The cooperative Jahn-Teller ordering investigation by absorption spectra in KDy(MoO4)2KDy(MoO_4)_2

preprint2014arXivOpen access

Abstract

Absorption spectra fine structure of KDy(MoO4)2KDy(MoO_4)_2 in the region of cooperative Jahn-Teller type ordering was studied. Temperature anomalies in the spectra occurring at phase transformation correlate with the ultrasound peculiarities observed earlier. Based on the symmetry approaching, possible activity of the irreducible representations of the rhombic D2hD_{2h} point group was discussed, which lead to the incommensurate phase at cooperative ordering. It was supposed, that coupled AuA_u-type phonon mode may lead to the incommensurate phase existence, which is possible at least in the temperature region 17-12 K.

Explore this paper’s authors, topics and related work.

Building this map preview

BZPEER is loading the nearby papers, people, topics and institutions for this page.

Reviews 0

Write a reviewWrite

No reviews yet.

Discussion 0

Add a commentWrite

No comments yet.