Scattering properties of the 2e−2e+2e^-2e^+ polyelectronic system

preprint2014arXivOpen access

Abstract

We study the 2e−2e+2e^-2e^+ equal-mass charge-neutral four-body system in the adiabatic hyperspherical framework. The lowest few adiabatic potentials are calculated for zero orbital angular momentum, positive parity, and charge conjugation symmetries. Propagating the R-matrix, the low-energy ss-wave scattering lengths of the singlet-singlet and triplet-triplet spin configurations are calculated. Lastly, we calculate the S-matrix for energies above the ionic threshold to estimate the transition rates between the single ionic fragmentation channel and the lowest few dimer-dimer fragmentation channels.

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