuum with a bandwidth of ∼22\sim22 meV is observed along the chain formed by alternating magnetic V4+^{4+} and nonmagnetic V5+^{5+} ions. Incipient magnetic Bragg peaks due to weak ferromagnetic interchain couplings emerge when approaching the magnetic transition at TN∼5.3T_N\sim 5.3 K while the excitations remain gapless within the instrumental resolution. Comparisons to the Bethe ansatz, density matrix renormalization group (DMRG) calculations, and effective field theories confirm Sr2_2V3_3O9_9 as a host of weakly coupled S=1/2S = 1/2 chains dominated by antiferromagnetic intrachain interactions of ∼7.1\sim7.1(1) meV.

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