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Wei Bao

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Published work

33 published item(s)

preprint2026arXiv

Lost in Benchmarks? Rethinking Large Language Model Benchmarking with Item Response Theory

The evaluation of large language models (LLMs) via benchmarks is widespread, yet inconsistencies between different leaderboards and poor separability among top models raise concerns about their ability to accurately reflect authentic model capabilities. This paper provides a critical analysis of benchmark effectiveness, examining mainstream prominent LLM benchmarks using results from diverse models. We first propose Pseudo-Siamese Network for Item Response Theory (PSN-IRT), an enhanced Item Response Theory framework that incorporates a rich set of item parameters within an IRT-grounded architecture. PSN-IRT can be utilized for accurate and reliable estimations of item characteristics and model abilities. Based on PSN-IRT, we conduct extensive analysis on 11 LLM benchmarks comprising 41,871 items, revealing significant and varied shortcomings in their measurement quality. Furthermore, we demonstrate that leveraging PSN-IRT is able to construct smaller benchmarks while maintaining stronger alignment with human preference.

preprint2026arXiv

Rethinking Event-Based Object Dtection through Representation-Level Temporal Aggregation and Model-Level Hypergraph Reasoning

Event cameras provide microsecond-level temporal resolution, low latency, and high dynamic range, offering potential for perception under fast motion and challenging illumination conditions. However, existing Event-based Object Detection (EOD) methods face limitations at both the representation and model levels: prior event representations usually encode temporal information indirectly through redundant structures, while detection models struggle to explicitly aggregate fragmented event responses into coherent high-order object features. To address these limitations, we present Event Dual Temporal-Relational Aggregation Detector (Ev-DTAD), a unified EOD framework that integrates representation-level temporal encoding with model-level temporal-hypergraph reasoning. Specifically, we introduce Hierarchical Temporal Aggregation (HTA), a compact three-channel pseudo-RGB representation that explicitly embeds temporal information across intra- and inter-window events. To further enhance detection under sparse and fragmented event responses, we propose Frequency-aware Hypergraph Temporal Fusion (FHTF), which refines multi-scale event features through temporal evolution modeling and high-order relational reasoning. Extensive experiments on Gen1 (+0.8 mAP and 1.7$\times$ faster), 1Mpx/Gen4 (+0.5 mAP and 1.6$\times$ faster), and eTraM (+3.0 mAP and 2.0$\times$ faster) demonstrate that Ev-DTAD achieves a competitive accuracy-efficiency trade-off, validating the complementarity between compact temporal representation and temporal-hypergraph feature reasoning.

preprint2023arXiv

Federated PCA on Grassmann Manifold for Anomaly Detection in IoT Networks

In the era of Internet of Things (IoT), network-wide anomaly detection is a crucial part of monitoring IoT networks due to the inherent security vulnerabilities of most IoT devices. Principal Components Analysis (PCA) has been proposed to separate network traffics into two disjoint subspaces corresponding to normal and malicious behaviors for anomaly detection. However, the privacy concerns and limitations of devices' computing resources compromise the practical effectiveness of PCA. We propose a federated PCA-based Grassmannian optimization framework that coordinates IoT devices to aggregate a joint profile of normal network behaviors for anomaly detection. First, we introduce a privacy-preserving federated PCA framework to simultaneously capture the profile of various IoT devices' traffic. Then, we investigate the alternating direction method of multipliers gradient-based learning on the Grassmann manifold to guarantee fast training and the absence of detecting latency using limited computational resources. Empirical results on the NSL-KDD dataset demonstrate that our method outperforms baseline approaches. Finally, we show that the Grassmann manifold algorithm is highly adapted for IoT anomaly detection, which permits drastically reducing the analysis time of the system. To the best of our knowledge, this is the first federated PCA algorithm for anomaly detection meeting the requirements of IoT networks.

preprint2022arXiv

Antiferromagnetic structure and magnetic properties of Dy2O2Te: An isostructural analog of the rare-earth superconductors R2O2Bi

The rare-earth compounds R2O2Bi (R=Tb, Dy, Er, Lu, Y) are newly discovered superconductors in the vicinity of a rare-earth magnetic long-range order. In this work, we determine the magnetic order of the parent compound Dy2O2Te by neutron scattering as the A-type antiferromagnetic structure below the Néel temperature TN=9.7K. The large staggered magnetic moment 9.4(1) μB per Dy at T=3.5K lies in the basal ab plane. In a magnetic field, anomalous magnetic properties including the bifurcation between zero-field- and field-cooling magnetization, a butterfly-shaped magnetic hysteresis, and slow magnetic relaxation emerge, which are related to the field-induced metamagnetic transitions in Dy2O2Te. Our experimental findings could stimulate further research on the relation between antiferromagnetism and superconductivity in these rare-earth compounds.

preprint2022arXiv

DONE: Distributed Approximate Newton-type Method for Federated Edge Learning

There is growing interest in applying distributed machine learning to edge computing, forming federated edge learning. Federated edge learning faces non-i.i.d. and heterogeneous data, and the communication between edge workers, possibly through distant locations and with unstable wireless networks, is more costly than their local computational overhead. In this work, we propose DONE, a distributed approximate Newton-type algorithm with fast convergence rate for communication-efficient federated edge learning. First, with strongly convex and smooth loss functions, DONE approximates the Newton direction in a distributed manner using the classical Richardson iteration on each edge worker. Second, we prove that DONE has linear-quadratic convergence and analyze its communication complexities. Finally, the experimental results with non-i.i.d. and heterogeneous data show that DONE attains a comparable performance to the Newton's method. Notably, DONE requires fewer communication iterations compared to distributed gradient descent and outperforms DANE and FEDL, state-of-the-art approaches, in the case of non-quadratic loss functions.

preprint2022arXiv

Electrically pumped polarized exciton-polaritons in a halide perovskite microcavity

Exciton polaritons, hybrid quasiparticles with part-light part-matter nature in semiconductor microcavities, are extensively investigated for striking phenomena such as polariton condensation and quantum emulation. These phenomena have recently been discovered in emerging lead halide perovskites at elevated temperatures up to room temperature. For advancing these discoveries into practical applications, one critical requirement is the realization of electrically pumped exciton-polaritons. However, electrically pumped polariton light-emitting devices with perovskites have not yet been achieved experimentally. Here, we devise a new method to combine the device with the microcavity and report the first halide perovskite polariton light-emitting device. Specifically, the device is based on a CsPbBr3 capacitive structure, which can inject the electrons and holes from the same electrode, conducive to the formation of excitons and simultaneously maintaining the high quality of the microcavity. In addition, highly polarization-selective polariton emissions have been demonstrated due to the optical birefringence in the CsPbBr3 microplate. This work paves the way for realizing practical polaritonic devices such as high-speed light-emitting devices for information communications and inversionless electrically pumped lasers based on perovskites.

preprint2021arXiv

Extreme Suppression of Antiferromagnetic Order and Critical Scaling in a Two-Dimensional Random Quantum Magnet

Sr$_2$CuTeO$_6$ is a square-lattice Néel antiferromagnet with superexchange between first-neighbor $S=1/2$ Cu spins mediated by plaquette centered Te ions. Substituting Te by W, the affected impurity plaquettes have predominantly second-neighbor interactions, thus causing local magnetic frustration. Here we report a study of Sr$_2$CuTe$_{1-x}$W$_x$O$_6$ using neutron diffraction and $μ$SR techniques, showing that the Néel order vanishes already at $x = 0.025 \pm 0.005$. We explain this extreme order suppression using a two-dimensional Heisenberg spin model, demonstrating that a W-type impurity induces a deformation of the order parameter that decays with distance as $1/r^2$ at temperature $T=0$. The associated logarithmic singularity leads to loss of order for any $x>0$. Order for small $x>0$ and $T>0$ is induced by weak interplane couplings. In the nonmagnetic phase of Sr$_2$CuTe$_{1-x}$W$_x$O$_6$, the $μ$SR relaxation rate exhibits quantum critical scaling with a large dynamic exponent, $z \approx 3$, consistent with a random-singlet state.

preprint2020arXiv

An Accurate Model for Predicting the (Graded) Effect of Context in Word Similarity Based on Bert

Natural Language Processing (NLP) has been widely used in the semantic analysis in recent years. Our paper mainly discusses a methodology to analyze the effect that context has on human perception of similar words, which is the third task of SemEval 2020. We apply several methods in calculating the distance between two embedding vector generated by Bidirectional Encoder Representation from Transformer (BERT). Our team will_go won the 1st place in Finnish language track of subtask1, the second place in English track of subtask1.

preprint2020arXiv

Evolution of superconductivity and antiferromagnetic order in Ba(Fe$_{0.92-x}$Co$_{0.08}$V$_x$)$_2$As$_2$

The vanadium doping effects on superconductivity and magnetism of iron pnictides are investigated in Ba(Fe$_{0.92-x}$Co$_{0.08}$V$_x$)$_2$As$_2$ by transport, susceptibility and neutron scattering measurements. The doping of magnetic impurity V causes a fast suppression of superconductivity with T$_c$ reduced at a rate of 7.4~K/1\%V. On the other hand, the long-range commensurate $C$-type antiferromagnetic order is recovered upon the V doping. The value of ordered magnetic moments of Ba(Fe$_{0.92-x}$Co$_{0.08}$V$_x$)$_2$As$_2$ follows a dome-like evolution versus doping concentration x. A possible Griffiths-type antiferromagnetic region of multiple coexisting phases in the phase diagram of Ba(Fe$_{0.92-x}$Co$_{0.08}$V$_x$)$_2$As$_2$ is identified, in accordance with previous theoretical predictions based on a cooperative behavior of the magnetic impurities and the conduction electrons mediating the Ruderman-Kittel-Kasuya-Yosida interactions between them.

preprint2020arXiv

Online Metric Learning for Multi-Label Classification

Existing research into online multi-label classification, such as online sequential multi-label extreme learning machine (OSML-ELM) and stochastic gradient descent (SGD), has achieved promising performance. However, these works do not take label dependencies into consideration and lack a theoretical analysis of loss functions. Accordingly, we propose a novel online metric learning paradigm for multi-label classification to fill the current research gap. Generally, we first propose a new metric for multi-label classification which is based on $k$-Nearest Neighbour ($k$NN) and combined with large margin principle. Then, we adapt it to the online settting to derive our model which deals with massive volume ofstreaming data at a higher speed online. Specifically, in order to learn the new $k$NN-based metric, we first project instances in the training dataset into the label space, which make it possible for the comparisons of instances and labels in the same dimension. After that, we project both of them into a new lower dimension space simultaneously, which enables us to extract the structure of dependencies between instances and labels. Finally, we leverage the large margin and $k$NN principle to learn the metric with an efficient optimization algorithm. Moreover, we provide theoretical analysis on the upper bound of the cumulative loss for our method. Comprehensive experiments on a number of benchmark multi-label datasets validate our theoretical approach and illustrate that our proposed online metric learning (OML) algorithm outperforms state-of-the-art methods.

preprint2019arXiv

Observation of Rydberg exciton polaritons and their condensate in a perovskite cavity

The condensation of half-light half-matter exciton polaritons in semiconductor optical cavities is a striking example of macroscopic quantum coherence in a solid state platform. Quantum coherence is possible only when there are strong interactions between the exciton polaritons provided by their excitonic constituents. Rydberg excitons with high principle value exhibit strong dipole-dipole interactions in cold atoms. However, polaritons with the excitonic constituent that is an excited state, namely Rydberg exciton polaritons (REPs), have not yet been experimentally observed. Here, for the first time, we observe the formation of REPs in a single crystal CsPbBr3 perovskite cavity without any external fields. These polaritons exhibit strong nonlinear behavior that leads to a coherent polariton condensate with a prominent blue shift. Furthermore, the REPs in CsPbBr3 are highly anisotropic and have a large extinction ratio, arising from the perovskite's orthorhombic crystal structure. Our observation not only sheds light on the importance of many-body physics in coherent polariton systems involving higher-order excited states, but also paves the way for exploring these coherent interactions for solid state quantum optical information processing.

preprint2016arXiv

A single-crystal neutron diffraction study on magnetic structure of the quasi-one-dimensional antiferromagnet SrCo2V2O8

The magnetic structure of the spin-chain antiferromagnet SrCo2V2O8 is determined by single-crystal neutron diffraction experiment. The system undergoes magnetic long range order below T_N = 4.96 K. The moment of 2.16μ_B per Co at 1.6 K in the screw chain running along the c axis alternates in the c-axis. The moments of neighboring screw chains are arranged antiferromagnetically along one in-plane axis and ferromagnetically along the other in-plane axis. This magnetic configuration breaks the 4-fold symmetry of the tetragonal crystal structure and leads to two equally populated magnetic twins with antiferromagnetic vector in the a or b axis. The very similar magnetic state to the isostructural BaCo2V2O8 warrants SrCo2V2O8 another interesting half-integer spin-chain antiferromagnet for investigation on quantum antiferromagnetism.

preprint2016arXiv

Simultaneous Occurrence of Multiferroism and the Short-Range Magnetic Order in DyFeO3

We report a combined neutron scattering and magnetization study on the multiferroic DyFeO3 which shows a very strong magnetoelectric effect. Applying magnetic field along the c-axis, the weak ferromagnetic order of the Fe ions is quickly recovered from a spin reorientation transition, and the long-range antiferromagnetic order of Dy becomes a short-range one. We found that the short-range order concurs with the multiferroic phase and is responsible for its sizable hysteresis. Our H-T phase diagram suggests that the strong magnetoelectric effect in DyFeO3 has to be understood with not only the weak ferromagnetism of Fe but also the short-range antiferromagnetic order of Dy.

preprint2016arXiv

The influence of the structural transition on magnetic fluctuations in NaFeAs

NaFeAs belongs to a class of Fe-based superconductors which parent compounds show separated structural and magnetic transitions. Effects of the structural transition on spin dynamics therefore can be investigated separately from the magnetic transition. A plateau in dynamic spin response is observed in a critical region around the structural transition temperature T_S. It is interpreted as due to the stiffening of spin fluctuations along the in-plane magnetic hard axis due to the dxz and dyz orbital ordering. The appearance of anisotropic spin dynamics in the critical region above the T_S at T* offers a dynamic magnetic scattering mechanism for anisotropic electronic properties in the commonly referred "nematic phase".

preprint2014arXiv

High-pressure single-crystal neutron scattering study of magnetic and Fe vacancy orders in (Tl,Rb)2Fe4Se5 superconductor

The magnetic and iron vacancy orders in superconducting (Tl,Rb)2Fe4Se5 single-crystals are investigated by using a high-pressure neutron diffraction technique. Similar to the temperature effect, the block antiferromagnetic order gradually decreases upon increasing pressure while the Fe vacancy superstructural order remains intact before its precipitous disappearance at the critical pressure Pc = 8.3 GPa. Combined with previously determined Pc for superconductivity, our phase diagram under pressure reveals the concurrence of the block AFM order, the iron vacancy order and superconductivity for the 245 superconductor. A synthesis of current experimental data in a coherent physical picture is attempted.

preprint2014arXiv

Optimizing User Association and Spectrum Allocation in HetNets: A Utility Perspective

The joint user association and spectrum allocation problem is studied for multi-tier heterogeneous networks (HetNets) in both downlink and uplink in the interference-limited regime. Users are associated with base-stations (BSs) based on the biased downlink received power. Spectrum is either shared or orthogonally partitioned among the tiers. This paper models the placement of BSs in different tiers as spatial point processes and adopts stochastic geometry to derive the theoretical mean proportionally fair utility of the network based on the coverage rate. By formulating and solving the network utility maximization problem, the optimal user association bias factors and spectrum partition ratios are analytically obtained for the multi-tier network. The resulting analysis reveals that the downlink and uplink user associations do not have to be symmetric. For uplink under spectrum sharing, if all tiers have the same target signal-to-interference ratio (SIR), distance-based user association is shown to be optimal under a variety of path loss and power control settings. For both downlink and uplink, under orthogonal spectrum partition, it is shown that the optimal proportion of spectrum allocated to each tier should match the proportion of users associated with that tier. Simulations validate the analytical results. Under typical system parameters, simulation results suggest that spectrum partition performs better for downlink in terms of utility, while spectrum sharing performs better for uplink with power control.

preprint2014arXiv

Structure, magnetic order and excitations in the 245 family of Fe-based superconductors

Elastic neutron scattering simultaneously probes both the crystal structure and magnetic order in a material. Inelastic neutron scattering measures phonons and magnetic excitations. Here, we review the average composition, crystal structure and magnetic order in the 245 family of Fe-based superconductors and in related insulating compounds from neutron diffraction works. A three-dimensional phase-diagram summarizes various structural, magnetic and electronic properties as a function of the sample composition. A high pressure phase diagram for the superconductor is also provided. Magnetic excitations and the theoretic Heisenberg Hamiltonian are provided for the superconductor. Issues for future works are discussed.

preprint2014arXiv

Uplink Interference Analysis for Two-tier Cellular Networks with Diverse Users under Random Spatial Patterns

Multi-tier architecture improves the spatial reuse of radio spectrum in cellular networks, but it introduces complicated heterogeneity in the spatial distribution of transmitters, which brings new challenges in interference analysis. In this work, we present a stochastic geometric model to evaluate the uplink interference in a two-tier network considering multi-type users and base stations. Each type of tier-1 users and tier-2 base stations are modeled as independent homogeneous Poisson point processes, and tier-2 users are modeled as locally non-homogeneous clustered Poisson point processes centered at tier-2 base stations. By applying a superposition-aggregation-superposition approach, we quantify the interference at both tiers. Our model is also able to capture the impact of two types of exclusion regions, where either tier-2 base stations or tier-2 users are restricted in order to avoid cross-tier interference. As an important application of this analytical model, an intensity planning scenario is investigated, in which we aim to maximize the total income of the network operator with respect to the intensities of tier-2 cells, under constraints on the outage probabilities of tier-1 and tier-2 users. The result of our interference analysis suggests that this maximization can be converted to a standard convex optimization problem. Finally, numerical studies further demonstrate the correctness of our analysis.

preprint2013arXiv

Insensitivity of User Distribution in Multicell Networks under General Mobility and Session Patterns

The location of active users is an important factor in the performance analysis of mobile multicell networks, but it is difficult to quantify due to the wide variety of user mobility and session patterns. In particular, the channel holding times in each cell may be arbitrarily distributed and dependent on those in other cells. In this work, we study the stationary distribution of users by modeling the system as a multi-route queueing network with Poisson inputs. We consider arbitrary routing and arbitrary joint probability distributions for the channel holding times in each route. Using a decomposition-composition approach, we show that the user distribution (1) is insensitive to the user movement patterns, (2) is insensitive to general and dependently distributed channel holding times, (3) depends only on the average arrival rate and average channel holding time at each cell, and (4) is completely characterized by an open network with M/M/infinity queues. This result is validated by experiments with the Dartmouth user mobility traces.

preprint2013arXiv

Neutron Scattering Study on Spin Dynamics in Superconducting (Tl,Rb)2Fe4Se5

We observed in superconducting (Tl,Rb)2Fe4Se5 spin-wave branches that span an energy range from 6.5 to 209 meV. Spin dynamics are successfully described by a Heisenberg localized spin model whose dominant in-plane interactions include only the nearest (J1 and J1') and next nearest neighbor (J2 and J2') exchange terms within and between the tetramer spin blocks, respectively. These experimentally determined exchange constants would crucially constrain the theoretical viewpoints on magnetism and superconductivity in the Fe-based materials.

preprint2013arXiv

Physics picture from neutron scattering study on Fe-based superconductors

Neutron scattering, with its ability to measure the crystal structure, the magnetic order, and the structural and magnetic excitations, plays an active role in investigating various families of Fe-based high-Tc superconductors. Three different types of antiferromag- netic orders have been discovered in the Fe plane, but two of them cannot be explained by the spin-density-wave (SDW) mechanism of nesting Fermi surfaces. Noticing the close relation between antiferromagnetic order and lattice distortion in orbital ordering from previous studies on manganites and other oxides, we have advocated orbital or- dering as the underlying common mechanism for the structural and antiferromagnetic transitions in the 1111, 122 and 11 parent compounds. We observe the coexistence of antiferromagnetic order and superconductivity in the (Ba,K)Fe2 As2 system, when its phase separation is generally accepted. Optimal Tc is proposed to be controlled by the local FeAs4 tetrahedron from our investigation on the 1111 materials. The Bloch phase coherence of the Fermi liquid is found crucial to the occurrence of bulk superconductiv- ity in iron chalcogenides of both the 11 and the 245 families. Iron chalcogenides carry a larger staggered magnetic moment (> 2μB /Fe) than that in iron pnictides (< 1μB /Fe) in the antiferromagnetic order. Normal state magnetic excitations in the 11 supercon- ductor are of the itinerant nature while in the 245 superconductor the spin-waves of localized moments. The observation of superconducting resonance peak provides a cru- cial piece of information in current deliberation of the pairing symmetry in Fe-based superconductors.

preprint2013arXiv

Structured Spectrum Allocation and User Association in Heterogeneous Cellular Networks

We study joint spectrum allocation and user association in heterogeneous cellular networks with multiple tiers of base stations. A stochastic geometric approach is applied as the basis to derive the average downlink user data rate in a closed-form expression. Then, the expression is employed as the objective function in jointly optimizing spectrum allocation and user association, which is of non-convex programming in nature. A computationally efficient Structured Spectrum Allocation and User Association (SSAUA) approach is proposed, solving the optimization problem optimally when the density of users is low, and near-optimally with a guaranteed performance bound when the density of users is high. A Surcharge Pricing Scheme (SPS) is also presented, such that the designed association bias values can be achieved in Nash equilibrium. Simulations and numerical studies are conducted to validate the accuracy and efficiency of the proposed SSAUA approach and SPS.

preprint2013arXiv

Superconductivity tuned by the iron vacancy order in K$_{\bf x}$Fe$_{\bf 2-y}$Se$_2$

Combining in-depth neutron diffraction and systematic bulk studies, we discover that the $\sqrt{5}\times\sqrt{5}$ Fe vacancy order with its associated block antiferromagnetic order is the ground state, with varying occupancy ratio of the iron 16i and vacancy 4d sites, across the phase-diagram of K$_{\bf x}$Fe$_{\bf 2-y}$Se$_2$. The orthorhombic order with one of the four Fe sites vacant appears only at intermediate temperature as a competing phase. The material experiences an insulator to metal crossover when the $\sqrt{5}\times\sqrt{5}$ order has highly developed. Superconductivity occurs in such a metallic phase.

preprint2013arXiv

Understanding the Benefits of Open Access in Femtocell Networks: Stochastic Geometric Analysis in the Uplink

We introduce a comprehensive analytical framework to compare between open access and closed access in two-tier femtocell networks, with regard to uplink interference and outage. Interference at both the macrocell and femtocell levels is considered. A stochastic geometric approach is employed as the basis for our analysis. We further derive sufficient conditions for open access and closed access to outperform each other in terms of the outage probability, leading to closed-form expressions to upper and lower bound the difference in the targeted received power between the two access modes. Simulations are conducted to validate the accuracy of the analytical model and the correctness of the bounds.

preprint2011arXiv

77Se NMR study of pairing symmetry and spin dynamics in KyFe2-xSe2

We present a 77Se NMR study of the newly discovered iron selenide superconductor KyFe2-xSe2, in which Tc = 32 K. Below Tc, the Knight shift 77K drops sharply with temperature, providing strong evidence for singlet pairing. Above Tc, Korringa-type relaxation indicates Fermi-liquid behavior. Our experimental results set strict constraints on the nature of possible theories for the mechanism of high-Tc superconductivity in this iron selenide system.

preprint2011arXiv

A Novel Large Moment Antiferromagnetic Order in K0.8Fe1.6Se2 Superconductor

The discovery of cuprate high Tc superconductors has inspired searching for unconventional su- perconductors in magnetic materials. A successful recipe has been to suppress long-range order in a magnetic parent compound by doping or high pressure to drive the material towards a quantum critical point, which is replicated in recent discovery of iron-based high TC superconductors. The long-range magnetic order coexisting with superconductivity has either a small magnetic moment or low ordering temperature in all previously established examples. Here we report an exception to this rule in the recently discovered potassium iron selenide. The superconducting composition is identified as the iron vacancy ordered K0.8Fe1.6Se2 with Tc above 30 K. A novel large moment 3.31 μB/Fe antiferromagnetic order which conforms to the tetragonal crystal symmetry has the unprecedentedly high an ordering temperature TN = 559 K for a bulk superconductor. Staggeredly polarized electronic density of states thus is suspected, which would stimulate further investigation into superconductivity in a strong spin-exchange field under new circumstance.

preprint2011arXiv

Common Crystalline and Magnetic Structure of superconducting A2Fe4Se5

Single crystal neutron diffraction study has been performed on new superconductor A2Fe4Se5, where A = Cs, K, (Tl,Rb) and (Tl,K), and the same Fe vacancy ordered crystal structure and the same block checkerboard antiferromagne tic order recently discovered in the K2Fe4Se5 superconductor are observed. Thus, all known alkali metal and/or Tl intercalated iron selenide superconductors share common crystalline and magnetic structure. Investigation on electronic process in these new superconductors, for which a different electronic structure from those in previous Fe-based high-Tc superconductors is emerging, now has a valid structural and magnetic framework.

preprint2011arXiv

On the Structure of Vacancy Ordered Superconducting Alkali Metal Iron Selenide

With single crystal X-ray diffraction studies, we compare the structures of three sample showing optimal superconductivity, K0.774(4)Fe1.613(2)Se2, K0.738(6)Fe1.631(3)Se2 and Cs0.748(2)Fe1.626(1)Se2. All have an almost identical ordered vacancy structure with a ({\sqrt}5 x {\sqrt}5 x 1) super cell. The tetragonal unit cell, space group I4/m, possesses lattice parameters at 250K of a = b = 8.729(2) Å and c = 14.120(3) Å, a = b = 8.7186(12) Å and c = 14.0853(19) Å and at 295 K, a = b = 8.8617(16) Å and c = 15.304(3) Å for the three crystals, respectively. The structure contains two iron sites; one is almost completely empty, whilst the other is fully occupied. There are similarly two alkali metal sites that are occupied in the range of 72.2(2) % to 85.3(3) %. The inclusion of alkali metals and the presence of vacancies within the structure allows for considerable relaxation of the FeSe4 tetrahedron, compared with members of the Fe(Te, Se, S) series, and the resulting shift of the Se - F - Se bond angles to less distorted geometry could be important in understanding the associated increase in the superconducting transition temperature. The structure of these superconductors distinguishes themselves from the structure of the non-superconducting phases by an almost complete absence of Fe on the (0 0.5 0.25) site as well as lower alkali metal occupancy that ensures an exact Fe2+ oxidation state, which are clearly critical parameters in the promotion of superconductivity.

preprint2011arXiv

Superconductivity and normal state properties of single-crystalline Tl0.47Rb0.34Fe1.63Se2 as seen via 77Se and 87Rb NMR

We report both 77Se and 87Rb NMR studies on Tl0.47Rb0.34Fe1.63Se2 single-crystalline superconductors (T_c about 32 K). Singlet superconductivity is decisively determined by a sharp drop of the Knight shift K(T) below T_c, after subtracting the superconducting diamagnetic effect. However, the Hebel-Slichter coherence peak below T_c is not observed in the spin-lattice relaxation rate 1/T_1, even with a low in-plane NMR field of 2.6 Tesla. Just above T_c, no evidence of low-energy spin fluctuation is found in the spin-lattice relaxation rate on both the 77Se and the 87Rb sites. Upon warming, however, the Knight shifts and the spin-lattice relaxation rates of both nuclei increase substantially with temperature. In particular, the Knight shift is nearly isotropic and follow a function fit of K=a+bT^2 from T_c up to 300 K. These normal state properties may be an indication of thermally activated spin fluctuations. Our observations should put a strong constraint to the theory of magnetism and superconductivity in the newly discovered iron-based superconductors.

preprint2008arXiv

Unusual heavy-mass nearly ferromagnetic state with a surprisingly large Wilson ratio in the double layered ruthenates (Sr$_{1-x}$Ca$_{x}$)$_{3}$Ru$_{2}$O$_{7}$

We report an unusual nearly ferromagnetic, heavy-mass state with a surprisingly large Wilson ratio $R_{\textrm{w}}$ (e.g., $R_{\textrm{w}}\sim$ 700 for $x =$ 0.2) in double layered ruthenates (Sr$_{1-x}$Ca$_{x}$)$_{3}$Ru$_{2}$O$_{7}$ with 0.08 $< x <$ 0.4. This state does not evolve into a long-range ferromagnetically ordered state despite considerably strong ferromagnetic correlations, but freezes into a cluster-spin-glass at low temperatures. In addition, evidence of non-Fermi liquid behavior is observed as the spin freezing temperature of the cluster-spin-glass approaches zero near $x \approx$ 0.1. We discuss the origin of this unique magnetic state from the Fermi surface information probed by Hall effect measurements.

preprint2005arXiv

Novel Coexistence of Superconductivity with Two Distinct Magnetic Orders

The heavy fermion Ce(Rh,Ir)In5 system exhibits properties that range from an incommensurate antiferromagnet on the Rh-rich end to an exotic superconductor on the Ir-rich end of the phase diagram. At intermediate composition where antiferromagnetism coexists with superconductivity, two types of magnetic order are observed: the incommensurate one of CeRhIn5 and a new, commensurate antiferromagnetism that orders separately. The coexistence of f-electron superconductivity with two distinct f-electron magnetic orders is unique among unconventional superconductors, adding a new variety to the usual coexistence found in magnetic superconductors.

preprint2005arXiv

Partial spin freezing in the quasi-two-dimensional La2(Cu,Li)O4

In conventional spin glasses, the magnetic interaction is not strongly anisotropic and the entire spin system freezes at low temperature. In La2(Cu,Li)O4, for which the in-plane exchange interaction dominates the interplane one, only a fraction of spins with antiferromagnetic correlations extending to neighboring planes become spin-glass. The remaining spins with only in-plane antiferromagnetic correlations remain spin-liquid at low temperature. Such a novel partial spin freezing out of a spin-liquid observed in this cold neutron scattering study is likely due to a delicate balance between disorder and quantum fluctuations in the quasi-two dimensional S=1/2 Heisenberg system.