Reentrant Wetting Transition of a Rough Wall

preprint1996arXivOpen access

Abstract

A 2D2D model describing depinning of an interface from a rough, self-affine substrate, is studied by transfer matrix methods. The phase diagram is determined for several values of the roughness exponent, ζSζ_S, of the attractive wall. For all ζS>0ζ_S>0 the following scenario is observed. In first place, in contrast to the case of a flat wall (ζS=0ζ_S=0), for wall attraction energies between zero and a ζSζ_S-dependent positive value, the substrate is always wet. Furthermore, in a small range of attraction energies, a dewetting transition first occurs as T increases, followed by a wetting one. This unusual reentrance phenomenon seems to be a peculiar feature of self-affine roughness, and does not occur, e. g., for periodically corrugated substrates.

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