Relativistic Scott correction in self-generated magnetic fields

preprint2012arXivOpen access

Abstract

We consider a large neutral molecule with total nuclear charge ZZ in a model with self-generated classical magnetic field and where the kinetic energy of the electrons is treated relativistically. To ensure stability, we assume that Zα<2/πZ α< 2/π, where αα denotes the fine structure constant. We are interested in the ground state energy in the simultaneous limit Z→∞Z \rightarrow \infty, α→0α\rightarrow 0 such that κ=Zακ=Z α is fixed. The leading term in the energy asymptotics is independent of κκ, it is given by the Thomas-Fermi energy of order Z7/3Z^{7/3} and it is unchanged by including the self-generated magnetic field. We prove the first correction term to this energy, the so-called Scott correction of the form S(αZ)Z2S(αZ) Z^2. The current paper extends the result of \cite{SSS} on the Scott correction for relativistic molecules to include a self-generated magnetic field. Furthermore, we show that the corresponding Scott correction function SS, first identified in \cite{SSS}, is unchanged by including a magnetic field. We also prove new Lieb-Thirring inequalities for the relativistic kinetic energy with magnetic fields.

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