Strong Valence Fluctuation Effects in SmTr2Tr_2Al20_{20}(Tr=Tr=Ti, V, Cr)

preprint2011arXivOpen access

Abstract

We present a single crystal study of low temperature magnetism and transport in SmTr2Tr_2Al20_{20} (Tr=Tr = Ti, V and Cr). Strong valence fluctuation is manifested as Kondo effects including a large Sommerfeld coefficient γγ, a weak temperature dependence of magnetic susceptibility and a −ln⁡T-\ln T dependent resistivity. All the systems order antiferromagnetically at TN=T_{\rm N}= 6.4 K (Ti), 2.3 K (V) and 1.8 K (Cr). Systematic change in the susceptibility, specific heat, and resistivity indicates that stronger cc-ff hybridization in SmV2_2Al20_{20} and SmCr2_2Al20_{20} than in SmTi2_2Al20_{20} suppresses TNT_{\rm N} and induces the valence fluctuations and moreover field insensitive heavy fermion states.

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