Single crystal growth and characterization of GdRh2_2Si2_2

preprint2016arXivOpen access

Abstract

High-temperature indium flux growth was applied to prepare single crystals of GdRh2_2Si2_2 by a modified Bridgman method leading to mm-sized single crystals with a platelet habitus. Specific heat and susceptibility data of GdRh2_2Si2_2 exhibit a pronounced anomaly at TN=107 KT_N = 107\rm \,K, where the AFM ordering sets in. Magnetic measurements on the single crystals were performed down to T=2T = 2\,K in external fields from B = 0 - 9\,T applied along the [100][100]-, [110][110]- and [001][001]-direction of the tetragonal lattice. The effective magnetic moment determined from a Curie-Weiss fit agrees well with values from literature, and is larger than the theoretically predicted value. Electrical transport data recorded for current flow parallel and perpendicular to the [001][001]-direction show a large anisotropy below TNT_N. The residual resistivity ratio RRR=ρ300K/ρ0∼23\rm RRR=ρ_{300K}/ρ_{0}\sim 23 demonstrates that we succeeded in preparing high-quality crystals using high-temperature indium flux-growth.

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