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Path Integral Methods in the Su-Schrieffer-Heeger Polaron Problem

I propose a path integral description of the Su-Schrieffer-Heeger Hamiltonian, both in one and two dimensions, after mapping the real space model onto the time scale. While the lattice degrees of freedom are classical functions of time and are integrated out exactly, the electron particle paths are treated quantum mechanically. The method accounts for the variable range of the electronic hopping processes. The free energy of the system and its temperature derivatives are computed by summing at any $T$ over the ensemble of relevant particle paths which mainly contribute to the total partition function. In the low $T$ regime, the {\it heat capacity over T} ratio shows un upturn peculiar to a glass-like behavior. This feature is more sizeable in the square lattice than in the linear chain as the overall hopping potential contribution to the total action is larger in higher dimensionality. The effects of the electron-phonon anharmonic interactions on the phonon subsystem are studied by the path integral cumulant expansion method.