Unusual Field-Insensitive Phase Transition and Kondo Behavior in SmTi2_2Al20_{20}

preprint2011arXivOpen access

Abstract

Magnetization, electrical resistivity and specific heat measurements were performed on high-quality single crystalline SmTi2_2Al20_{20} (residual resistivity ratio ∼\sim 40) grown by Al self-flux method. A Kondo-like log⁡T\log T dependence in the resistivity is observed below 50 K. We discovered a field-insensitive phase transition at TxT_{x} = 6.5 K and a field-insensitive heavy fermion behavior with the electronic specific heat coefficient γγ = 150 mJ/(K2^{2} mol). Specific heat analysis reveals that the ground state is a Γ8Γ_{8} quartet state and the Sm magnetic dipole moment mSmm_{\rm Sm} (∼0.5μB\sim 0.5 μ_{\rm B} at T≃T \simeq 0) orders below TxT_{x} in spite of the field-insensitive behavior. Possible reasons for the field insensitiveness will be discussed.

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