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Paper detail

Near-infrared luminescence in bismuth-doped TlCl crystal

Experimental and theoretical studies of spectral properties of crystalline TlCl:Bi are performed. Two broad near-infrared luminescence bands with a lifetime about 0.25 ms are observed: a strong band near 1.18 mkm excited by 0.40, 0.45, 0.70 and 0.80 mkm radiation, and a weak band at > 1.5 mkm excited by 0.40 and 0.45 mkm radiation. Computer modeling of Bi-related centers in TlCl lattice suggests that Bi^+__V^-(Cl) center (Bi^+ in Tl site and a negatively charged Cl vacancy in the nearest anion site) is most likely responsible for the IR luminescence.

preprint2013arXivOpen access
V. G. PlotnichenkoV. O. SokolovD. V. PhilippovskiyE. M. Dianov. I. S. LisitskyM. S. KouznetsovK. S. Zaramenskikh
cond-mat.mtrl-sciphysics.optics
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V. G. PlotnichenkoV. O. SokolovD. V. PhilippovskiyE. M. Dianov. I. S. LisitskyM. S. KouznetsovK. S. Zaramenskikh

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