Paper detail

On the relation between the second law of thermodynamics and classical and quantum mechanics

In textbooks on statistical mechanics, one finds often arguments based on classical mechanics, phase space and ergodicity in order to justify the second law of thermodynamics. However, the basic equations of motion of classical mechanics are deterministic and reversible, while the second law of thermodynamics is irreversible and not deterministic, because it states that a system forgets its past when approaching equilibrium. I argue that all "derivations" of the second law of thermodynamics from classical mechanics include additional assumptions that are not part of classical mechanics. The same holds for Boltzmann's H-theorem. Furthermore, I argue that the coarse-graining of phase-space that is used when deriving the second law cannot be viewed as an expression of our ignorance of the details of the microscopic state of the system, but reflects the fact that the state of a system is fully specified by using only a finite number of bits, as implied by the concept of entropy, which is related to the number of different microstates that a closed system can have. While quantum mechanics, as described by the Schroedinger equation, puts this latter statement on a firm ground, it cannot explain the irreversibility and stochasticity inherent in the second law.

preprint2014arXivOpen access

Signal facts

What is known right now

Open access1 author1 topic

Next steps

Decide what to do with this paper

Use like or dislike for the fast social read. The more specific scholarly feedback stays available below when needed.

Log in to curate

Reading frame

Keep the important context close to the paper

Keep the important signals around this paper in one place: votes, save state, collection context, reviews and the metadata you need before deciding what to do next.

Institutions

Add specific reaction

Move through the context

Research map

Open full explorer

Move through nearby people, institutions, topics and adjacent work without leaving the paper page.

Building this map preview

BZPEER is loading the nearby papers, people, topics and institutions for this page.

Structured reviews

0 review(s)

ContributeLeave structured feedbackUse the review template when you have a concrete strength, concern or method question.Open review form

No structured reviews yet. High-signal critique starts here.

Work discussion

0 comment(s)

DiscussAdd a high-signal commentKeep quick notes, caveats and replication pointers separate from formal reviews.Open comment form

No discussion yet. The first strong comment sets the tone.