Paper detail

Scaling equations for mode-coupling theories with multiple decay channels

Multiple relaxation channels often arise in the dynamics of liquids where the momentum current associated to the particle-conservation law splits into distinct contributions. Examples are strongly confined liquids for which the currents in lateral and longitudinal direction to the walls are very different, or fluids of nonspherical particles with distinct relaxation patterns for translational and rotational degrees of freedom. Here, we perform an asymptotic analysis of the slow structural relaxation close to kinetic arrest as described by mode-coupling theory (MCT) with several relaxation channels. Compared to standard MCT, the presence of multiple relaxation channels significantly changes the structure of the underlying equations of motion and leads to additional, non-trivial terms in the asymptotic solution. We show that the solution can be rescaled, and thus prove that the well-known $ β$-scaling equation of MCT remains valid even in the presence of multiple relaxation channels. The asymptotic treatment is validated using a novel schematic model. We demonstrate that the numerical solution of this schematic model can indeed be described by the derived asymptotic scaling laws close to kinetic arrest. Additionally, clear traces of the existence of two distinct decay channels are found in the low-frequency susceptibility spectrum, suggesting that clear footprints of the additional relaxation channels can in principle be detected in simulations or experiments of confined or molecular liquids.

preprint2020arXivOpen access
0citations
0reviews
0saves
Nocode
Nodataset
0institutions

Next steps

Decide what to do with this paper

Use like or dislike for the fast social read. The more specific scholarly feedback stays available below when needed.

Log in to curate

Reading frame

Keep the important context close to the paper

Keep the important signals around this paper in one place: votes, save state, collection context, reviews and the metadata you need before deciding what to do next.

Institutions

Add specific reaction

Move through the context

Research map

Open full explorer

Move through nearby people, institutions, topics and adjacent work without leaving the paper page.

Building this graph slice

BZPEER is loading the nearby papers, people, topics and institutions for this page.

Structured reviews

0 review(s)

ContributeLeave structured feedbackUse the review template when you have a concrete strength, concern or method question.Open review form

No structured reviews yet. High-signal critique starts here.

Work discussion

0 comment(s)

DiscussAdd a high-signal commentKeep quick notes, caveats and replication pointers separate from formal reviews.Open comment form

No discussion yet. The first strong comment sets the tone.