Universal lower bounds on energy and momentum diffusion in liquids

Thermal energy can be conducted by different mechanisms including by single particles or collective excitations. Thermal conductivity is system-specific and shows a richness of behaviors currently explored in different systems including insulators, strange metals and cuprate superconductors. Here, we show that despite the seeming complexity of thermal transport, the thermal diffusivity $α$ of liquids and supercritical fluids has a lower bound which is fixed by fundamental physical constants for each system as $α_m=\frac{1}{4π}\frac{\hbar}{\sqrt{m_em}}$, where $m_e$ and $m$ are electron and molecule masses. The newly introduced elementary thermal diffusivity has an absolute lower bound dependent on $\hbar$ and the proton-to-electron mass ratio only. We back up this result by a wide range of experimental data. We also show that theoretical minima of $α$ coincide with the fundamental lower limit of kinematic viscosity $ν_m$. Consistent with experiments, this points to a universal lower bound for two distinct properties, energy and momentum diffusion, and a surprising correlation between the two transport mechanisms at their minima. We observe that $α_m$ gives the minimum on the phase diagram except in the vicinity of the critical point, whereas $ν_m$ gives the minimum on the entire phase diagram.

No reviews yet.

No comments yet.