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Ze Zhang

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Published work

13 published item(s)

preprint2026arXiv

AMSnet-q: Unsupervised Circuit Identification and Performance Labeling for AMS Circuits

Analog and mixed-signal (AMS) circuit design remains heavily reliant on expert knowledge. While recent AI-driven automation tools can generate candidate topologies, they critically depend on manually curated datasets with functional and performance annotations -- a requirement that current large language models (LLMs) and vision models cannot automate. Existing approaches still require domain experts to manually interpret circuit functionality. We present AMSnet-q, a fully automated, unsupervised pipeline that eliminates human-in-the-loop annotation by converting schematic images directly into a labeled AMS circuit database. Unlike prior work that stops at netlist extraction, our framework automates the complete verification loop: it performs schematic-to-netlist conversion, topology-aware testbench generation, and simulation-based sizing validation to objectively determine circuit functionality. Validated in 28 nm technology, AMSnet-q processed 739 schematics from the AMSnet 1.0 dataset, automatically constructing a repository of 4 circuit classes, 105 distinct topologies, and 89,789 labeled device configurations. By decoupling human effort from dataset volume and reducing the workload to a one-time testbench template per circuit class, AMSnet-q enables scalable, objective, and fully automated AMS database construction.

preprint2022arXiv

Group frame neural network of moving object ghost imaging combined with frame merging algorithm

The nature of multiple samples to extract correlation information limits the applications of ghost imaging of moving objects. A novel multi-to-one neural network is proposed and the concept of "batch frame" is introduced to improve the serial imaging method. The neural network extracts more correlation information from a small number of samples, thus reducing the sampling ratio of the ghost imaging technique. We combine the correlation characteristics between images to propose a frame merging algorithm, which eliminates the dynamic blur of high-speed moving objects and further improves the reconstruction quality of moving object images at a low sampling ratio. The experimental results are consistent with the simulation results.

preprint2022arXiv

Non-neglectable entropy effect on sintering of supported nanoparticles

Sintering refers to particle coalescence by heat, which has been known as a thermal phenomenon involving all aspects of natural science for centuries. It is particularly important in heterogeneous catalysis because normally sintering results in deactivation of the catalysts. In previous studies, the enthalpy contribution was considered to be dominant in sintering and the entropy effect is generally considered neglectable. However, we unambiguously demonstrate in this work that entropy could prevail over the enthalpy contribution to dominate the sintering behavior of supported nanoparticles (NPs) by designed experiments and improved theoretical framework. Using in situ Cs-corrected environmental scanning transmission electron microscopy and synchrotron-based ambient pressure X-ray photoelectron spectroscopy, we observe the unprecedent entropy-driven phenomenon that supported NPs reversibly redisperse upon heating and sinter upon cooling in three systems (Pd-CeO2, Cu-TiO2, Ag-TiO2). We quantitatively show that the configurational entropy of highly dispersed ad-atoms is large enough to reverse their sintering tendency at the elevated temperature. This work reshapes the basic understanding of sintering at the nanoscale and opens the door for various de-novo designs of thermodynamically stable nanocatalysts.

preprint2022arXiv

Pulsed Laser Ejection of Single-Crystalline III-V Solar Cells From GaAs Substrates

Like many optoelectronics, the highest quality III-V solar cells start out as thin single-crystalline multilayers on GaAs substrates. Separating these device layers from their growth substrate enables higher performing devices and wafer reuse, both of which are critical for III-V solar cell viability in a terrestrial market. Here, we remove rigidly-bonded, lattice-matched, 16 mm$^2$ x 3.5 um thick GaAs devices off a GaAs substrate using a 10 ns, unfocused Nd:YAG laser pulse. The pulse is selectively absorbed in a lower-bandgap, lattice-matched, crystalline layer below the device, driving a quasi-two dimensional ablation event that ejects the crystalline multilayer from the substrate. After minutes of selective wet-chemical etching and front contact deposition, our champion 0.1 cm$^2$ device showed a (17.4 +/- 0.5) % power conversion efficiency and an open-circuit voltage of 1.07 V, using AM1.5 direct (1000 W m$^{-2}$) with no anti-reflection coating. We show that the performance is comparable to similar solar cells produced via conventional substrate dissolution processes. We discuss unique process characteristics and opportunities, such as the potential to separate wafer-sized thin film solar cells per laser pulse.

preprint2020arXiv

Direct Visualization of Irreducible Ferrielectricity in Crystals

In solids, charge polarity can one-to-one correspond to spin polarity phenomenologically, e.g. ferroelectricity/ferromagnetism, antiferroelectricity/antiferromagnetism, and even dipole-vortex/magnetic-vortex, but ferrielectricity/ferrimagnetism kept telling a disparate story in microscopic level. Since the definition of a charge dipole involves more than one ion, there may be multiple choices for a dipole unit, which makes most ferrielectric orders equivalent to ferroelectric ones, i.e. this ferrielectricity is not necessary to be a real independent branch of polarity. In this work, by using the spherical aberration-corrected scanning transmission electron microscope, we visualize a nontrivial ferrielectric structural evolution in BaFe2Se3, in which the development of two polar sub-lattices is out-of-sync, for which we term it as irreducible ferrielectricity. Such irreducible ferrielectricity leads to a non-monotonic behavior for the temperature-dependent polarization, and even a compensation point in the ordered state. Our finding unambiguously distinguishes ferrielectrics from ferroelectrics in solids.

preprint2019arXiv

Experimental Observation of Equilibrium and Dynamical Quantum Phase Transitions via Out-of-Time-Ordered Correlators

The out-of-time-ordered correlators (OTOC) have been established as a fundamental concept for quantifying quantum information scrambling and diagnosing quantum chaotic behavior. Recently, it was theoretically proposed that the OTOC can be used as an order parameter to dynamically detect both equilibrium quantum phase transitions (EQPTs) and dynamical quantum phase transitions (DQPTs) in one-dimensional many-body systems. Here we report the first experimental observation of EQPTs and DQPTs in a quantum spin chain via quench dynamics of OTOC on a nuclear magnetic resonance quantum simulator. We observe that the quench dynamics of both the order parameter and the two-body correlation function cannot detect the DQPTs, but the OTOC can unambiguously detect the DQPTs. Moreover, we demonstrate that the long-time average value of the OTOC in quantum quench signals the equilibrium quantum critical point and ordered quantum phases, thus one can measure the EQPTs from the non-equilibrium quantum quench dynamics. Our experiment paves a way for experimentally investigating DQPTs through OTOCs and for studying the EQPTs through the non-equilibrium quantum quench dynamics with quantum simulators.

preprint2015arXiv

Image definition evaluation functions for X-ray crystallography: a new perspective on the phase problem

The core theme of X-ray crystallography is reconstructing the electron density distribution of crystals under the constraints of observed diffraction data. Nevertheless, the reconstruction of electron density distribution by straightforward Fourier synthesis is usually hindered due to the well-known phase problem and finite resolution of diffraction data. In analogy with optical imaging system, the reconstructed electron density map may be regarded as the image of the real electron density distribution in crystals. Inspired by image definition evaluation functions applied in auto-focusing process, we proposed two evaluation functions for the reconstructed electron density images. One of them is based on atomicity of electron density distribution and properties of Fourier synthesis. Tests were performed on synthetic data of known structures, and it was found that this evaluation function can distinguish the correctly reconstructed electron density image from wrong ones when diffraction data of atomic resolution is available. An algorithm was established based on this evaluation function and applied in reconstructing the electron density image from synthetic data of known structures. The other evaluation function, which is based on the positivity of electron density and constrained entropy maximization, was designed for cases where only diffraction data of rather limited resolution is available. Tests on synthetic data indicate that this evaluation function may identify the correct phase set even for a dataset at the resolution as low as 3.5 Å. Though no algorithm of structure solution has been figured out based on the latter function, the results presented here provide a new perspective on the phase problem.

preprint2015arXiv

Nanoscale Origins of the Damage Tolerance of the High-Entropy Alloy CrMnFeCoNi

Damage-tolerance can be an elusive characteristic of structural materials requiring both high strength and ductility, properties that are often mutually exclusive. High-entropy alloys are of interest in this regard. Specifically, the single-phase CrMnFeCoNi alloy displays tensile strength levels of ~1 GPa, excellent ductility (~60-70%) and exceptional fracture toughness (KJIc > 200 MPa/m). Here, through the use of in-situ straining in an aberration-corrected transmission electron microscope, we report on the salient atomistic to micro-scale mechanisms underlying the origin of these properties. We identify a synergy of multiple deformation mechanisms, rarely achieved in metallic alloys, which generates high strength, work hardening and ductility, including the easy motion of Shockley partials, their interactions to form stacking-fault parallelepipeds, and arrest at planar-slip bands of undissociated dislocations. We further show that crack propagation is impeded by twinned, nano-scale bridges that form between the near-tip crack faces and delay fracture by shielding the crack tip.

preprint2015arXiv

Probing the anisotropic behaviors of black phosphorus by transmission electron microscope, angular-dependent Raman spectra and electronic transports measurements

In this work, we correlated the angular dependence of the Raman response of black phosphorus to its crystallographic orientation by using transmission electron microscopy and Raman spectroscopy. It was found that the intensity of the A2g mode reached a maximum when the polarization direction of the incident light was parallel to the zigzag crystallographic orientation. Notably, it was further confirmed that the zigzag crystallographic direction exhibited superior conductance and carrier mobility. Because of the lattice extension along the armchair direction, an intensification of the anisotropic Raman response was observed. This work provides direct evidence of the correlation between anisotropic properties and crystallographic direction and represents a turning point in the discussion of the angular-dependent electronic properties of black phosphorus.

preprint2014arXiv

Dimensional cross-over of the bandgap transition in quasi-two-dimensional MoS2

The anisotropy of the electronic transition is an important physical property not only determining the materials' optical property, but also revealing the underlying character of the electronic states involved. Here we used momentum-resolved electron energy-loss spectroscopy to study the evolution of the anisotropy of the electronic transition involving the low energy valence electrons in the free-standing MoS2 systems as the layer thickness was reduced to monolayer. We used the orientation and the spectral-density analysis to show that indirect to direct band-gap transition is accompanied by a three- to two-dimensional anisotropy cross-over. The result provides a logical explanation for the large sensitivity of indirect transition to the change of thickness compared with that for direct transition. By tracking the energy of indirect transition, we also revealed the asymmetric response of the valence band and conduction band to the quantum confinement effect. Our results have implication for future optoelectronic applications of atomic thin MoS2.

preprint2014arXiv

Plasma-assisted fabrication of monolayer phosphorene and its Raman characterization

There have been continuous efforts to seek for novel functional two-dimensional semiconductors with high performance for future applications in nanoelectronics and optoelectronics. In this work, we introduce a successful experimental approach to fabricate monolayer phosphorene by mechanical cleavage and the following Ar+ plasma thinning process. The thickness of phosphorene is unambiguously determined by optical contrast combined with atomic force microscope (AFM). Raman spectroscopy is used to characterize the pristine and plasma-treated samples. The Raman frequency of A2g mode stiffens, and the intensity ratio of A2g to A1g modes shows monotonic discrete increase with the decrease of phosphorene thickness down to monolayer. All those phenomena can be used to identify the thickness of this novel two-dimensional semiconductor efficiently. This work for monolayer phosphorene fabrication and thickness determination will facilitates the research of phosphorene.

preprint2013arXiv

Engineered optical nonlinearities and enhanced light transmission in soft-matter systems with tunable polarizabilities

In this work, we demonstrate that the nonlinear response of certain soft-matter systems can be tailored at will by appropriately engineering their optical polarizability. In particular, we deliberately synthesize stable colloidal suspensions with negative polarizabilities, and observe for the first time robust propagation and enhanced transmission of self-trapped light over long distances that would have been otherwise impossible in conventional suspensions with positive polarizabilities. What greatly facilitates this behavior is an induced saturable nonlinear optical response introduced by the thermodynamic properties of these colloidal systems. This in turn leads to a substantial reduction in scattering via self-activated transparency effects. Our results may open up new opportunities in developing soft-matter systems with tunable optical nonlinearities.

preprint2008arXiv

Ni/Ni3C Core-Shell Nanochains and Its Magnetic Properties: One-Step Synthesis at low temperature

One-dimensional Ni/Ni3C core-shell nanoball chains with an average diameter by around 30 nm were synthesized by means of a mild chemical solution method using a soft template of trioctylphosphineoxide (TOPO). It was revealed that the uniform Ni nanochains were capped with Ni3C thin shells by about 1 to 4 nm in thickness and each Ni core consists of polygrains. The coercivity of the core-shell nanochains is much enhanced (600 Oe at 5 K) and comparable with single Ni nanowires due to the one-dimensional shape anisotropy. Deriving from the distinctive structure of Ni core and Ni3C shell, this architecture may possess a possible bi-functionality. This unique architecture is also useful for the study on the magnetization reversal mechanism of one-dimensional magnetic nanostructure.