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Distinct magnetic phase transition at the surface of an antiferromagnet

In the majority of magnetic systems the surface is required to order at the same temperature as the bulk. In the present study, we report a distinct and unexpected surface magnetic phase transition, uniquely at a lower temperature than the Néel temperature. Employing grazing incidence X-ray resonant magnetic scattering we have observed the near surface behavior of uranium dioxide. UO$_2$ is a non-collinear, triple-q, antiferromagnet with the U ions on an face-centered-cubic lattice. Theoretical investigations establish that at the surface the energy increase, due to the lost bonds, reduces when the spins near the surface rotate, gradually losing their normal to the surface component. At the surface the lowest-energy spin configuration has a double-q (planar) structure. With increasing temperature, thermal fluctuations saturate the in-plane crystal field anisotropy at the surface, leading to soft excitations that have ferromagnetic $XY$ character and are decoupled from the bulk. The structure factor of a finite two-dimensional $XY$ model, fits the experimental data well for several orders of magnitude of the scattered intensity. Our results support a distinct magnetic transition at the surface in the Kosterlitz-Thouless universality class.