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Voltammetry at porous electrodes: A theoretical study

Theory is presented to simulate both chronoamperometry and cyclic voltammetry at porous electrodes fabricated by means of electro-deposition around spherical templates. A theoretical method to extract heterogeneous rate constants for quasireversible and irreversible systems is proposed by the approximation of decoupling of the diffusion within the porous electrode and of bulk diffusion to the electrode surface.

preprint2014arXivOpen access
Edward O. BarnesXiaojun ChenaPeilin LiRichard G. Compton
physics.chem-ph
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Open access4 authors1 topic
Imported metadata coverageMissing code, dataset, citation and institution fields are tracked without dominating the paper.Details
Citations: 0Reviews: 0Saves: 0Code: not linkedDataset: not linkedInstitutions: 0

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Edward O. BarnesXiaojun ChenaPeilin LiRichard G. Compton

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