Towards a large deviation theory for statistical-mechanical complex systems

preprint2011arXivOpen access

Abstract

The theory of large deviations constitutes a mathematical cornerstone in the foundations of Boltzmann-Gibbs statistical mechanics, based on the additive entropy SBG=−kB∑i=1Wpiln⁡piS_{BG}=- k_B\sum_{i=1}^W p_i \ln p_i. Its optimization under appropriate constraints yields the celebrated BG weight e−βEie^{-βE_i}. An elementary large-deviation connection is provided by NN independent binary variables, which, in the N→∞N\to\infty limit yields a Gaussian distribution. The probability of having n≠N/2n \ne N/2 out of NN throws is governed by the exponential decay e−Nre^{-N r}, where the rate function rr is directly related to the relative BG entropy. To deal with a wide class of complex systems, nonextensive statistical mechanics has been proposed, based on the nonadditive entropy Sq=kB1−∑i=1Wpiqq−1S_q=k_B\frac{1- \sum_{i=1}^W p_i^q}{q-1} (q∈R; S1=SBGq \in {\cal R}; \,S_1=S_{BG}). Its optimization yields the generalized weight eq−βqEie_q^{-β_q E_i} (eqz≡[1+(1−q)z]1/(1−q); e1z=ez)e_q^z \equiv [1+(1-q)z]^{1/(1-q)};\,e_1^z=e^z). We numerically study large deviations for a strongly correlated model which depends on the indices Q∈[1,2)Q \in [1,2) and γ∈(0,1)γ\in (0,1). This model provides, in the N→∞N\to\infty limit (∀γ\forall γ), QQ-Gaussian distributions, ubiquitously observed in nature (Q→1Q\to 1 recovers the independent binary model). We show that its corresponding large deviations are governed by eq−Nrqe_q^{-N r_q} (∝1/N1/(q−1)\propto 1/N^{1/(q-1)} if q>1q>1) where q=Q−1γ(3−Q)+1≥1q= \frac{Q-1}{γ(3-Q)}+1 \ge 1. This qq-generalized illustration opens wide the door towards a desirable large-deviation foundation of nonextensive statistical mechanics.

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