Paper detail

Spin-state Crossover Model for the Magnetism of Iron Pnictides

We propose a minimal model describing magnetic behavior of Fe-based superconductors. The key ingredient of the model is a dynamical mixing of quasi-degenerate spin states of Fe2+ ion by intersite electron hoppings, resulting in an effective local spin Seff. The moments Seff tend to form singlet pairs, and may condense into a spin nematic phase due to the emergent biquadratic exchange couplings. The long-range ordered part m of Seff varies widely, 0<=m<=Seff, but magnon spectra are universal and scale with Seff, resolving the puzzle of large but fluctuating Fe-moments. Unusual temperature dependences of a local moment and spin susceptibility are also explained.