Abstract

We calculate the conductance as a function of temperature G(T)G(T) through Au monoatomic chains containing one Co atom as a magnetic impurity, and connected to two conducting leads with a 4-fold symmetry axis. Using the information derived from {\it ab initio} calculations, we construct an effective model $\Heff$ that hybridizes a 3d7^7 quadruplet at the Co site with two 3d8^8 triplets through the hopping of 5dxz_{xz} and 5dyz_{yz} electrons of Au. The quadruplet is split by spin anisotropy due to spin-orbit coupling. Solving $\Heff$ with the numerical renormalization group (NRG) % Wb: reverted my own change we find that at low temperatures G(T)=a−bTG(T)=a-b \sqrt{T} and the ground state impurity entropy is ln⁡(2)/2\ln(2)/2, a behavior similar to the two-channel Kondo model. Stretching the chain leads to a non Kondo phase, with the physics of the underscreened Kondo model at the quantum critical point.

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