Abstract

To elucidate the origin of nematic order in Fe-based superconductors, we report a Raman scattering study of lattice dynamics, which quantify the extent of C4C_4-symmetry breaking, in BaFe2_2As2_2 and FeSe. FeSe possesses a nematic ordering temperature TsT_\mathrm{s} and orbital-related band-energy split below TsT_\mathrm{s} that are similar to those in BaFe2_2As2_2, but unlike BaFe2_2As2_2 it has no long-range magnetic order. We find that the EgE_g phonon-energy split in FeSe sets in only well below TsT_\mathrm{s}, and its saturated value is substantially smaller than that in BaFe2_2As2_2. Together with reported results for the Ba(Fe1−x_{1-x}Cox_{x})2_2As2_2 family, the data suggest that magnetism exerts a major influence on the lattice.

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