Microscopic observation of superconducting fluctuations in κκ-(BEDT-TTF)2_{2}Cu[N(CN)2_{2}]Br by 13^{13}C NMR spectroscopy

preprint2014arXivOpen access

Abstract

We performed 13^{13}C-NMR experiment and measured spin-lattice relaxation rate divided by temperature 1/T1T1/T_{1}T near the superconducting (SC) transition temperature TcT_{c} in κκ-(BEDT-TTF)2_{2}Cu[N(CN)2_{2}]Br (κκ-Br salt), and κκ-(BEDT-TTF)2_{2}Cu(NCS)2_{2} (κκ-NCS salt). We observed the reduction of 1/T1T1/T_{1}T starting at the temperature higher than TcT_c in κκ-Br salt. Microscopic observation of quasi-particle density of states in the fluctuating SC state revealed the effects of short-range Cooper pairs induced in the normal state to the quasi-particle density of states. We also performed systematic measurements in the fields both parallel and perpendicular to the conduction plane in κκ-Br and κκ-NCS salts, and confirmed that the reduction of 1/T1T1/T_{1}T above TcT_{c} is observed only in κκ-Br salt regardless of the external field orientation.

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