Abstract

We report that CaMn7_7O12_{12} is a new magnetic multiferroic material. The appearance of a ferroelectric polarization coinciding with the magnetic phase transition (∼90\sim90 K) suggests the presence of ferroelectricity induced by magnetism, further confirmed by its strong magnetoelectric response. With respect to other known magnetic multiferroics, CaMn7_7O12_{12} displays attractive multiferroic properties, such as a high ferroelectric critical temperature and large polarization. More importantly, these results open a new avenue to search for magnetic multiferroics in the catalogue of doped oxides.

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