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Jiguang Li

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Published work

20 published item(s)

preprint2026arXiv

Dynamic Treatment on Networks

In networks, effective dynamic treatment allocation requires deciding both whom to treat and also when, so as to amplify policy impact through spillovers. An early intervention at a well-connected node can trigger cascades that change which nodes are worth targeting in the next period. Existing treatment strategies under network interference are largely static while dynamic treatment frameworks typically ignore network structure altogether. We integrate these perspectives and propose Q-Ising, a three-stage pipeline that (i) estimates network adoption dynamics via a Bayesian dynamic Ising model from a single observed panel, (ii) augments treatment adoption histories with continuous posterior latent states, and (iii) learns a dynamic policy via offline reinforcement learning. The Bayesian mechanism enables uncertainty quantification over dynamic decisions, yielding posterior ensemble policies with interpretable spillover estimates. We provide a finite-sample regret upper bound that decomposes into standard offline-RL uncertainty, network abstraction error, and first stage error in Ising state estimation. We apply our method to data from Indian village microfinance networks and synthetic stochastic block models under simulated heterogeneous susceptible-infected-susceptible (SIS) dynamics and demonstrate that adaptive targeting outperforms static centrality benchmarks.

preprint2026arXiv

Robust Bayesian Optimization via Tempered Posteriors

Bayesian optimization (BO) iteratively fits a Gaussian process (GP) surrogate to accumulated evaluations and selects new queries via an acquisition function such as expected improvement (EI). In practice, BO often concentrates evaluations near the current incumbent, causing the surrogate to become overconfident and to understate predictive uncertainty in the region guiding subsequent decisions. We develop a robust GP-based BO via tempered posterior updates, which downweight the likelihood by a power $α\in (0,1]$ to mitigate overconfidence under local misspecification. We establish cumulative regret bounds for tempered BO under a family of generalized improvement rules, including EI, and show that tempering yields strictly sharper worst-case regret guarantees than the standard posterior $(α=1)$, with the most favorable guarantees occurring near the classical EI choice. Motivated by our theoretic findings, we propose a prequential procedure for selecting $α$ online: it decreases $α$ when realized prediction errors exceed model-implied uncertainty and returns $α$ toward one as calibration improves. Empirical results demonstrate that tempering provides a practical yet theoretically grounded tool for stabilizing BO surrogates under localized sampling.

preprint2024arXiv

Feasibility of extracting the proton weak charge from quantum-control measurements of atomic parity violation on the $2s-3s$ or $2s-4s$ transition in hydrogen

We explore the feasibility of extracting electroweak observables from a measurement of atomic parity violation in hydrogen. Our proposed quantum-control scheme focuses on the $2s-3s$ or $2s-4s$ transitions in hydrogen. This work is motivated by the recently observed anomaly in the W-boson mass, which may substantially modify the Standard Model value of the proton weak charge. We also study the accuracy of the previously employed approximations in computing parity-violating effects in hydrogen.

preprint2022arXiv

Theoretical Calculation of the Quadratic Zeeman Shift Coefficient of the 3P0 clock state for Strontium Optical Lattice Clock

The quadratic Zeeman shift coefficient of 3P0 clock state for strontium is determined in theory and experiment. In theory, we derived the expression of the quadratic Zeeman shift of 3P0 clock state for 88Sr and 87Sr in the weak-magnetic-field approximation. By using the multi-configuration Dirac-Hartree-Fock theory, the quadratic Zeeman shift coefficients were calculated. To determine the calculated results, the quadratic Zeeman shift coefficient of 3P0,F=9/2,MF=+/-9/2 clock state was measured in our 87Sr optical lattice clock. The calculated results C2=-23.38(5) MHz/T2 for 88Sr and the 3P0,F=9/2,MF=+/-9/2 clock state for 87Sr agree well with the other experimental and theoretical values, especially the most accurate measurement recently. As the 1S0,F=9/2,MF=+/-5/2-3P0,F=9/2,MF=+/-3/2 transitions have been used as another clock transition for less sensitive to the magnetic field noise, we also calculated the quadratic Zeeman shift coefficients for the other magnetic states.

preprint2020arXiv

Hyperfine structure of $^{173}\mathrm{Yb}^+$: toward resolving the $^{173}\mathrm{Yb}$ nuclear octupole moment puzzle

Hyperfine structure (HFS) of atomic energy levels arises due to interactions of atomic electrons with a hierarchy of nuclear multipole moments, including magnetic dipole, electric quadrupole and higher rank moments. Recently, a determination of the magnetic octupole moment of the $^{173}\mathrm{Yb}$ nucleus was reported from HFS measurements in neutral ${}^{173}\mathrm{Yb}$ [PRA 87, 012512 (2013)], and is four orders of magnitude larger than the nuclear theory prediction. Considering this substantial discrepancy between the spectroscopically extracted value and nuclear theory, here we propose to use an alternative system to resolve this tension, a singly charged ion of the same $^{173}\mathrm{Yb}$ isotope. Utilizing the substantial suite of tools developed around $\mathrm{Yb}^+$ for quantum information applications, we propose to extract nuclear octupole and hexadecapole moments from measuring hyperfine splittings in the extremely long lived first excited state ($4f^{13}(^2\!F^{o})6s^2$, $J=7/2$) of $^{173}\mathrm{Yb}^+$. We present results of atomic structure calculations in support of the proposed measurements.

preprint2020arXiv

Theoretical study of electronic structure of erbium and fermium

We use a recently developed version of the configuration method for open shells to study electronic structure of erbium and fermium atoms. We calculate excitation energies of odd states connected to the even ground state by electric dipole transitions, the corresponding transition rates, isotope shift, hyperfine structure, ionization potentials and static scalar polarizabilities. We argue that measuring isotope shift for several transitions can be used to study nuclear deformation in even-even nuclei. This is important for testing nuclear theory and for searching for the hypothetical island of stability. Since erbium and fermium have similar electronic structures, calculations for erbium serve as a guide to the accuracy of the calculations.

preprint2020arXiv

Theoretical study of the spectroscopic properties of mendelevium ($Z=101$)

Using recently developed version of the configuration interaction method for atoms with open shells we calculate electron structure and spectroscopic properties of the mendelevium atom (Md, $Z=101$). These include energy levels, first and second ionisation potentials, electron affinity, hyperfine structure and electric dipole transition amplitudes between ground and low lying states of opposite parity. The accuracy of the calculations is controlled by performing similar calculations for lighter analog of mendelevium, thulium atom and comparing the results with experiment and other calculations. The calculations for Md are to address the lack of experimental data and help in planing and interpreting the measurements.

preprint2020arXiv

Time keeping and searching for new physics using metastable states of Cu, Ag and Au

We study the prospects of using the electric quadrupole transitions from the ground states of Cu, Ag and Au to the metastable state $^2{\rm D}_{5/2}$ as clock transitions in optical lattice clocks. We calculate lifetimes, transition rates, systematic shifts, and demonstrate that the fractional uncertainty of the clocks can be similar to what is achieved in the best current optical clocks. The use of these proposed clocks for the search of new physics, such as time variation of the fine structure constant, search for low-mass scalar dark matter, violation of Local Position Invariance and violation of Lorenz Invariance is discussed.

preprint2016arXiv

Atomic Parameters for the $2p^53p~^2[3/2]_2 - 2p^53s~^2[3/2]^o_2$ Transition of Ne I relevant in nuclear physics

We calculated the magnetic dipole hyperfine interaction constants and the electric field gradients of $2p^53p~^2[3/2]_2$ and $2p^53s~^2[3/2]^o_2$ levels of Ne I by using the multiconfiguration Dirac-Hartree-Fock method. The electronic factors contributing to the isotope shifts were also estimated for the $λ= 614.5$ nm transition connecting these two states. Electron correlation and relativistic effects including the Breit interaction were investigated in details. Combining with recent measurements, we extracted the nuclear quadrupole moment values for $^{20}$Ne and $^{23}$Ne with a smaller uncertainty than the current available data. Isotope shifts in the $2p^53p~^2[3/2]_2 - 2p^53s~^2[3/2]^o_2$ transition based on the present calculated field- and mass-shift parameters are in good agreement with the experimental values. However, the field shifts in this transition are two or three orders of magnitude smaller than the mass shifts, making rather difficult to deduce changes in nuclear charge mean square radii. According to our theoretical predictions, we suggest to use instead transitions connecting levels arising from the $2p^53s$ configuration to the ground state, for which the normal mass shift and specific mass shift contributions counteract each other, producing relatively small mass shifts that are only one order of magnitude larger than relatively large field shifts, especially for the $2p^53s~^2[1/2]^o_1 - 2p^6~^1S_0$ transition.

preprint2015arXiv

EUV and Visible Spectroscopy of Promethiumlike Heavy Ions

We present extreme ultraviolet and visible spectra of promethiumlike tungsten and gold obtained with an electron beam ion trap (EBIT). Although the contributions from a few charge states are involved in the spectra, the charge state of the ion assigned to the observed lines is definitely identified by the time-of-flight analysis of the ions performed at the same time with the spectroscopic measurements. Experimental results are compared with collisional-radiative model calculations as well as previous experimental and theoretical studies.

preprint2015arXiv

Multi-configuration Dirac-Hartree-Fock calculations of excitation energies, oscillator strengths and hyperfine structure constants for low-lying levels of Sm I

The multi-configuration Dirac-Hartree-Fock method was employed to calculate the total and excitation energies, oscillator strengths and hyperfine structure constants for low-lying levels of Sm I. In the first-order perturbation approximation, we systematically analyzed correlation effects from each electrons and electron pairs. It was found that the core correlations are of importance for physical quantities concerned. Based on the analysis, the important configuration state wave functions were selected to constitute atomic state wave functions. By using this computational model, our excitation energies, oscillator strengths, and hyperfine structure constants are in better agreement with experimental values than earlier theoretical works.

preprint2015arXiv

Theoretical isotope shifts in neutral barium

The present work deals with a set of problems in isotope shifts of neutral barium spectral lines. Some well known transitions ($6s^2~^1S_0-6s6p~^{1,3}P^o_1$ and $6s^2~^1S_0-6p^2~^3P_0$) are first investigated. Values of the changes in the nuclear mean-square charge radius are deduced from the available experimental isotope shifts using our ab initio electronic factors. The three sets $\{ δ\langle r^2\rangle^{A,A'}\} $ obtained from these lines are consistent with each other. The combination of the available nuclear mean-square radii with our electronic factors for the $6s5d~^3D_{1,2} -6s6p~^{1}P^o_1$ transitions produces isotope shift values in conflict with the laser spectroscopy measurements of Dammalapati et al. (Eur. Phys. J. D 53, 1 (2009)).

preprint2014arXiv

Magnetic-field-dependent angular distributions and linear polarizations of emissions from the $2p^53s~^3P_2$ state in Ne-like ions

We studied the effect of an external magnetic field on the angular distributions and the linear polarizations of emissions from the $2s^22p^53s~^3P^o_2$ state in Ne-like ions. Since a B-dependent E1 decay channel is opened by the magnetic field and competes with the inherent M2 transition, the angular distributions and the linear polarizations strongly depend on the magnetic field strength (B). As an example, we illustrated the effect in Ne-like Mg. The B-dependent angular distributions and linear polarization degrees can also be considered as a tool for diagnostics of the magnetic field in plasmas.

preprint2013arXiv

Relativistic effects on the hyperfine structures of 2p4(3P)3p 2Do, 4Do and 4Po in 19F I

The hyperfine interaction constants of the 2p4(3P)3p 2Do_{3/2,5/2}, 4Do_{1/2-7/2} and 4Po_{1/2-5/2} levels in neutral fluorine are investigated theoretically. Large-scale calculations are carried out using the multiconfiguration Hartree-Fock (MCHF) and Dirac-Hartree-Fock (MCDHF) methods. In the framework of the MCHF approach, the relativistic effects are taken into account in the Breit-Pauli approximation using non relativistic orbitals. In the fully relativistic approach, the orbitals are optimized using the Dirac-Coulomb Hamiltonian with correlation models inspired by the non relativistic calculations. Higher-order excitations are captured through multireference configuration interaction calculations including the Breit interaction. In a third (intermediate) approach, the Dirac-Coulomb-Breit Hamiltonian matrix is diagonalized in a relativistic configuration space built with non relativistic MCHF radial functions converted into Dirac spinors using the Pauli approximation. The magnetic dipole hyperfine structure constants calculated with the three relativistic models are consistent and reveal unexpectedly large effects of relativity for 2Do_{5/2}, 4Po_{3/2} and 4Po_{5/2}. The agreement with the few available experimental values is satisfactory. The strong J-dependence of relativistic corrections on the hyperfine constants is investigated through the detailed analysis of the orbital, spin-dipole and contact relative contributions calculated with the non relativistic magnetic dipole operator.

preprint2013arXiv

The effect of an external magnetic field on the determination of E1M1 two-photon decay rates in Be-like ions

In this work we report on ab initio theoretical results for the magnetic field induced 2s2p ^3P_0 - 2s^2 ^1S_0 E1 transition for ions in the beryllium isoelectronic sequence between Z=5 and 92. It has been proposed that the rate of the E1M1 two-photon transition 2s2p ^3P_0 - 2s^2 ^1S_0 can be extracted from the lifetime of the ^3P_0 state in Be-like ions with zero nuclear spin by employing resonant recombination in a storage-ring. This experimental approach involves a perturbing external magnetic field. The effect of this field needs to be evaluated in order to properly extract the two-photon rate from the measured decay curves. The magnetic field induced transition rates are carefully evaluated and it is shown that, with a typical storage-ring field strength, it is dominant or of the same order as the E1M1 rate for low- and mid-Z ions. Results for several field strengths and ions are presented and we also give a simple Z-dependent formula for the rate. We estimate the uncertainties of our model to be within 5% for low- and mid-Z ions, and slightly larger for more highly charged ions. Furthermore we evaluate the importance of including both perturber states, ^3P_1 and ^1P_1, and it is shown that excluding the influence of the ^1P_1 perturber overestimates the rate by up to 26% for the mid-Z ions.

preprint2013arXiv

Theoretical investigations on magnetic field induced $2p^53s^3P_{0,2} - 2p^6^1S_0$ transitions in Ne-like ions without nuclear spin

We report theoretical results for magnetic field induced $2p^53s^3P_{0,2} - 2p^6^1S_0$ E1 transitions in Ne-like ions with zero nuclear spin (I=0) between Mg III and Zn XXI as well as in Ne I. We demonstrate that it is important to include both ``perturber'' states $2p^53s^1P_1$ and $2p^53s^3P_1$ in order to produce reliable transition rates. Furthermore, we investigate the trends of the rates along the isoelectronic sequence of the $2p^53s^3P_{0,2} - 2p^6^1S_0$ transitions and their competition with the $2p^53s^3P_0 - 2p^53s^3P_1$ M1 and the $2p^53s^3P_2 - 2p^6^1S_0$ M2 decays. For the $2p^53s^3P_0$ state the magnetic field induced transition becomes the dominant decay channel for the light elements even in a relatively weak magnetic field, and it will therefore prove useful in diagnostics of the strength of magnetic fields in different plasmas. The influence of an external magnetic field on the lifetime of the $2p^53s^3P_2$ state is much smaller but still observable for the ions near the neutral end of the sequence. As a special case, the magnetic field effect on the lifetimes of $2p^53s^3P_{0,2}$ states of neutral $^{20}$Ne is discussed. It is found that the lifetimes are drastically reduced by a magnetic field, which may be an underlying reason for the discrepancies in the lifetime of the $2p^53s^3P_2$ state between experiment (14.73(14) s) and theory (17.63 s).

preprint2012arXiv

Effects of the electron correlation and Breit and hyperfine interactions on the lifetime of the 2p$^5$3s states in neutral neon

In the framework of the multiconfiguration Dirac-Hartree-Fock method, we investigate the transition properties of four excited states in the $2p^53s$ configuration of neutral neon. The electron correlation effects are taken into account systematically by using the active space approach. The effect of higher-order correlation on fine structures is shown. We also study the influence of the Breit interaction and find that it reduces the oscillator strength of the $^3P^o_1 - ^1S_0$ transition by 17%. It turns out that the inclusion of the Breit interaction is essential even for such a light atomic system. Our ab initio calculated line strengths, oscillator strengths and transition rates are compared with other theoretical values and experimental measurements. Good agreement is found except for the $^3P^o_2 - ^1S_0$ M2 transition for which discrepancies of around 15% between theories and experiments remain. In addition, the impact of hyperfine interactions on the lifetimes of the $^3P^o_0$ and $^3P^o_2$ metastable states is investigated for the $^{21}$Ne isotope (I=3/2). We find that hyperfine interactions reduce the lifetimes drastically. For the $^3P^o_0$ state the lifetime is decreased by a factor of 630.

preprint2012arXiv

Mass- and field-shift isotope parameters for the $2s - 2p$ resonance doublet of lithium-like ions

It was recently shown that dielectronic recombination measurements can be used for accurately inferring changes in the nuclear mean-square charge radii of highly-charged lithium-like neodymium [Brandau et al., Phys. Rev. Lett. 100 073201 (2008)]. To make use of this method to derive information about the nuclear charge distribution for other elements and isotopes, accurate electronic isotope shift parameters are required. In this work, we calculate and discuss the relativistic mass- and field-shift factors for the two $2s ^{2}S_{1/2} - 2p ^{2}P^{o}_{1/2,3/2}$ transitions along the lithium isoelectronic sequence. Based on the multiconfiguration Dirac-Hartree-Fock method, the electron correlation and the Breit interaction are taken into account systematically. The analysis of the isotope shifts for these two transitions along the isoelectronic sequence demonstrates the importance and competition between the mass shifts and the field shifts.

preprint2010arXiv

$M_F$-dependent Hyperfine Induced Transition Rates in an External Magnetic Field for Be-like $^{47}$Ti$^{18+}$

Hyperfine induced $2s2p~^3P_0 \rightarrow 2s^2~^1S_0$ transition rates in an external magnetic field for Be-like $^{47}$Ti were calculated based on the multiconfiguration Dirac-Fock method. It was found that the transition probability is dependent on the magnetic quantum number $M_F$ of the excited state, even in the weak field. The present investigation clarified that the difference of the hyperfine induced transition rate of Be-like Ti ions between experiment [Schippers {\sl et al.}, Phys Rev Lett {\bf 98}, (2007) 033001(4)] and theory does not result from the influence of external magnetic field.

preprint2009arXiv

Interference effects in hyperfine induced $2s2s ^3P_0, ^3P_2 \to 2s^2 ^1S_0$ transitions of Be-like ions

The hyperfine induced $2s2p ^3P_0, ^3P_2 \to 2s^2 ^1S_0$ E1 transition probabilities of Be-like ions were calculated using grasp2K based on multi-configuration Dirac-Fock method and HFST packages. It was found that the hyperfine quenching rates are strongly affected by the interference for low-Z Be-like ions, especially for $2s2p ^3P_0 \to 2s^2 ^1S_0$ transition. In particular, the trends of interference effects with atomic number $Z$ in such two transitions are not monotone. The strongest interference effect occurs near Z=7 for $2s2p ^3P_0 \to 2s^2 ^1S_0$ E1 transition, and near Z=9 for $2s2p ^3P_2 \to 2s^2 ^1S_0$ E1 transition.