Inter-grain tunneling in the half-metallic double-perovskites Sr2_2BB'O6_6 (BB'-- FeMo, FeRe, CrMo, CrW, CrRe

preprint2013arXivOpen access

Abstract

The zero-field conductivities (σσ) of the polycrystaline title materials, are governed by inter-grain transport. In the majority of cases their σσ(T) can be described by the "fluctuation induced tunneling" model. Analysis of the results in terms of this model reveals two remarkable features: 1. For \emph{all} Sr2_2FeMoO6_6 samples of various microstructures, the tunneling constant (barrier width ×\times inverse decay-length of the wave-function) is ∼\sim 2, indicating the existence of an intrinsic insulating boundary layer with a well defined electronic (and magnetic) structure. 2. The tunneling constant for \emph{all} cold-pressed samples decreases linearly with increasing magnetic-moment/formula-unit.

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