The magnetic structures of the anisotropic inter-metallic compounds Er2_2CoGa8_8 and Tm2_2CoGa8_8

preprint2011arXivOpen access

Abstract

Two members of the iso-structural R2_2CoGa8_8 inter-metallic series, Er2_2CoGa8_8 and Tm2_2CoGa8_8, have been studied by powder neutron diffraction. Antiferromagnetic ordering of the rare-earth sublattices was confirmed to occur at 3.0 K and 2.0 K, respectively. Furthermore, determination of the critical exponent showed Er2_2CoGa8_8 to adopt a 3D universality class. In spite of a common magnetic easy axis and similar structural characteristics, the antiferromagnetic structures were found to be different for the erbium and thulium based compounds. The corresponding magnetic space groups were determined to be P2ammm′P_{2a}mmm' and PCmmmP_Cmmm. The difference in magnetic structures is discussed based on crystal electric field effects that are known to be prevalent in such materials.

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