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Phonon study of rhombohedral BS under high pressure

Raman spectra of rhombohedral boron monosulfide (r-BS) were measured under pressures up to 34 GPa at room temperature. No pressure-induced structural phase transition was observed, while strong pressure shift of Raman bands towards higher wavenumbers has been revealed. IR spectroscopy as a complementary technique has been used in order to completely describe the phonon modes of r-BS. All experimentally observed bands have been compared with theoretically calculated ones and modes assignment has been performed. r-BS enriched by 10B isotope was synthesized, and the effect of boron isotopic substitution on Raman spectra was observed and analyzed.

preprint2015arXivOpen access
Kirill A. CherednichenkoPetr S. SokolovAleksandr KalinkoYann Le GodecAlain PolianJean-Paul ItieVladimir L. Solozhenko
cond-mat.mtrl-sci
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Open access7 authors1 topic
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Kirill A. CherednichenkoPetr S. SokolovAleksandr KalinkoYann Le GodecAlain PolianJean-Paul ItieVladimir L. Solozhenko

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