Ground state energy of large atoms in a self-generated magnetic field

preprint2009arXivOpen access

Abstract

We consider a large atom with nuclear charge ZZ described by non-relativistic quantum mechanics with classical or quantized electromagnetic field. We prove that the absolute ground state energy, allowing for minimizing over all possible self-generated electromagnetic fields, is given by the non-magnetic Thomas-Fermi theory to leading order in the simultaneous Z→∞Z\to \infty, $\al\to 0$ limit if $Z\al^2\leq κ$ for some universal κκ, where $\al$ is the fine structure constant.

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