Non-Equilibrium Thermodynamics and Stochasticity, A Phenomenological Look on Jarzynki's Equality

preprint2016arXivOpen access

Abstract

The theory of phenomenological Non-equilibrium Thermodynamics is extended by includimg stochastic processes in order to account for recently derived thermodynamical relations such as the Jarzynski equality. Four phenomenological axioms are postulated resulting in a phenomenological interpretation of Jarzynski's equality. Especially, considering the class of Jarzynski processes Jarzynski's equality follows from the axiom that the statistical average of the exponential work is protocol independent.

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