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Quantum Isothermal Reversible Process of Particles in a Box with a Delta Potential

For an understanding of a heat engine working in the microscopic scale, it is often necessary to estimate the amount of reversible work extracted by isothermal expansion of the quantum gas used as its working substance. We consider an engine with a movable wall, modeled as an infinite square well with a delta peak inside. By solving the resulting one-dimensional Schrödinger equation, we obtain the energy levels and the thermodynamic potentials. Our result shows how quantum tunneling degrades the engine by decreasing the amount of reversible work during the isothermal expansion.