Abstract

Absolute transition frequencies of the 2s  2S1/2→2p  2P1/2,3/22s\; ^2{\rm S}_{1/2} \rightarrow 2p\;^2\mathrm{P}_{1/2,3/2} transitions in Be+^+ were measured for the isotopes 7,9−12^{7,9-12}Be. The fine structure splitting of the 2p2p state and its isotope dependence are extracted and compared to results of \textit{ab initio} calculations using explicitly correlated basis functions, including relativistic and quantum electrodynamics effects at the order of mα6m α^6 and mα7ln⁡αm α^7 \ln α. Accuracy has been improved in both the theory and experiment by 2 orders of magnitude, and good agreement is observed. This represents one of the most accurate tests of quantum electrodynamics for many-electron systems, being insensitive to nuclear uncertainties.

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