Abstract

Using angle-resolved photoemission spectroscopy (ARPES), we revealed the surface electronic structure and superconducting gap of (Li0.8_{0.8}Fe0.2_{0.2})OHFeSe, an intercalated FeSe-derived superconductor without antiferromagnetic phase or Fe-vacancy order in the FeSe layers, and with a superconducting transition temperature (TcT_c) ∼\sim 40 K. We found that (Li0.8_{0.8}Fe0.2_{0.2})OH layers dope electrons into FeSe layers. The electronic structure of surface FeSe layers in (Li0.8_{0.8}Fe0.2_{0.2})OHFeSe resembles that of Rbx_xFe2−y_{2-y}Se2_2 except that it only contains half of the carriers due to the polar surface, suggesting similar quasiparticle dynamics between bulk (Li0.8_{0.8}Fe0.2_{0.2})OHFeSe and Rbx_xFe2−y_{2-y}Se2_2. Superconducting gap is clearly observed below TcT_c, with an isotropic distribution around the electron Fermi surface. Compared with AxA_xFe2−y_{2-y}Se2_2 (\textit{A}=K, Rb, Cs, Tl/K), the higher TcT_c in (Li0.8_{0.8}Fe0.2_{0.2})OHFeSe might be attributed to higher homogeneity of FeSe layers or to some unknown roles played by the (Li0.8_{0.8}Fe0.2_{0.2})OH layers.

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