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Matteo Rinaldi

Matteo Rinaldi contributes to research discovery and scholarly infrastructure.

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Published work

18 published item(s)

preprint2026arXiv

Beyond Continuity: Challenges of Context Switching in Multi-Turn Dialogue with LLMs

Users interacting with Large Language Models (LLMs) in a multi-turn conversation routinely refine their requests or pivot to new topics. LLMs, however, often miss these topic shifts and carry over irrelevant context from previous turns, leading to inaccurate responses. In this paper, we stress-test the multi-turn understanding of LLMs and study the following two sub-tasks: (1) detecting whether the user pivots or refines in the current turn, and (2) shortlisting relevant context from previous turns. To this end, we construct synthetic benchmarks based on real-world datasets from varied domains, as to simulate context shifts of different levels of difficulty. We then evaluate the zero-shot performance of ten LLMs (open-weight, closed-source and reasoning), and demonstrate that only some reasoning and strongly instructed LLMs are accurate in detecting pivots; open-weight LLMs struggle with the task and frequently carry stale context even with explicit cues; and all models suffer from a position bias. Based on the results, we discuss key takeaways for improving long-term robustness in multi-turn capabilities for LLMs.

preprint2026arXiv

DMRG/FQ: a Polarizable Embedding Approach Combining Density Matrix Renormalization Group and Fluctuating Charges

We present an integrated multiscale framework that combines the Density Matrix Renormalization Group (DMRG) with a polarizable fluctuating-charge (FQ) force field for the simulation of electronic excited states in solution. The method exploits the capabilities of DMRG to accurately describe systems with strong static correlation, while the FQ model provides a self-consistent and physically grounded representation of solvent polarization within a QM/MM embedding. The DMRG/FQ approach is applied to representative solvated systems, using extensive molecular dynamics sampling. The method yields reliable excitation energies, solvatochromic shifts, and a close agreement with available experimental data. The results highlight the importance of mutual polarization for capturing specific solute-solvent interactions, particularly in systems where hydrogen bonding or directional interactions play a dominant role.

preprint2026arXiv

Long Range Outlook for Short-Range Correlations

Short range correlated (SRC) N N pairs are pairs of nucleons with high relative momentum (prel > kF where kF ~ 250 MeV/c is the Fermi momentum in medium to heavy nuclei) and lower center of mass momentum. The motivation for studying SRC pairs ranges from a desire to achieve a more comprehensive understanding of the many-body nuclear wave-function at high-resolution to searching for explicit QCD-dynamics effects within the nuclear medium, not to mention connections to many other open problems in nuclear physics. Exploring short-range correlations was one of the physics motivations for building CEBAF (now Jefferson Lab). Scientists used the high luminosity and high energy of this cutting-edge machine to find kinematics that cleanly showed the signals of short-range correlations. This paved the way in the last two decades for tremendous progress understanding these correlations. This paper reviews recent progress and highlights outstanding questions and areas that need further study.

preprint2022arXiv

Enlighting the transverse structure of the proton via double parton scattering in photon-induced interactions

In the present paper we address double parton scattering (DPS) in quasi-real photon-proton interactions. By using electromagnetic and hadronic models of the photon light cone wave functions, we compute the so-called effective cross-section, $σ_{eff}^{γp}$ which allows us to calculate the DPS contribution to these processes under dedicated assumptions. In particular, for the four-jet photoproduction in HERA kinematics we found a sizeable DPS contribution. We show that if the photon virtuality $Q^2$ could be measured and thus the dependence of $σ_{eff}^{γp}$ on such a parameter exposed, information on the transverse distance between partons active in proton could be extracted. To this aim, we set lower limits on the integrated luminosity needed to observe such an effect which would allow the extraction of novel information on the proton structure.

preprint2022arXiv

European Aerosol Phenomenology -- 8: Harmonised Source Apportionment of Organic Aerosol using 22 Year-long ACSM/AMS Datasets

Organic aerosol (OA) is a key component to total submicron particulate matter (PM1), and comprehensive knowledge of OA sources across Europe is crucial to mitigate PM1 levels. Europe has a well-established air quality research infrastructure from which yearlong datasets using 21 aerosol chemical speciation monitors (ACSMs) and 1 aerosol mass spectrometer (AMS) were gathered during 2013-2019. It includes 9 non-urban and 13 urban sites. This study developed a state-of-the-art source apportionment protocol to analyse long-term OA mass spectrum data by applying the most advanced source apportionment strategies (i.e., rolling PMF, ME-2, and bootstrap). This harmonised protocol enables the quantifications of the most common OA components such as hydrocarbon-like OA (HOA), biomass burning OA (BBOA), cooking-like OA (COA), more oxidised-oxygenated OA (MO-OOA), and less oxidised-oxygenated OA (LO-OOA). Other components such as coal combustion OA (CCOA), solid fuel OA (SFOA: mainly mixture of coal and peat combustion), cigarette smoke OA (CSOA), sea salt (mostly inorganic but part of the OA mass spectrum), coffee OA, and ship industry OA could also be separated at a few specific sites. Oxygenated OA (OOA) components make up most of the submicron OA mass (average = 71.1%, a range of 43.7-100%). Solid fuel combustion-related OA components (i.e., BBOA, CCOA, and SFOA) are still considerable with in total 16.0% yearly contribution to the OA, yet mainly during winter months (21.4%). Overall, this comprehensive protocol works effectively across all sites governed by different sources and generates robust and consistent source apportionment results. Our work presents a comprehensive overview of OA sources in Europe with a unique combination of high time resolution and long-term data coverage (9-36 months), providing essential information to improve/validate air quality, health impact, and climate models.

preprint2022arXiv

Glueballs at high temperature within the Hard-Wall holographic model

In this investigation an holographic description of the deconfined phase transition of scalar and tensor glueballs is presented within the so called hard-wall model. The spectra of these bound states of gluons have been calculated from the linearized Einstein equations for a graviton propagating from a thermal $AdS_5$ space to an AdS Black-Hole. In this framework, the deconfined phase is reached via a two steps mechanism. We propose that the transition between the AdS thermal sector to the BH is described via a first order phase transition, with discontinuous masses at the critical temperature, which has been determined by Herzog's method of regulating the free energy densities. Then, the glueball masses diverge with increasing $T$ in the BH phase and thus lead to deconfined states à la Hagedorn.

preprint2022arXiv

Meson and Glueball spectroscopy within the Graviton Soft-Wall model

In this contribution we present results of the calculations of several hadronic spectra within the holographic graviton soft-wall (GSW) model. In particular, we studied and compared with data for the ground state and excitations of: glueballs, scalar, vector, axial and pseudo-scalar mesons. The GSW model is found to be capable to describe these observable with only few parameters.

preprint2021arXiv

Performant implementation of the atomic cluster expansion (PACE): Application to copper and silicon

The atomic cluster expansion is a general polynomial expansion of the atomic energy in multi-atom basis functions. Here we implement the atomic cluster expansion in the performant C++ code \verb+PACE+ that is suitable for use in large scale atomistic simulations. We briefly review the atomic cluster expansion and give detailed expressions for energies and forces as well as efficient algorithms for their evaluation. We demonstrate that the atomic cluster expansion as implemented in \verb+PACE+ shifts a previously established Pareto front for machine learning interatomic potentials towards faster and more accurate calculations. Moreover, general purpose parameterizations are presented for copper and silicon and evaluated in detail. We show that the new Cu and Si potentials significantly improve on the best available potentials for highly accurate large-scale atomistic simulations.

preprint2020arXiv

A proton imagining via double parton scattering

In this contribution we discuss the main outcomes of our studies on the so called double parton distribution functions (dPDFs), accessible quantities in high energy proton-proton and proton nucleus collisions, in double parton scattering processes (DPS). These new distributions are almost unknown, nevertheless they encode information on how partons inside a proton are correlated among each other. Double PDFs represent a new tool to explore the three dimensional partonic structure of hadrons. Here, we show results obtained from calculations of dPFDs. In particular we focus our attention on the impact of double correlations in experimental observables by showing how the latter could be studied in the next LHC run. We also discuss how the present knowledge on a peculiar experimental observable could unveil new information on the transverse proton structure

preprint2020arXiv

Double parton correlations in mesons within AdS/QCD soft-wall models: a first comparison with lattice data

Double parton distribution functions (dPDFs), entering the double parton scattering (DPS) cross section, are unknown fundamental quantities encoding new interesting properties of hadrons. Here, the pion dPDFs are investigated within different holographic QCD quark models in order to access their basic features. Results of the calculation,s obtained within the AdS/QCD soft-wall approach, have been compared with predictions of lattice QCD evaluations of the pion two-current correlation functions. The present analysis confirms that double parton correlations, affecting dPDFs, are very important and not direct accessible from generalised parton distribution functions and electromagnetic form factors. The comparison between lattice data and quark model calculations unveils the relevance of the contributions of high partonic Fock states in the pion. Nevertheless, by using a complete general procedure, results of lattice QCD have been used, for the first time, to estimate the mean value of the so called $σ_{eff}$, a relevant experimental observable for DPS processes. In addition, the results of the first calculations of the $ρ$ meson dPDFs are discussed in order to make predictions.

preprint2020arXiv

EMC effect, few-nucleon systems and Poincaré covariance

An approach for a Poincaré covariant description of nuclear structure and of lepton scattering off nuclei is proposed within the relativistic Hamiltonian dynamics in the light-front form. Indeed a high level of accuracy is needed for a comparison with the increasingly precise present and future experimental data at high momentum transfer. Therefore, to distinguish genuine QCD effects or effects of medium modified nucleon structure functions from conventional nuclear structure effects, the commutation rules between the Poincaré generators should be satisfied. For the first time in this paper a proper hadronic tensor for inclusive deep inelastic scattering of electrons off nuclei is derived in the impulse approximation in terms of the single nucleon hadronic tensor. Our approach is based : i) on a light-front spectral function for nuclei, obtained taking advantage of the successful non-relativistic knowledge of nuclear interaction, and ii) on the free current operator that, if defined in the Breit reference frame with the momentum transfer, $\bf q$, parallel to the $z$ axis, fulfills Poincaré covariance and current conservation. Our results can be generalized : i) to exclusive processes or to semi-inclusive deep inelastic scattering processes; ii) to the case where the final state interaction is considered through a Glauber approximation; iii) to finite momentum transfer kinematics. As a first test, the hadronic tensor is applied to obtain the nuclear structure function F$_2^A$ and to evaluate the EMC effect for $^3He$ in the Bjorken limit. Encouraging results including only the two-body part of the light-front spectral function are presented.

preprint2020arXiv

Generalized parton distributions of light nuclei

The measurement of nuclear generalized parton distributions (GPDs) in hard exclusive processes, such as deeply virtual Compton Scattering (DVCS), will be one of the main achievements of a new generation of experiments at high luminosity, such as those under way at the Jefferson Laboratory (JLab) with the 12 GeV electron beam and, above all, those planned at the future Electron Ion Collider. The CLAS collaboration at JLab has recently demonstrated the possibility to disentangle the two different channels of nuclear DVCS, the coherent and incoherent ones, a first step towards the measurement of GPDs of nuclei and of bound nucleons, respectively, opening new exciting perspectives in the field. In this scenario, theoretical precise calculations, ultimately realistic, become mandatory. Light nuclei, for which realistic studies are affordable and conventional nuclear effects can be safely estimated, so that possible exotic effects can be exposed, play an important role. The status of the calculation of GPDs for light nuclei will be summarized, in particular for $^3$He and $^4$He, and some updates will be presented. The prospects for the next years, related to the new series of measurements at future facilities, will be addressed.

preprint2020arXiv

Pure glueball states in a Light-Front holographic approach

A phenomenological analysis of the scalar glueball and scalar meson spectra is carried out by using the AdS/QCD framework in the bottom-up approach. The resulting spectra are in good agreement for glueballs with lattice QCD results and for mesons with PDG data. We make use of the relation between the mode functions in AdS/QCD and the wave functions in Light-Front $QCD$ to discuss the mixing of glueballs and mesons. The results of our investigation point out that above 2 GeV scalar particles will appear in almost degenerate pairs of unmixed glueball and mesons states leading to an interesting phenomenology whereby gluon dynamics could be well investigated.

preprint2020arXiv

Systematic Synthesis and Design of Ultra-Low Threshold Parametric Frequency Dividers

A new method is discussed for the systematic synthesis, design and performance optimization of varactor-based parametric frequency dividers (PFDs) exhibiting an ultra-low power threshold ($P_{th}$). For the first time, it is analytically shown that the $P_{th}$-value exhibited by any PFD can always be expressed as an explicit closed-form function of the different impedances forming its network. Such a unique and unexplored property permits to rely on linear models, during the PFD design and performance optimization. The validity of our analytical model has been verified, in a commercial circuit simulator, through time-domain and frequency-domain algorithms. To demonstrate the effectiveness of our new synthesis approach, we also report on a lumped prototype of a 200:100MHz PFD, realized on a printed circuit board (PCB). Although inductors with quality factors lower than 50 were used, the PFD prototype exhibits a $P_{th}$-value lower than $-$15dBm. Such a low $P_{th}$-value is the lowest one ever reported for passive varactor-based PFDs, operating in the same frequency range.

preprint2019arXiv

Radio Frequency Magnet-free Circulators Based on Spatiotemporal Modulation of Surface Acoustic Wave Filters

In this paper, a new generation of magnet-free circulators with high performance is proposed. Circulators are crucial devices in modern communication systems due to their ability to enable full-duplexing and double the spectral efficiency directly in the physical layer of the radio-frequency (RF) front-end. Traditionally, Lorentz reciprocity is broken by applying magnetic bias to ferrite materials, therefore conventional circulators are bulky and expensive. In this paper, this problem is addressed by replacing the magnetic bias with periodic spatiotemporal modulation. Compared to previous works, the proposed circulator is constructed using surface acoustic wave (SAW) filters instead of transmission lines (TL), which reduces the modulation frequency by at least a factor of 20 and ensures ultra-low power consumption and high linearity. The miniaturized high quality (Q) factor SAW filters also lead to a low-loss non-reciprocal band with strong isolation (IX) and broad bandwidth (BW) on a chip scale, therefore addressing such limitations in previous magnet-free demonstrations. Furthermore, compared to the conventional differential circuit configuration, a novel quad configuration is developed, which doubles the intermodulation-free bandwidth.

preprint2019arXiv

The proton structure via double parton scattering

In this talk we present the results of the investigation on the so called double parton distribution functions (dPDFs), accessible quantities in high energy proton-proton and proton nucleus collisions, in double parton scattering processes (DPS). These new and almost unknown distributions encode information on how partons inside a proton are correlated among each other and represent a new tool to explore the three dimensional partonic structure of hadrons. In the present contribution, results of the calculations of dPFDs are presented also including phenomenological investigations on the impact of double correlations in experimental observables, showing how the latter could be observed in the next LHC run. In addition we discuss how present information on experimental observables could be related to the transverse proton structure.

preprint2013arXiv

Studying the neutron orbital structure by coherent hard exclusive processes off 3He

Hard exclusive processes, such as Deeply Virtual Compton Scattering (DVCS), allow to access generalized parton distributions (GPDs). By means of an Impulse Approximation (IA) calculation, it is shown here how, in the low momentum transfer region, the sum of the GPDs H and E is dominated by the neutron contribution. Thanks to this property, 3He could open a new way to access the neutron structure information. In this work, a simple and efficient extraction procedure of the neutron GPDs, able to take into account the nuclear effects included in IA analysis, is proposed.