Spin-orbit coupling inactivity of Co2+^{2+} ion in geometrically frustrated magnet GeCo2_2O4_4

preprint2011arXivOpen access

Abstract

We report single-crystal neutron diffraction studies on a spinel antiferromagnet GeCo2_2O4_4, which exhibits magnetic order with a trigonal propagation vector and tetragonal lattice expansion (c/a≃1.001c/a\simeq1.001) below TN=21T_{\rm N}=21 K. For this inconsistency between spin and lattice in symmetry, magnetic Bragg reflections with a tetragonal propagation vector were discovered below TNT_{\rm N}. We discuss spin and orbital states of Co2+^{2+} ion underlying the new magnetic component.

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