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Hao Zeng

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Published work

20 published item(s)

preprint2026arXiv

An Interpretable and Scalable Framework for Evaluating Large Language Models

Evaluation of large language models (LLMs) is increasingly critical, yet standard benchmarking methods rely on average accuracy, overlooking both the inherent stochasticity of LLM outputs and the heterogeneity of benchmark items. Item Response Theory (IRT) offers a principled framework for modeling latent model abilities and item characteristics, but conventional methods are computationally expensive and numerically unstable, limiting large-scale implementations. To address these challenges, we propose an interpretable and scalable framework for LLM evaluation based on the majorization-minimization principle. Our approach reformulates the problem as a sequence of constrained matrix factorization subproblems, enabling stable and efficient parameter estimation with theoretical guarantees for identifiability and convergence. Experiments on synthetic and real-world datasets, including MATH-500 and six Open LLM Leaderboard benchmarks, demonstrate that our method achieves superior scalability and interpretability. It delivers orders-of-magnitude speedups over competing methods while maintaining comparable or even higher estimation accuracy. Our results align with established scaling laws and offer insights into item difficulty and discrimination, informing more principled benchmark design.

preprint2025arXiv

Marangoni-driven freezing dynamics of supercooled binary droplets

Solidification of droplets is of great importance to various technological applications, drawing considerable attention from scientists aiming to unravel the fundamental physical mechanisms. In the case of multicomponent droplets undergoing solidification, the emergence of concentration gradients may trigger significant interfacial flows that dominate the freezing dynamics. Here, we experimentally investigate the fascinating interfacial freezing dynamics of supercooled ethanol-water droplets, accompanied with the migration and growth of massive ice particles. We reveal that these unique freezing dynamics are driven by solidification-induced solutal Marangoni flow within the droplets. Our model, which incorporates the temperature- and concentration-dependent properties of the ethanol-water mixture, quantitatively predicts both the migration velocity and the growth rate of the ice particles. The former is determined by the solutal Marangoni flow velocity, while the latter is governed by a balance between the latent heat release and the enhanced thermal dissipation by the Marangoni flow. Moreover, we show that the final wrapping state of droplets can be modulated by the concentration of ethanol. Our findings may pave the way for novel insights into the physicochemical hydrodynamics of multicomponent liquids undergoing phase transitions.

preprint2023arXiv

A Deep Reinforcement Learning Approach for Online Parcel Assignment

In this paper, we investigate the online parcel assignment (OPA) problem, in which each stochastically generated parcel needs to be assigned to a candidate route for delivery to minimize the total cost subject to certain business constraints. The OPA problem is challenging due to its stochastic nature: each parcel's candidate routes, which depends on the parcel's origin, destination, weight, etc., are unknown until its order is placed, and the total parcel volume is uncertain in advance. To tackle this challenge, we propose the PPO-OPA algorithm based on deep reinforcement learning that shows competitive performance. More specifically, we introduce a novel Markov Decision Process (MDP) framework to model the OPA problem, and develop a policy gradient algorithm that adopts attention networks for policy evaluation. By designing a dedicated reward function, our proposed algorithm can achieve a lower total cost with smaller violation of constraints, comparing to the traditional method which assigns parcels to candidate routes proportionally. In addition, the performances of our proposed algorithm and the Primal-Dual algorithm are comparable, while the later assumes a known total parcel volume in advance, which is unrealistic in practice.

preprint2022arXiv

Bone tumor suppression in rabbits by hyperthermia below the clinical safety limit using aligned magnetic bone cement

Demonstrating highly efficient alternating current (AC) magnetic field heating of nanoparticles in physiological environments under clinically safe field parameters has remained a great challenge, hindering clinical applications of magnetic hyperthermia. In this work, we report exceptionally high loss power of magnetic bone cement under clinical safety limit of AC field parameters, incorporating DC field-aligned soft magnetic Zn0.3Fe2.7O4 nanoparticles with low concentration. Under an AC field of 4 kA/m at 430 kHz, the aligned bone cement with 0.2 wt% nanoparticles achieved a temperature increase of 30 C in 180 s. This amounts to a specific loss power value of 327 W/gmetal and an intrinsic loss power of 47 nHm^2/kg, which is enhanced by 50-fold compared to randomly oriented samples. The high-performance magnetic bone cement allows for the demonstration of effective hyperthermia suppression of tumor growth in the bone marrow cavity of New Zealand White Rabbits subjecting to rapid cooling due to blood circulation, and significant enhancement of survival rate.

preprint2022arXiv

Dative epitaxy of commensurate monocrystalline covalent-van der Waals moiré supercrystal

Realizing van der Waals (vdW) epitaxy in the 80s represents a breakthrough that circumvents the stringent lattice matching and processing compatibility requirements in conventional covalent heteroepitaxy. However, due to the weak vdW interactions, there is little control over film qualities by the substrate. Typically, discrete domains with a spread of misorientation angles are formed, limiting the applicability of vdW epitaxy. Here we report the epitaxial growth of monocrystalline, covalent Cr5Te8 2D crystals on monolayer vdW WSe2 by chemical vapor deposition, driven by interfacial dative bond formation. The lattice of Cr5Te8, with a lateral dimension of a few ten microns, is fully commensurate with that of WSe2 via 3 x 3 (Cr5Te8)-7 x 7 (WSe2) supercell matching, forming a single crystalline moire superlattice. Our work has established a conceptually distinct paradigm of thin film epitaxy termed dative epitaxy, which takes full advantage of covalent epitaxy with chemical bonding for fixing the atomic registry and crystal orientation, while circumventing its stringent lattice matching and processing compatibility requirements; conversely, it ensures the full flexibility of vdW epitaxy, while avoiding its poor orientation control. Cr5Te8 2D crystals grown by dative epitaxy exhibit square magnetic hysteresis, suggesting minimized interfacial defects that can serve as pinning sites.

preprint2022arXiv

Transformer-based Multimodal Information Fusion for Facial Expression Analysis

Human affective behavior analysis has received much attention in human-computer interaction (HCI). In this paper, we introduce our submission to the CVPR 2022 Competition on Affective Behavior Analysis in-the-wild (ABAW). To fully exploit affective knowledge from multiple views, we utilize the multimodal features of spoken words, speech prosody, and facial expression, which are extracted from the video clips in the Aff-Wild2 dataset. Based on these features, we propose a unified transformer-based multimodal framework for Action Unit detection and also expression recognition. Specifically, the static vision feature is first encoded from the current frame image. At the same time, we clip its adjacent frames by a sliding window and extract three kinds of multimodal features from the sequence of images, audio, and text. Then, we introduce a transformer-based fusion module that integrates the static vision features and the dynamic multimodal features. The cross-attention module in the fusion module makes the output integrated features focus on the crucial parts that facilitate the downstream detection tasks. We also leverage some data balancing techniques, data augmentation techniques, and postprocessing methods to further improve the model performance. In the official test of ABAW3 Competition, our model ranks first in the EXPR and AU tracks. The extensive quantitative evaluations, as well as ablation studies on the Aff-Wild2 dataset, prove the effectiveness of our proposed method.

preprint2021arXiv

An Extrapolated Iteratively Reweighted l1 Method with Complexity Analysis

The iteratively reweighted l1 algorithm is a widely used method for solving various regularization problems, which generally minimize a differentiable loss function combined with a nonconvex regularizer to induce sparsity in the solution. However, the convergence and the complexity of iteratively reweighted l1 algorithms is generally difficult to analyze, especially for non-Lipschitz differentiable regularizers such as nonconvex lp norm regularization. In this paper, we propose, analyze and test a reweighted l1 algorithm combined with the extrapolation technique under the assumption of Kurdyka-Lojasiewicz (KL) property on the objective. Unlike existing iteratively reweighted l1 algorithms with extrapolation, our method does not require the Lipschitz differentiability on the regularizers nor the smoothing parameters in the weights bounded away from zero. We show the proposed algorithm converges uniquely to a stationary point of the regularization problem and has local linear complexity--a much stronger result than existing ones. Our numerical experiments show the efficiency of our proposed method.

preprint2021arXiv

Convergence Rate Analysis of Proximal Iteratively Reweighted $\ell_1$ Methods for $\ell_p$ Regularization Problems

In this paper, we focus on the local convergence rate analysis of the proximal iteratively reweighted $\ell_1$ algorithms for solving $\ell_p$ regularization problems, which are widely applied for inducing sparse solutions. We show that if the Kurdyka-Lojasiewicz (KL) property is satisfied, the algorithm converges to a unique first-order stationary point; furthermore, the algorithm has local linear convergence or local sublinear convergence. The theoretical results we derived are much stronger than the existing results for iteratively reweighted $\ell_1$ algorithms.

preprint2021arXiv

Covalent 2D Cr$_2$Te$_3$ ferromagnet

To broaden the scope of van der Waals 2D magnets, we report the synthesis and magnetism of covalent 2D magnetic Cr$_2$Te$_3$ with a thickness down to one-unit-cell. The 2D Cr$_2$Te$_3$ crystals exhibit robust ferromagnetism with a Curie temperature of 180 K, a large perpendicular anisotropy of 7*105 J m-3, and a high coercivity of ~ 4.6 kG at 20 K. First-principles calculations further show a transition from canted to collinear ferromagnetism, a transition from perpendicular to in-plane anisotropy, and emergent half-metallic behavior in atomically-thin Cr$_2$Te$_3$, suggesting its potential application for injecting carriers with high spin polarization into spintronic devices.

preprint2021arXiv

PcmNet: Position-Sensitive Context Modeling Network for Temporal Action Localization

Temporal action localization is an important and challenging task that aims to locate temporal regions in real-world untrimmed videos where actions occur and recognize their classes. It is widely acknowledged that video context is a critical cue for video understanding, and exploiting the context has become an important strategy to boost localization performance. However, previous state-of-the-art methods focus more on exploring semantic context which captures the feature similarity among frames or proposals, and neglect positional context which is vital for temporal localization. In this paper, we propose a temporal-position-sensitive context modeling approach to incorporate both positional and semantic information for more precise action localization. Specifically, we first augment feature representations with directed temporal positional encoding, and then conduct attention-based information propagation, in both frame-level and proposal-level. Consequently, the generated feature representations are significantly empowered with the discriminative capability of encoding the position-aware context information, and thus benefit boundary detection and proposal evaluation. We achieve state-of-the-art performance on both two challenging datasets, THUMOS-14 and ActivityNet-1.3, demonstrating the effectiveness and generalization ability of our method.

preprint2020arXiv

Controlling valley splitting and Polarization of dark- and bi-excitons in monolayer WS$_2$ by a tilted magnetic field

We developed a comprehensive theoretical framework focusing on many-body effects of exciton species in monolayer WS$_2$, including bright and dark excitons, and intra- and inter-valley biexcitons, to investigate valley dynamics in monolayer WS$_2$ subjected to a tilted magnetic field B. In particular, the evolution of the exciton population densities and the many-body particle scatterings are considered to calculate the valley polarization (V P ) as a function of the magnetic field. We found valley splittings for the dark exciton and biexciton energy levels that are larger than those of bright excitons, of -0.23 meV/T. For example, -0.46 meV/T for dark excitons and -0.69 meV/T for bright-dark intra-valley biexcitons. Furthermore, inter-valley bright-dark excitons have an opposite valley energy splittings of +0.23 meV/T. For the samples pumped by linearly polarized light, V P exhibits distinct magnetic field dependence for different types of many-body particle states. Among them, the V P of the intra-valley bright-dark biexcitons increases with increasing magnetic field and reaches nearly 50% at B=65 T. The brightened dark exciton, on the other hand, exhibits vanishing VP, indicating long valley relaxation time. Remarkably, the inter-valley bright-dark biexciton shows unconventional behavior with an inverted VP. The opposite VP for intra- and inter-valley bright-dark biexcitons, coupled with their large valley splitting and long valley lifetime may facilitate their coherent manipulation for quantum computing.

preprint2020arXiv

Prediction of Ternary Fluorooxoborates with Coplanar Triangle Units [BOxF3-x]x- From First-Principles

Ten new ternary fluorooxoborate structures were obtained from first-principles prediction. Coplanar aligned triangle structure units [BO2F]2- and [BOF2]- like [BO3]3- in borates were found from the computational simulation. We identified new covalent coordination patterns of the F atom connected with the B atoms which are located in the bridging site, -B--F--B-. Besides, one molecular crystal with [B4O4F4] molecular unit was attached.

preprint2020arXiv

Thermoelectric probe of defect state induced by ionic liquid gating in vanadium dioxide

Thermoelectric measurements detect the asymmetry between the density of states above and below the chemical potential in a material. It provides insights into small variations in the density of states near the chemical potential, complementing electron transport measurements. Here, combined resistance and thermoelectric power measurements are performed on vanadium dioxide (VO2), a prototypical correlated electron material, under ionic-liquid (IL) gating. With IL gating, charge transport below the metal-to-insulator-transition (MIT) temperature remains in the thermally activated regime, while the Seebeck coefficient exhibits an apparent transition from semiconducting to metallic behavior. The contrasting behavior indicates changes in electronic structure upon IL gating, due to the formation of oxygen defect states. The experimental results are corroborated by numerical simulations based on a model density of states incorporating a gating induced defect band. This study reveals thermoelectric measurements to be a convenient and sensitive probe for the role of defect states induced by IL gating in suppressing the MIT in VO2, which remains benign in charge transport measurements, and possibly for studying defect sates in other materials.

preprint2020arXiv

Ti-alloying of BaZrS3 chalcogenide perovskite for photovoltaics

BaZrS3, a prototypical chalcogenide perovskite, has been shown to possess a direct band gap, an exceptionally strong near band edge light absorption, and good carrier transport. Coupled with its great stability, non-toxicity with earth abundant elements, it is thus a promising candidate for thin film solar cells. However, its reported band gap in the range of 1.7-1.8 eV is larger than the optimal value required to reach the Shockley-Queisser limit of a single junction solar cell. Here we report the synthesis of Ba(Zr1-xTix)S3 perovskite compounds with a reduced band gap. It is found that Ti alloying is extremely effective in band gap reduction of BaZrS3: a mere 4 at% alloying decreases the band gap from 1.78 to 1.51 eV, resulting in a theoretical maximum power conversion efficiency of 32%. Higher Ti-alloying concentration is found to destabilize the distorted chalcogenide perovskite phase.

preprint2016arXiv

Chalcogenide Perovskites- an Emerging Class of Ionic Semiconductors

We report the synthesis and characterization of a novel class of ionic semiconductor materials- inorganic chalcogenide perovskites. Several different compounds including BaZrS3, CaZrS3, SrTiS3 and SrZrS3 were synthesized by high temperature sulfurization of their oxide counterparts. Their crystal structures were identified by XRD and composition by EDX. UV-vis and photoluminescence measurements confirmed that they are direct gap semiconductors with band gap values consistent with theoretical predictions. By adopting an anion alloying approach, we demonstrate widely tunable band gap from 1.73 eV to 2.87 eV. These strongly ionic semiconductors provide a new avenue for engineering the semiconducting properties for applications such as energy harvesting, solid state lighting and sensing.

preprint2013arXiv

Realizing Chemical Codoping in Oxide Semiconductors

We demonstrate experimentally a chemical codoping approach that would simultaneously narrow the band gap and control the band edge positions of oxide semiconductors. Using TiO2 as an example, we show that a sequential doping scheme with nitrogen (N) leading the way, followed by phosphorous (P), is crucial for the incorporation of both N and P into the anion sites. Various characterization techniques confirm the formation of the N-P bonds, and as a consequence of the chemical codoping, the band gap of the TiO2 is reduced from 3.0 eV to 1.8 eV. The realization of chemical codoping could be an important step forward in improving the general performance of electronic and optoelectronic materials and devices.

preprint2012arXiv

Carrier-Dopant Exchange Interactions in Mn-doped PbS Colloidal Quantum Dots

Carrier-dopant exchange interactions in Mn-doped PbS colloidal quantum dots were studied by circularly polarized magneto-photoluminescence. Mn substitutional doping leads to paramagnetic behavior down to 5 K. While undoped quantum dots show negative circular polarization, Mn doping changes its sign to positive. A circular polarization value of 40% was achieved at T=7 K and B=7 tesla. The results are interpreted in terms of Zeeman splitting of the band edge states in the presence of carrier-dopant exchange interactions that are qualitatively different from the s,p-d exchange interactions in II-VI systems.

preprint2011arXiv

Anisotropic paramagnetism of monoclinic Nd2Ti2O7 single crystals

The anisotropic paramagnetism and specific heat in Nd2Ti2O7 single crystals are investigated. Angular dependence of the magnetization and Weiss temperatures show the dominant role of the crystal field effect in the magnetization. By incorporating the results from the diluted samples, contributions to Weiss temperature from exchange interactions and crystal field interactions are isolated. The exchange interactions are found to be ferromagnetic, while the crystal field contributes a large negative part to the Weiss temperature, along all three crystallographic directions. The specific heat under magnetic field reveals a two-level Schottky ground state scheme, due to the Zeeman splitting of the ground state doublet, and the g-factors are thus determined. These observations provide solid foundations for further investigations of Nd2Ti2O7.

preprint2011arXiv

Giant Positive Magnetoresistance in Co@CoO Nanoparticle Arrays

We report the magnetotransport properties of self-assembled Co@CoO nanoparticle arrays at temperatures below 100 K. Resistance shows thermally activated behavior that can be fitted by the general expression of R exp{(T/T0)^v}. Efros-Shklovskii variable range hopping (v=1/2) and simple activation (hard gap, v=1) dominate the high and low temperature region, respectively, with a strongly temperature-dependent transition regime in between. A giant positive magnetoresistance of >1,400% is observed at 10K, which decreases with increasing temperature. The positive MR and most of its features can be explained by the Zeeman splitting of the localized states that suppresses the spin dependent hopping paths in the presence of on-site Coulomb repulsion.

preprint2010arXiv

Emergent order in the spin-frustrated system DyxTb2-xTi2O7 studied by ac susceptibility measurements

We report the a.c. susceptibility study of Dy_xTb_{2-x}Ti_2O_7 with x in [0, 2]. In addition to the single-ion effect at Ts (single-ion effect peak temperature) corresponding to the Dy3+ spins as that in spin ice Dy_2Ti_2O_7 and a possible spin freezing peak at Tf (Tf < 3 K), a new peak associated with Tb^{3+} is observed in $χ_{ac}(T)$ at nonzero magnetic field with a characteristic temperature T^* (Tf < T^* < Ts). T^* increases linearly with x in a wide composition range (0 < x < 1.5 at 5 kOe). Both application of a magnetic field and increasing doping with Dy3+ enhance T^*. The T^* peak is found to be thermally driven with an unusually large energy barrier as indicated from its frequency dependence. These effects are closely related to the crystal field levels, and the underlying mechanism remains to be understood.