Abstract
We have calculated the p-wave phase shifts and scattering length of Li. For this we solve the partial wave Schrödinger equation and analyze the validity of adopting the semiclassical solution to evaluate the constant factors in the solution. Unlike in the wave case, the semiclassical solution does not provide unique value of the constants. We suggest an approximate analytic solution, which provides reliable results in special cases. Further more, we also use the variable phase method to evaluate the phase shifts. The p-wave scattering lengths of Cs and Cs are calculated to validate the schemes followed. Based on our calculations, the value of the wave scattering length of Li is .
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