Resonant inelastic x-ray scattering study of αα-RuCl3_3: a progress report

preprint2019arXivOpen access

Abstract

Ru M3_3-edge resonant inelastic x-ray scattering (RIXS) measurements of RuCl3_3 with 27 meV resolution reveals a spin-orbit exciton without noticeable splitting. We extract values for the spin-orbit coupling constant (λ=154±2λ=154\pm2 meV) and trigonal distortion field energy (∣Δ∣<65\left|Δ\right|<65 meV) which support the jeff=1/2j_{\rm eff}=1/2 nature of RuCl3_3. We demonstrate the feasibility of M-edge RIXS for 4d4d systems, which allows ultra high-resolution RIXS of 4d4d systems until instrumentation for L-edge RIXS improves.

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