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On the equation of state of a dense columnar liquid crystal

An accurate description of a columnar liquid crystal of hard disks at high packing fractions is presented using an improved free-volume theory. It is shown that the orientational entropy of the disks in the one-dimensional fluid direction leads to a different high-density scaling pressure compared to the prediction from traditional cell theory. Excellent quantitative agreement is found with recent Monte-Carlo simulation results for various thermodynamic and structural properties of the columnar state.

preprint2004arXivOpen access
H. H. Wensink
cond-mat.stat-mechcond-mat.soft
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Open access1 author2 topics
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H. H. Wensink

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