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Published work

33 published item(s)

preprint2026arXiv

On the (In-)Security of the Shuffling Defense in the Transformer Secure Inference

For Transformer models, cryptographically secure inference ensures that the client learns only the final output, while the server learns nothing about the client's input. However, securely computing nonlinear layers remains a major efficiency bottleneck due to the substantial communication rounds and data transmission required. To address this issue, prior works reveal intermediate activations to the client, allowing nonlinear operations to be computed in plaintext. Although this approach significantly improves efficiency, exposing activations enables adversaries to extract model weights. To mitigate this risk, existing works employ a shuffling defense that reveals only randomly permuted activations to the client. In this work, we show that the shuffling defense is not as robust as previously claimed. We propose an attack that aligns differently shuffled activations to a common permutation and subsequently exploits them to extract model weights. Experiments on Pythia-70m and GPT-2 demonstrate that the proposed attack can align shuffled activations with mean squared errors ranging from $10^{-9}$ to $10^{-6}$. With a query cost of approximately \$1, the adversary can recover model weights with L1-norm differences ranging from $10^{-4}$ to $10^{-2}$ compared to the oracle weights.

preprint2023arXiv

The application of Nano-silica gel in sealing well micro-annuli and cement channeling

The possibility for hydrocarbon fluids to migrate through debonded micro-annuli wells is a major concern in the petroleum industry. With effective permeability of 0.1-1.0 mD, the existence of channels in a cement annulus with apertures of 10-300 micrometer constitutes a major threat. Squeeze cement is typically difficult to repair channels-leakage with small apertures; hence, a low-viscosity sealer that can be inserted into these channels while producing a long-term resilient seal is sought. A novel application using nano-silica sealants could be the key to seal these channels. In the construction and sealing of hydrocarbon wells, cementing is a critical phase. Cement is prone to cracking during the life cycle of a well because of the changes in downhole conditions. The usage of micro-sized cross-linked nano-silica gel as a sealant material to minimize damaged cement sheaths is investigated in this study. Fluid leakage through channels in the cement was investigated using an experimental system. With a diameter of 0.05 inches, the impact of the cement channel size was explored. The sealing efficiency increased from 86 percent to 95 percent when the nano-silica concentration of the sealing gel increased from 13 percent to 25 percent. This demonstrates that the concentration of nano-silica in the sealing gel affects the gel's ability to seal against fluid flow. This research proposes a new way for improving cement zonal isolation and thereby lowering the impact of cement failure in the oil and gas industry.

preprint2023arXiv

Well Cement Degradation and Wellbore Integrity in Geological CO2 Storages: A Literature Review

Carbon capture and storage (CCS) has emerged as the most effective method to curb the CO2 concentration in the atmosphere. It can store up to 5 billion tons of CO2 per year. To guarantee a safe and economical geological storage, the well cement degradation and wellbore integrity need to be studied thoroughly. This review paper is designed to provide a fundamental background of well cement degradation and wellbore integrity in geological CO2 storages to support the researchers in further investigation. The review mainly focuses on mechanical, thermal, chemical property changes and corrosion time for cement in experiments and simulation during geological CO2 storage. However, the debonding interface between casing/cement or cement/formation has not been addressed profoundly. A further investigation should inspect how pressure, temperature, and chemical reaction affect the micro-annuli of casing/cement or cement/formation. Also, a mathe-matical model should be established to predict the corrosion rate in geological CO2 storage.

preprint2022arXiv

An Automatic and Efficient BERT Pruning for Edge AI Systems

With the yearning for deep learning democratization, there are increasing demands to implement Transformer-based natural language processing (NLP) models on resource-constrained devices for low-latency and high accuracy. Existing BERT pruning methods require domain experts to heuristically handcraft hyperparameters to strike a balance among model size, latency, and accuracy. In this work, we propose AE-BERT, an automatic and efficient BERT pruning framework with efficient evaluation to select a "good" sub-network candidate (with high accuracy) given the overall pruning ratio constraints. Our proposed method requires no human experts experience and achieves a better accuracy performance on many NLP tasks. Our experimental results on General Language Understanding Evaluation (GLUE) benchmark show that AE-BERT outperforms the state-of-the-art (SOTA) hand-crafted pruning methods on BERT$_{\mathrm{BASE}}$. On QNLI and RTE, we obtain 75\% and 42.8\% more overall pruning ratio while achieving higher accuracy. On MRPC, we obtain a 4.6 higher score than the SOTA at the same overall pruning ratio of 0.5. On STS-B, we can achieve a 40\% higher pruning ratio with a very small loss in Spearman correlation compared to SOTA hand-crafted pruning methods. Experimental results also show that after model compression, the inference time of a single BERT$_{\mathrm{BASE}}$ encoder on Xilinx Alveo U200 FPGA board has a 1.83$\times$ speedup compared to Intel(R) Xeon(R) Gold 5218 (2.30GHz) CPU, which shows the reasonableness of deploying the proposed method generated subnets of BERT$_{\mathrm{BASE}}$ model on computation restricted devices.

preprint2022arXiv

CAEN: A Hierarchically Attentive Evolution Network for Item-Attribute-Change-Aware Recommendation in the Growing E-commerce Environment

Traditional recommendation systems mainly focus on modeling user interests. However, the dynamics of recommended items caused by attribute modifications (e.g. changes in prices) are also of great importance in real systems, especially in the fast-growing e-commerce environment, which may cause the users' demands to emerge, shift and disappear. Recent studies that make efforts on dynamic item representations treat the item attributes as side information but ignore its temporal dependency, or model the item evolution with a sequence of related users but do not consider item attributes. In this paper, we propose Core Attribute Evolution Network (CAEN), which partitions the user sequence according to the attribute value and thus models the item evolution over attribute dynamics with these users. Under this framework, we further devise a hierarchical attention mechanism that applies attribute-aware attention for user aggregation under each attribute, as well as personalized attention for activating similar users in assessing the matching degree between target user and item. Results from the extensive experiments over actual e-commerce datasets show that our approach outperforms the state-of-art methods and achieves significant improvements on the items with rapid changes over attributes, therefore helping the item recommendation to adapt to the growth of the e-commerce platform.

preprint2022arXiv

DAIS: Automatic Channel Pruning via Differentiable Annealing Indicator Search

The convolutional neural network has achieved great success in fulfilling computer vision tasks despite large computation overhead against efficient deployment. Structured (channel) pruning is usually applied to reduce the model redundancy while preserving the network structure, such that the pruned network can be easily deployed in practice. However, existing structured pruning methods require hand-crafted rules which may lead to tremendous pruning space. In this paper, we introduce Differentiable Annealing Indicator Search (DAIS) that leverages the strength of neural architecture search in the channel pruning and automatically searches for the effective pruned model with given constraints on computation overhead. Specifically, DAIS relaxes the binarized channel indicators to be continuous and then jointly learns both indicators and model parameters via bi-level optimization. To bridge the non-negligible discrepancy between the continuous model and the target binarized model, DAIS proposes an annealing-based procedure to steer the indicator convergence towards binarized states. Moreover, DAIS designs various regularizations based on a priori structural knowledge to control the pruning sparsity and to improve model performance. Experimental results show that DAIS outperforms state-of-the-art pruning methods on CIFAR-10, CIFAR-100, and ImageNet.

preprint2022arXiv

Differentiable Multi-Agent Actor-Critic for Multi-Step Radiology Report Summarization

The IMPRESSIONS section of a radiology report about an imaging study is a summary of the radiologist's reasoning and conclusions, and it also aids the referring physician in confirming or excluding certain diagnoses. A cascade of tasks are required to automatically generate an abstractive summary of the typical information-rich radiology report. These tasks include acquisition of salient content from the report and generation of a concise, easily consumable IMPRESSIONS section. Prior research on radiology report summarization has focused on single-step end-to-end models -- which subsume the task of salient content acquisition. To fully explore the cascade structure and explainability of radiology report summarization, we introduce two innovations. First, we design a two-step approach: extractive summarization followed by abstractive summarization. Second, we additionally break down the extractive part into two independent tasks: extraction of salient (1) sentences and (2) keywords. Experiments on English radiology reports from two clinical sites show our novel approach leads to a more precise summary compared to single-step and to two-step-with-single-extractive-process baselines with an overall improvement in F1 score Of 3-4%.

preprint2022arXiv

Effective Few-Shot Named Entity Linking by Meta-Learning

Entity linking aims to link ambiguous mentions to their corresponding entities in a knowledge base, which is significant and fundamental for various downstream applications, e.g., knowledge base completion, question answering, and information extraction. While great efforts have been devoted to this task, most of these studies follow the assumption that large-scale labeled data is available. However, when the labeled data is insufficient for specific domains due to labor-intensive annotation work, the performance of existing algorithms will suffer an intolerable decline. In this paper, we endeavor to solve the problem of few-shot entity linking, which only requires a minimal amount of in-domain labeled data and is more practical in real situations. Specifically, we firstly propose a novel weak supervision strategy to generate non-trivial synthetic entity-mention pairs based on mention rewriting. Since the quality of the synthetic data has a critical impact on effective model training, we further design a meta-learning mechanism to assign different weights to each synthetic entity-mention pair automatically. Through this way, we can profoundly exploit rich and precious semantic information to derive a well-trained entity linking model under the few-shot setting. The experiments on real-world datasets show that the proposed method can extensively improve the state-of-the-art few-shot entity linking model and achieve impressive performance when only a small amount of labeled data is available. Moreover, we also demonstrate the outstanding ability of the model's transferability.

preprint2022arXiv

FuncFooler: A Practical Black-box Attack Against Learning-based Binary Code Similarity Detection Methods

The binary code similarity detection (BCSD) method measures the similarity of two binary executable codes. Recently, the learning-based BCSD methods have achieved great success, outperforming traditional BCSD in detection accuracy and efficiency. However, the existing studies are rather sparse on the adversarial vulnerability of the learning-based BCSD methods, which cause hazards in security-related applications. To evaluate the adversarial robustness, this paper designs an efficient and black-box adversarial code generation algorithm, namely, FuncFooler. FuncFooler constrains the adversarial codes 1) to keep unchanged the program's control flow graph (CFG), and 2) to preserve the same semantic meaning. Specifically, FuncFooler consecutively 1) determines vulnerable candidates in the malicious code, 2) chooses and inserts the adversarial instructions from the benign code, and 3) corrects the semantic side effect of the adversarial code to meet the constraints. Empirically, our FuncFooler can successfully attack the three learning-based BCSD models, including SAFE, Asm2Vec, and jTrans, which calls into question whether the learning-based BCSD is desirable.

preprint2022arXiv

IPAPRec: A promising tool for learning high-performance mapless navigation skills with deep reinforcement learning

This paper studies how to improve the generalization performance and learning speed of the navigation agents trained with deep reinforcement learning (DRL). Although DRL exhibits huge potential in robot mapless navigation, DRL agents performing well in training scenarios are often found to perform poorly in unfamiliar scenarios. In this work, we propose that the representation of LiDAR readings is a key factor behind the degradation of agents' performance and present a powerful input pre-processing (IP) approach to address this issue. As this approach uses adaptively parametric reciprocal functions to pre-process LiDAR readings, we refer to this approach as IPAPRec and its normalized version as IPAPRecN. IPAPRec/IPAPRecN can highlight important short-distance values and compress the range of less-important long-distance values in laser scans, which well address the issues induced by conventional representations of laser scans. Their high performance was validated by extensive simulation and real-world experiments. The results show that our methods can substantially improve navigation agents' generalization performance and greatly reduce the training time compared to conventional methods.

preprint2022arXiv

The Green polynomials via vertex operators

An iterative formula for the Green polynomial is given using the vertex operator realization of the Hall-Littlewood function. Based on this, (1) a general combinatorial formula of the Green polynomial is given; (2) several compact formulas are given for Green's polynomials associated with upper partitions of length $\leq 3$ and the diagonal lengths $\leq 3$; (3) a Murnaghan-Nakayama type formula for the Green polynomial is obtained; and (4) an iterative formula is derived for the bitrace of the finite general linear group $G$ and the Iwahori-Hecke algebra of type $A$ on the permutation module of $G$ by its Borel subgroup.

preprint2021arXiv

Design of Polar Code Lattices of Small Dimension

Polar code lattices are formed from binary polar codes using Construction D. In this paper, we propose a design technique for finite-dimension polar code lattices. The dimension $n$ and target probability of decoding error are parameters for this design. To select the rates of the Construction D component codes, rather than using the capacity as in past work, we use the explicit finite-length properties of the polar code. Under successive cancellation decoding, density evolution allows choosing code rates that satisfy the equal error probability rule. At an error-rate of $10^{-4}$, a dimension $n=128$ polar code lattice achieves a VNR of 2.5 dB, within 0.2 dB of the best-known BCH code lattice, but with significantly lower decoding complexity.

preprint2021arXiv

Lepton flavor violating Higgs decay $h\rightarrow μτ$ in the littlest Higgs Model with T-parity

Inspired by the recent CMS $h \to μτ$ excess, we calculate the lepton flavor violating Higgs decay $h \to μτ$ in the littlest Higgs model with T-parity (LHT). Under the constraints of $\ell_i \to \ell_j γ$, $Z \to \ell_i \bar{\ell}_j$ and Higgs data, we find that the branching ratio of $h \to μτ$ can maximally reach $\mathcal O(10^{-4})$. We also investigate the correlation between $h \to μτ$, $τ\to μγ$ and $Z \to μτ$, which can be used to test LHT model at future $e^+e^-$ colliders.

preprint2021arXiv

LSM-DFN Modeling for Seismic Responses in Complex Fractured Media: Comparison of Static and Dynamic Elastic Moduli

Crack microgeometries pose a paramount influence on effective elastic characteristics and sonic responses. Geophysical exploration based on seismic methods are widely used to assess and understand the presence of fractures. Numerical simulation as a promising way for this issue, still faces some challenges. With the rapid development of computers and computational techniques, discrete-based numerical approaches with desirable properties have been increasingly developed, but have not yet extensively applied to seismic response simulation for complex fractured media. For this purpose, we apply the coupled LSM-DFN model (Liu and Fu, 2020b) to examining the validity in emulating elastic wave propagation and scattering in naturally-fractured media. By comparing to the theoretical values, the implement of the schema is validated with input parameters optimization. Moreover, dynamic elastic moduli from seismic responses are calculated and compared with static ones from quasi-static loading of uniaxial compression tests. Numerical results are consistent with the tendency of theoretical predictions and available experimental data. It shows the potential for reproducing the seismic responses in complex fractured media and quantitatively investigating the correlations and differences between static and dynamic elastic moduli.

preprint2021arXiv

On irreducible characters of the Iwahori-Hecke algebra in type $A$

We use vertex operators to compute irreducible characters of the Iwahori-Hecke algebra of type $A$. Two general formulas are given for the irreducible characters in terms of those of the symmetric groups or the Iwahori-Hecke algebras in lower degrees. Explicit formulas are derived for the irreducible characters labeled by hooks and two-row partitions. Using duality, we also formulate a determinant type Murnaghan-Nakayama formula and give another proof of Ram's combinatorial Murnaghan-Nakayama formula. As applications, we study super-characters of the Iwahori-Hecke algebra as well as the bitrace of the regular representation and provide a simple proof of the Halverson-Luduc-Ram formula.

preprint2020arXiv

Black and White Anatase, Rutile and Mixed Forms: Band-Edges and Photocatalytic Activity

Here we investigate the band-level energetics of "black" hydrogenated titania in different polymorphs using in-situ photoelectrochemical measurements and XPS valence band measurements. We find that the conduction band of black rutile is higher in energy than in black anatase by 0.4 eV. For photocatalytic hydrogen generation, in a polymorph hetero-junction such as in black Degussa P25, thus black rutile can act as a photosensitizer while black anatase provides charge-mediation catalysis onto H2O to generate H2. By optimizing the thermal reduction conditions of black anatase/rutile junctions the H2 production can be significantly increased.

preprint2020arXiv

Black Magic in Gray Titania: Noble-Metal-Free Photocatalytic H2 Evolution from Hydrogenated Anatase

"Black" TiO2 has gained increasing interest because of its outstanding properties and promising applications in a wide range of fields. Among the outstanding features of the material is that certain synthesis processes lead to the formation of an intrinsic co-catalytic center and thus enable noble-metal free photocatalytic H2 generation. In this work, we report "grey TiO2" by an appropriate hydrogenation treatment exhibits excellent photocatalytic hydrogen. In this case, by the employment of thermally stable and high-surface-area TiO2 nanoparticles as well as mesoporous particles as the hydrogenation precursor, the appropriate extent of reduction of TiO2 (coloration) and the formation of Ti3+ is the key for the efficient noble-metal-free photocatalytic H2 generation. The EPR results reveal that "grey TiO2" shows stronger Ti3+ feature at g ca. 1.93 than "black TiO2" contributing to the intrinsic catalytic center for H2 evolution.

preprint2020arXiv

Danger-aware Adaptive Composition of DRL Agents for Self-navigation

Self-navigation, referred as the capability of automatically reaching the goal while avoiding collisions with obstacles, is a fundamental skill required for mobile robots. Recently, deep reinforcement learning (DRL) has shown great potential in the development of robot navigation algorithms. However, it is still difficult to train the robot to learn goal-reaching and obstacle-avoidance skills simultaneously. On the other hand, although many DRL-based obstacle-avoidance algorithms are proposed, few of them are reused for more complex navigation tasks. In this paper, a novel danger-aware adaptive composition (DAAC) framework is proposed to combine two individually DRL-trained agents, obstacle-avoidance and goal-reaching, to construct a navigation agent without any redesigning and retraining. The key to this adaptive composition approach is that the value function outputted by the obstacle-avoidance agent serves as an indicator for evaluating the risk level of the current situation, which in turn determines the contribution of these two agents for the next move. Simulation and real-world testing results show that the composed Navigation network can control the robot to accomplish difficult navigation tasks, e.g., reaching a series of successive goals in an unknown and complex environment safely and quickly.

preprint2020arXiv

Global small analytic solutions of MHD boundary layer equations

In this paper, we prove the global existence and the large time decay estimate of solutions to the two-dimensional MHD boundary layer equations with small initial data, which is analytical in the tangential variable. The main idea of the proof is motivated by that of \cite{PZ5}. The additional difficulties are: 1. there appears the magnetic field; 2. the far field here depends on the tangential variable; 3. the Reynolds number is different from magnetic Reynolds number. In particular, we solved an open question in \cite{XY19} concerning the large time existence of analytical solutions to the MHD boundary layer equations.

preprint2020arXiv

Interactive Human-Machine Learning Framework for Modelling of Ferroelectric-Dielectric Composites

Data driven materials discovery and optimization requires databases that are error free and experimentally verified. Performing material measurements are time-consuming and often restricted by the fact that material sample preparations are non-trivial, labour-intensive and expensive. Numerical modelling of materials has been studied over the years in order to address these issues and nowadays it has been developed at multi-scale and multi-physics levels. However, numerical models for nano-composites, especially for ferroelectrics are limited due to multiple unknowns including oxygen vacancy densities, grain sizes and domain boundaries existing in the system. In this work, we introduce a human-machine interactive learning framework by developing a scalable semi-empirical model to accurately predict material properties enabled by deep learning (DL). MgO-doped BST (BaxSr1-xTiO3) is selected as an example ferroelectric-dielectric composite for validation. The DL model transfer-learns the experimental features of materials from a measurement database which includes data for over 100 different ferroelectric composites collected by screening the published data and combining our own measurement data. The trained DL model is utilized in providing feedback to human researchers, who then refine computer model parameters accordingly, hence completing the interactive learning cycle. Finally, the developed DL model is applied to predict and optimise new ferroelectric-dielectric composites with the highest figure of merit (FOM) value.

preprint2020arXiv

Intrinsically Activated SrTiO3: Photocatalytic H2 Evolution from Neutral Aqueous Methanol Solution in the Absence of Any Noble Metal Cocatalyst

Noble metal cocatalysts are conventionally a crucial factor in oxide-semiconductor-based photocatalytic hydrogen generation. In the present work, we show that optimized high-temperature hydrogenation of commercially available strontium titanate (SrTiO3) powder can be used to engineer an intrinsic cocatalytic shell around nanoparticles that can create a photocatalyst that is highly effective without the use of any additional cocatalyst for hydrogen generation from neutral aqueous methanol solutions. This intrinsic activation effect can also be observed for SrTiO3[100] single crystal as well as Nb-doped SrTiO3 (100) single crystal. For all types of SrTiO3 samples (nanopowders and either of the single crystals), hydrogenation under optimum conditions leads to a surface-hydroxylated layer together with lattice defects visible by transmission electron microscopy, electron paramagnetic resonance (EPR), and photoluminescence (PL). Active samples provide states in a defective matrix -- this is in contrast to the inactive defects formed in other reductive atmospheres. In aqueous media, active SrTiO3 samples show a significant negative shift of the flatband potential (in photoelectrochemical as well as in capacitance data) and a lower charge-transfer resistance for photoexcited electrons. We therefore ascribe the remarkable cocatalyst-free activation of the material to a synergy between thermodynamics (altered interface energetics induced by hydroxylation) and kinetics (charge transfer mediation by suitable Ti3+ states).

preprint2020arXiv

Large diameter TiO$_2$ nanotubes enable integration of conformed hierarchical and blocking layers for enhanced dye-sensitized solar cell efficiency

In the present work we grow anodic TiO$_2$ nanotube layer with tube diameter ~ 500 nm and an open tube mouth. We use this morphology in dye-sensitized solar cells (DSSCs) and show that these tubes allow the construction of hybrid hierarchical photoanode structures of nanotubes with a defined and wall-conformance TiO2 nanoparticles decoration. At the same time, the large diameter allows the successful establishment of an additional (insulating) blocking layer of SiO$_2$ or Al$_2$O$_3$. We show that this combination of hierarchical structure and blocking layer significantly enhances the solar cell efficiency by suppressing recombination reactions. In such a DSSC structure, the solar cell efficiency under back side illumination with AM1.5 illumination is enhanced from 5% neat tube to 7 %.

preprint2020arXiv

Large spin gaps in half metals MN4 (M=Mn, Fe, Co) with N2 dimers

We predict that cubic MN4 (M=Mn, Fe, Co) are all half metals with the largest spin gap up to ~ 5 eV. They possess robust ferromagnetic ground states with the highest Curie temperature up to ~ 103 K. Our calculations indicate these compounds are energetically favored, dynamically and mechanically stable. It is proposed that self-doping of these 3d transition metals occurs in MN4 due to the reduction in electronegativity of N2 dimers. This model can well explain the calculated integer magnetic moments, large spin gaps of MN4 and semiconducting behavior for NiN4 as well. Our results highlight the difference in electronegativity between transition metal ions and non-metal entities in forming half metals and the role of N2 dimer in enlarging the spin gaps for nitride half metals.

preprint2020arXiv

Mono-b events from single stop production at the HL-LHC and HE-LHC

Top-squarks (stop) play an important role in SUSY naturalness. The stop pair production is considered as the most effective way to search for stop at the LHC. However, the collider signature of stop pair production is usually characterized by $t\bar{t}$ plus missing transverse energy, which is also predicted in many other non-supersymmetric models. On the other hand, the single stop production via the electroweak interaction can provide some distinctive signatures, and thus will help to confirm the existence of the stop. In this paper, we investigate the observability of the mono-$b$ events from the single stop production process $pp \to \tilde t_1 \tildeχ^-_1 \to b+ E\!\!\!\!/_T$ in a simplified MSSM framework where the higgsinos and stops are the only sparticles at the HL-LHC and HE-LHC. We find that the stop mass and the higgsino mass may be probed up to about 1.6 TeV and 550 GeV at $5σ$ level at the HE-LHC with the integrated luminosity ${\cal L} = 15~\text{ab}^{-1}$. We also present the $2σ$ exclusion limits of the stop mass at the HL-LHC and HE-LHC.

preprint2020arXiv

Noble metal free photocatalytic H$_2$ generation on black TiO$_2$: On the influence of crystal facets vs. crystal damage

In this study, we investigate noble metal free photocatalytic water splitting on natural anatase single crystal facets and on wafer slices of the [001] plane before and after these surfaces have been modified by high pressure hydrogenation (HPH) and hydrogen ion-implantation. We find that on the natural, intact low index planes photocatalytic H$_2$ evolution (in absence of noble metal co-catalyst) can only be achieved when the hydrogenation treatment is accompanied by the introduction of crystal damage, such as simple scratching, miscut in the wafer or by implantation damage. X-ray reflectivity (XRR), Raman, and optical reflection measurements show that plain hydrogenation leads to a ~ 1 nm thick black titania surface layer without activity, while a colorless, density modified and ~ 7 nm thick layer with broken crystal symmetry is present in the ion implanted surface. These results demonstrate that i) the H-treatment of an intact anatase surface needs to be combined with defect formation for catalytic activation, and ii) activation does not necessarily coincide with the presence of black color.

preprint2020arXiv

Noble-Metal-Free Photocatalytic Hydrogen Evolution Activity: The Impact of Ball Milling Anatase Nanopowders with TiH2

In this work, we demonstrate that a well-established and facile ball milling approach using mixtures of commercial anatase nanoparticles and TiH2 introduces noble-metal-free photocatalytic H2 activity to titania. We characterize this synergistic effect in view of the nature of defects, state of hydroxylation, and investigate the effect on the energetics and kinetics of electronic states and the resulting H2 evolution performance.

preprint2020arXiv

Optimized FTO seeding enables the growth of high efficient Ta-doped TiO$_2$ nanorod photoanodes

Tantalum doped rutile nanorods were hydrothermally grown on FTO substrates using a new seeding approach. This approach allows the incorporation of high concentrations of up to 4.8 at% tantalum as active doping and results in a significant enhancement of photoelectrochemical water splitting rate (1.8 mA/cm2 at a potential of +1.5 V vs RHE) which corresponds to ca. 1% photocurrent conversion efficiency under AM 1.5, 100 mW/cm2 simulated sunlight irradiation.

preprint2020arXiv

Photocatalysis with TiO2 Nanotubes: Colorful Reactivity and Designing Site-Specific Photocatalytic Centers into TiO2 Nanotubes

Photocatalytic reactions on TiO2 have recently gained an enormous resurgence because of various new strategies and findings that promise to drastically increase efficiency and specificity of such reactions by modifications of the titania scaffold and chemistry. In view of geometry, in particular, anodic TiO2 nanotubes have attracted wide interest, as they allow a high degree of control over the separation of photogenerated charge carriers not only in photocatalytic reactions but also in photoelectrochemical reactions. A key advantage of ordered nanotube arrays is that nanotube modifications can be embedded site specifically into the tube wall; that is, cocatalysts, doping species, or junctions can be placed at highly defined desired locations (or with a desired regular geometry or pattern) along the tube wall. This allows an unprecedented level of engineering of energetics of reaction sites for catalytic and photocatalytic reactions, which target not only higher efficiencies but also the selectivity of reactions. Many recent tube alterations are of a morphologic nature (mesoporous structures, designed faceted crystallites, hybrids, or 1D structures), but a number of color-coded (namely, black, blue, red, green, gray) modifications have attracted wide interest because of the extension of the light absorption spectrum of titania in the visible range and because unique catalytic activity can be induced. The present Perspective gives an overview of TiO2 nanotubes in photocatalysis with an emphasis on the most recent advances in the use of nanotube arrays and discusses the underlying concepts in tailoring their photocatalytic reactivity.

preprint2020arXiv

Probing a new decay of vector-like top partner mediated by heavy Majorana neutrino via single production

Models beyond the Standard Model have been proposed to simultaneously solve the problems of naturalness and neutrino mass, in which heavy Majorana neutrinos and vector-like top partners are usually predicted. A new decay channel of the top partner mediated by the heavy Majorana neutrino can thus appear: $T\to b\,W^{+}\to b\,\ell^{+}\ell^{+}q\bar{q'}$. We study in this paper the observability of this decay process through single production of the top partner at the 14 TeV LHC: $pp\to T/\bar{T}$+jets$\to b/\bar{b}+μ^{\pm}μ^{\pm}$+jets. $2σ$ exclusion bounds on the top partner mass and mixing parameters are given by Monte-Carlo simulation, which surpass those from the search through VLT pair production in the mass range of $m_{T}>1.3$ TeV.

preprint2020arXiv

Probing single stop production at the FCC-hh/SPPC

Top squark (stop) is a crucial part of supersymmetric models (SUSY) to understand the naturalness problem. Other than the traditional stop pair production, the single production via electroweak interaction provides signals with distinctive features which could help confirm the existence of the top squark. In this paper, we investigate the observability of stop through the mono-top channel of the single stop production at the future proton-proton colliders, FCC-hh and SPPC, in a simplified Minimal Supersymmetric Standard Model (MSSM). With the integrated luminosity of 3000 $\text{fb}^{-1}$, we can probe the stop with mass up to 3.25 TeV by the mono-top channel at $5σ$ level. Considering the systematic uncertainty of 10%, the exclusion limit for stop mass can be reached at about 1.5 TeV. Exclusion limits on stop mass and higgsino mass parameter $μ$ are also presented.

preprint2020arXiv

Top quark as a probe of heavy Majorana neutrino at the LHC and future collider

Right-handed (RH) Majorana neutrinos play a crucial role in understanding the origin of neutrino mass, the nature of dark matter and the mechanism of matter-antimatter asymmetry. In this work, we investigate the observability of heavy Majorana neutrino through the top quark neutrinoless double beta decay process $t \to b \ell^+ \ell^+ j j$ at hadron colliders. By performing detector level simulation, we demonstrate that our method can give stronger limits on the light-heavy neutrino mixing parameters $|V_{eN, μN}|$ in the mass range of 15 GeV $< m_N <$ 80 GeV than other existing collider bounds.

preprint2020arXiv

Transparent Classification with Multilayer Logical Perceptrons and Random Binarization

Models with transparent inner structure and high classification performance are required to reduce potential risk and provide trust for users in domains like health care, finance, security, etc. However, existing models are hard to simultaneously satisfy the above two properties. In this paper, we propose a new hierarchical rule-based model for classification tasks, named Concept Rule Sets (CRS), which has both a strong expressive ability and a transparent inner structure. To address the challenge of efficiently learning the non-differentiable CRS model, we propose a novel neural network architecture, Multilayer Logical Perceptron (MLLP), which is a continuous version of CRS. Using MLLP and the Random Binarization (RB) method we proposed, we can search the discrete solution of CRS in continuous space using gradient descent and ensure the discrete CRS acts almost the same as the corresponding continuous MLLP. Experiments on 12 public data sets show that CRS outperforms the state-of-the-art approaches and the complexity of the learned CRS is close to the simple decision tree. Source code is available at https://github.com/12wang3/mllp.

preprint2020arXiv

Universal Physical Camouflage Attacks on Object Detectors

In this paper, we study physical adversarial attacks on object detectors in the wild. Previous works mostly craft instance-dependent perturbations only for rigid or planar objects. To this end, we propose to learn an adversarial pattern to effectively attack all instances belonging to the same object category, referred to as Universal Physical Camouflage Attack (UPC). Concretely, UPC crafts camouflage by jointly fooling the region proposal network, as well as misleading the classifier and the regressor to output errors. In order to make UPC effective for non-rigid or non-planar objects, we introduce a set of transformations for mimicking deformable properties. We additionally impose optimization constraint to make generated patterns look natural to human observers. To fairly evaluate the effectiveness of different physical-world attacks, we present the first standardized virtual database, AttackScenes, which simulates the real 3D world in a controllable and reproducible environment. Extensive experiments suggest the superiority of our proposed UPC compared with existing physical adversarial attackers not only in virtual environments (AttackScenes), but also in real-world physical environments. Code and dataset are available at https://mesunhlf.github.io/index_physical.html.