New bounds on the maximum ionization of atoms

preprint2011arXivOpen access

Abstract

We prove that the maximum number NcN_c of non-relativistic electrons that a nucleus of charge ZZ can bind is less than 1.22Z+3Z1/31.22Z+3Z^{1/3}. This improves Lieb's upper bound Nc<2Z+1N_c<2Z+1 [{\it Phys. Rev. A} {\bf 29}, 3018-3028 (1984)] when Z≥6Z\ge 6. Our method also applies to non-relativistic atoms in magnetic field and to pseudo-relativistic atoms. We show that in these cases, under appropriate conditions, lim sup⁡Z→∞Nc/Z≤1.22\limsup_{Z\to \infty}N_c/Z \le 1.22.

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