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Optimizing Thermodynamic Cycles with Two Finite-Sized Reservoirs

We study the non-equilibrium thermodynamics of a heat engine operating between two finite-sized reservoirs with well-defined temperatures. Within the linear response regime, it is found that the uniform temperature of the two reservoirs at final time $τ$ is bounded from below by the entropy production $σ_{\mathrm{min}}\propto1/τ$. We discover a general power-efficiency trade-off depending on the ratio of heat capacities ($γ$) of the reservoirs for the engine. And a universal efficiency at maximum average power of the engine for arbitrary $γ$ is obtained. For practical purposes, the operation protocol of an ideal gas heat engine to achieve the optimal performance associated with $σ_{\mathrm{min}}$ is demonstrated. Our findings can be used to develop an general optimization scenario for thermodynamic cycles with finite-sized reservoirs in real-world circumstances.

preprint2021arXivOpen access
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