Precise measurement of hyperfine structure in the 2P1/2{2P}_{1/2} state of 7^{7}Li using saturated-absorption spectroscopy

preprint2010arXivOpen access

Abstract

We report a precise measurement of the hyperfine interval in the 2P1/2{2P}_{1/2} state of 7^{7}Li. The transition from the ground state (D1D_1 line) is accessed using a diode laser and the technique of saturated-absorption spectroscopy in hot Li vapor. The interval is measured by locking an acousto-optic modulator to the frequency difference between the two hyperfine peaks. The measured interval of 92.040(6)~MHz is consistent with an earlier measurement reported by us using an atomic-beam spectrometer [Das and Natarajan, J.\ Phys.\ B {\bf 41}, 035001 (2008)]. The interval yields the magnetic dipole constant in the P1/2P_{1/2} state as A=46.047(3)A=46.047(3), which is discrepant from theoretical calculations by >80>80~kHz.

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