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Giant Nernst effect and bipolarity in the quasi-one-dimensional metal, Li(0.9)Mo(6)O(17)

The Nernst coefficient for the quasi-one-dimensional metal, Li(0.9)Mo(6)O(17), is found to be among the largest known for metals (~500 microV/KT at T~20K), and is enhanced in a broad range of temperature by orders of magnitude over the value expected from Boltzmann theory for carrier diffusion. A comparatively small Seebeck coefficient implies that Li(0.9)Mo(6)O(17) is bipolar with large, partial Seebeck coefficients of opposite sign. A very large thermomagnetic figure of merit, ZT~0.5, is found at high field in the range T~35-50K.

preprint2012arXivOpen access
J. L. CohnB. D. WhiteC. A. M. dos SantosJ. J. Neumeier
cond-mat.str-elcond-mat.mtrl-sci
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J. L. CohnB. D. WhiteC. A. M. dos SantosJ. J. Neumeier

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